含银高分子膜材料的应用及研究进展

doi:10.19964/j.issn.1006-4990.2020-0386

Abstract

Abstract:

With the wide application of polymer membrane materials in the fields of water treatment technology,medicine,food,agriculture and chemical industry,it has become a hot topic in recent years to improve the bacteriostasis,anti-pollution and water flux of polymer membrane materials by different methods in order to prolong the service life of polymer membrane materials.The main applications of silver-containing polymer membrane materials were introduced.The different effects of silver and silver ions on the modification of polymer membrane materials were described respectively.The modification methods of silver-containing polymer membrane materials by phase transformation,blending,in-situ synthesis,ion exchange and interfacial polymerization were discussed.The optimization of antibacterial performance,anti pollution performance and water flux of polymer membrane materials modified by different modification methods were summarized.The addition of silver could improve the bacteriostatic rate of polymer membrane materials,and the bacteriostatic rate could reach 100%.The addition of silver could effectively improve the anti-pollution performance of membrane materials,and its water flux to polymer membrane materials was also improved to a certain extent.

Key words: silver, polymer membrane material, modification, bacteriostasis, anti-pollution

CLC Number:

TQ383

Guan Ruoling,Sun Chang,Zhuo Xianqin. Application and research progress of silver-containing polymer membrane materials[J]. Inorganic Chemicals Industry, 2021, 53(6): 110-117.

Figures/Tables 10

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References 32

[1]	耿奎士, 董然. 高分子膜材料的研究概况[J]. 合成树脂及塑料, 1993(2):52-57.
[2]	杜春慧, 吴春金, 吴礼光. 智能型高分子膜的制备及应用研究进展[J]. 现代化工, 2010,30(3):27-30,32.
[3]	孙宇轩, 张所波. 官能化聚醚砜(酮)膜材料制备与性能研究[J]. 膜科学与技术, 2020,40(1):328-339.
[4]	胡利杰, 梁松苗, 蔡志奇, 等. 抗菌超滤膜研究进展[J]. 塑料科技, 2015,43(11):96-100.
[5]	陈义丰, 余建峰, 张亚涛, 等. 抗菌超滤膜的研究进展[J]. 现代化工, 2012,32(3):21-25.
[6]	管若伶, 王海增. 氯化银-聚醚砜复合膜制备及吸附去除水中Br^-研究[J]. 水处理技术, 2018,44(5):22-26.
[7]	孟宸羽, 马振营, 范志平, 等. 矿物中碘元素树脂交换吸附方法研究[J]. 中国锰业, 2017,35(4):126-129.
[8]	秦龙鑫, 潘国元, 张杨, 等. 纳米银在水处理膜中的应用进展[J]. 化工进展, 2016,35(7):2114-2120.
[9]	初洺旭, 程志强, 李明堂. 载银交联聚乙烯醇/木耳多糖复合纳米纤维膜的制备及其性能研究[J]. 化工新型材料, 2019,47(S1):45-49.
[10]	Basri H, Ismail A F, Aziz M. Polyethersulfone(PES)-silver compo-site UF membrane:Effect of silver loading and PVP molecular weight on membrane morphology and antibacterial activity[J]. Desalination, 2011,273(1):72-80. doi: 10.1016/j.desal.2010.11.010
[11]	李鑫, 方小峰, 李健生, 等. 纳米Ag粒子原位杂化PVDF超滤膜的抗污染性能[J]. 环境科学学报, 2014,34(3):638-644.
[12]	刘姿铔, 曹如雅, 张曼莹. 介孔石墨相氮化碳载银聚醚砜膜制备及性能研究[J]. 无机材料学报, 2019,34(5):478-486.
[13]	朱子沛, 钟炼军, 何其, 等. 负载纳米银磺化聚醚砜超滤膜的制备及其抗菌性[J]. 精细化工, 2017,34(6):637-644.
[14]	曾琦斐, 李绍国, 谭荣喜. 聚乙烯吡咯烷酮还原氧化银制备纳米银颗粒的研究[J]. 无机盐工业, 2015,47(8):37-39.
[15]	Diagne F, Malaisamy R, Boddie V, et al. Polyelectrolyte and silver nanoparticle modification of microfiltration membranes to mitigate organic and bacterial fouling[J]. Environmental Science & Tech-nology, 2012,46(7):4025-4033.
[16]	何小娟, 杨再鹏, 党海燕, 等. 膜技术在水处理中的应用及膜材料研究进展[J]. 化工环保, 2004,24(3):185-189.
[17]	Zodrow K, Brunet L, Mahendra S, et al. Polysulfone ultrafiltration membranes impregnated with silver nanoparticles show improved biofouling resistance and virus removal[J]. Water Research, 2008,43(3):715-723. doi: 10.1016/j.watres.2008.11.014
[18]	薄艳娜, 林勤保, 苏启枝, 等. 纳米银-聚乙烯复合薄膜的制备及表征[J]. 包装工程, 2017,38(19):8-13.
[19]	艾茜, 胡长鹰, 林勤保, 等. 纳米银/低密度聚乙烯复合食品包装薄膜的表征及性能[J]. 食品工业科技, 2014,35(22):294-298.
[20]	管若伶, 王海增. 溴资源与主要化工品[J]. 无机盐工业, 2018,50(4):6-10.
[21]	Sanchez-Polo M, Rivera-Utrilla J, Salhi E, et al. Ag-doped carbon aerogels for removing halide ions in water treatment[J]. Water Re-search, 2007,41(5):1031-1037.
[22]	宋锡高. 中国碘素产业发展现状[J]. 无机盐工业, 2014,46(3):9-12.
[23]	张加幸, 于跃芹. 海带漂烫水中碘的空气吹出法提取工艺研究[J]. 无机盐工业, 2016,48(5):27-29.
[24]	王景刚, 冯丽娟, 相湛昌, 等. 碘提取方法的研究进展[J]. 无机盐工业, 2008,40(11):11-14.
[25]	高强立, 何雅莉, 刘晓丹, 等. 纳米银负载型阳离子交换树脂的制备及其对水中碘离子的吸附去除[J]. 化工环保, 2020,40(3):1-7.
[26]	高从堦, 陈益棠. 纳滤膜及其应用[J]. 中国有色金属学报, 2004,14(z1):310-316.
[27]	刘方, 李巧玲. 氧化高银醋酸纤维素膜的制备及性能[J]. 现代化工, 2016,36(1):144-146.
[28]	魏占锋, 董峰, 王哲, 等. 载银纳米纤维素/聚乙烯醇复合膜的制备及性能研究[J]. 包装工程, 2018,39(9):51-55.
[29]	朱天容, 胡思前, 余凡, 等. 银负载聚酰亚胺复合膜的制备及导电性能研究[J]. 化工新型材料, 2019,47(10):56-59.
[30]	侯智婕, 李巧玲. 氧化高银/聚酰胺复合膜的制备及性能研究[J]. 现代化工, 2017,37(1):115-117,119.
[31]	陈义丰, 王涛, 张亚涛, 等. 负载纳米银的埃洛石纳米管/聚醚砜杂化超滤膜的制备及其抗菌性能[J]. 化工学报, 2012,63(6):1922-1928.
[32]	肖汉. 超滤膜技术在环境工程水处理中的研究与进展[J]. 资源节约与环保, 2020(1):81,84.

膜名称	加入银种类	样品编号	细菌种类	加入银前后抑菌率/%
膜名称	加入银种类	样品编号	细菌种类	未加入银	加入银
介孔石墨相氮化碳载银聚醚砜膜^[12]	硝酸银	a	大肠杆菌	0	100
介孔石墨相氮化碳载银聚醚砜膜^[12]	硝酸银	b	假单胞菌	0	100
负载纳米银磺化聚醚砜膜^[13]	银单质	c	大肠杆菌	几乎无抗菌能力	96.7
		d	假单胞菌	几乎无抗菌能力	98.3
		e	金黄色葡萄球菌	几乎无抗菌能力	87.7

膜名称	添加银种类	添加银前后纯水通量/（L·m^-2·h^-1）
膜名称	添加银种类	未添加银	添加银
纳米银粒子原位杂化聚偏二氟乙烯超滤膜^[11]	银单质	36.40	82.40
介孔石墨相氮化碳载银聚醚砜膜^[12]	AgNO₃	—	258.29
氧化高银/聚酰胺复合膜^[30]	AgNO₃	42.41	161.48

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Inorganic Acid-Base-Salt Committee of CIESC

Application and research progress of silver-containing polymer membrane materials

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