煤矸石制备磁性X型分子筛及其Pb2+吸附研究

doi:10.19964/j.issn.1006-4990.2025-0042

Abstract

Abstract:

In order to improve the adsorption performance and recyclability of molecular sieves，a magnetic molecular sieve with the corresponding structure was prepared by hydrothermal synthesis using coal gangue with a silicon⁃aluminum ratio suitable for X zeolite，and it was used in the treatment of wastewater containing heavy metals.The results showed that the optimal preparation conditions for magnetic X zeolite were：n（H₂C₂O₄）/n（Fe³⁺） was 5，crystallization time was 10 h，and crystallization temperature was 85 ℃，n（citric acid）/n（Al₂O₃） was 0.85，and ultrasound promoted the complexation of molecular sieves and citric acid，which had a better synergistic effect.The synthesized molecular sieves were characterized and analyzed by XRD，SEM，FT-IR，XPS and carbon dioxide adsorption.The effect of parameters such as iron content，adsorption time，pH，initial concentration and amount of molecular sieve added on the adsorption of lead ions were considered.When the iron content of the molecular sieve was 0.33%，the adsorption time was 14 min，the solution pH was 5，the lead ion concentration was 50 mg/L and the molecular sieve dosage was 0.2 g，magnetic X zeolite showed the best adsorption effect on lead ions.Moreover，the magnetic recovery rate of magnetic molecular sieve still reached more than 90% after being recycled 8 times in an external magnetic field，achieving the goal of saving resources，low carbon and environmental protection.

Key words: coal gangue, magnetic, X zeolite, Pb²⁺ absorption

CLC Number:

TQ424.25

PENG Huanling, CUI Wei, LEI Hongmei. Study on preparation of magnetic X zeolite from coal gangue and its adsorption properties of Pb²⁺[J]. Inorganic Chemicals Industry, 2026, 58(1): 92-98.

Figures/Tables 15

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References 20

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样品	w（SiO₂）	w（Al₂O₃）	w（Fe₂O₃）	w（CaO）	w（MgO）
董东矿	58.80	25.61	10.10	2.09	0.21
澄合一矿	62.00	21.43	5.34	4.40	0.37
澄合二矿	67.75	15.97	4.94	3.28	0.38
合阳一矿	46.30	33.61	10.27	1.39	0.18
王斜矿	51.15	26.16	12.44	2.19	0.27

水平	试验因素
水平	A 晶化时间/h	B 晶化温度/℃	C n（H₂C₂O₄）/n（Fe³⁺）
1	6	75	4
2	8	85	5
3	10	95	6

样品号	因素			吸附量/ （mg·g^-1）
样品号	A 晶化时间/h	B 晶化温度/℃	C n（H₂C₂O₄）/ n（Fe³⁺）	吸附量/ （mg·g^-1）
1	6	75	4	107.75
2	6	85	5	105.26
3	6	95	6	109.11
4	8	75	5	146.81
5	8	85	6	147.80
6	8	95	4	146.71
7	10	75	6	184.22
8	10	85	4	186.47
9	10	95	5	190.24
K₁	322.11	438.78	440.93
K₂	441.32	544.79	442.31
K₃	560.93	446.06	441.13
极差R	238.82	106.01	1.38
主次顺序	A>B>C
最优水平	A₃	B₂	C₂
最优组合	A₃B₂C₂

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Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation of magnetic X zeolite from coal gangue and its adsorption properties of Pb²⁺

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Study on preparation of magnetic X zeolite from coal gangue and its adsorption properties of Pb2+