无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (7): 29-.

• 论文 • 上一篇    下一篇

球形纳米氧化钇的制备与表征

吴洪达,贾佑顺,张兵兵,张泽远,叶海梅   

  1. 广西科技大学生物与化学工程学院,广西柳州 545006
  • 出版日期:2016-07-10 发布日期:2016-07-25

Preparation and characterization of spherical nano-sized Y2O3 powders

 WU  Hong-Da, JIA  You-Shun, ZHANG  Bing-Bing, ZHANG  Ze-Yuan, YE  Hai-Mei   

  1. College of Biological and Chemical Engineering,Guangxi University of Science and Technology,Liuzhou 545006,China
  • Published:2016-07-10 Online:2016-07-25

摘要: 以尿素为沉淀剂,硝酸钇为钇源,十六烷基三甲基溴化铵为分散剂,采用均相沉淀法制备球形纳米氧化钇粉体,研究了反应物浓度比、表面活性剂用量、反应时间、搅拌转速、反应温度对氧化钇形貌及粒径的影响。通过激光粒度分析、X射线衍射(XRD)分析、扫描电镜(SEM)分析、傅里叶红外光谱(FTIR)分析等手段对样品进行表征。结果表明,反应物浓度比、反应时间、搅拌转速、反应温度会影响粉体的尺寸,适量CTAB的加入可显著降低氧化钇的粒径;在最佳工艺条件下,可制得粒径大小为110~130 nm的球形氧化钇粉体。

关键词: 均相沉淀法, 球形纳米氧化钇, 尿素, 十六烷基三甲基溴化铵

Abstract: The spherical nano-sized Y2O3 powders were prepared by homogeneous precipitation method,with urea as the pre- cipitating agent,Y(NO3)3 as the yttrium source,and CTAB as the dispersant.The effects of reactants concentration ratio,dis- persant dosage,reaction time,reaction temperature,and stirring rate on the morphology and particle size of Y2O3 powders were investigated.The samples were characterized by laser particle size analyzer,X-ray diffraction(XRD),scanning electron microscopy(SEM),and Fourier transform infrared spectroscopy(FTIR).Results showed that the reactants concentration ratio, reaction time,stirring speed,and reaction temperature will affect the size of the powders,and the suitable addition of CTAB could reduce the particle size of Y2O3 significantly.Under the conditions of optimum process,the particle size of Y2O3 powders was about 110~130 nm.

Key words: homogeneous precipitation method, spherical nanometer Y2O3, urea, CTAB

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