无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (7): 48-.

• 论文 • 上一篇    下一篇

镁渣固化/稳定污酸渣中重金属铜和镉

陈玉洁,韩凤兰,罗 钊   

  1. 北方民族大学材料科学与工程学院,宁夏银川 750021
  • 出版日期:2015-07-10 发布日期:2015-09-24

Solidification/stabilization of heavy mental Cu and Cd in waste acid residue by magnesium slag

 CHEN  Yu-Jie, HAN  Feng-Lan, LUO   Zhao   

  1. School of Material Science &Engineering,Beifang University of Nationalities,Yinchuan 750021,China
  • Published:2015-07-10 Online:2015-09-24

摘要: 利用镁渣固化/稳定污酸渣中重金属铜和镉。向污酸渣与镁渣的混合渣料中掺杂不同浓度的铜和镉,做毒性浸出实验,用ICP检测铜和镉的含量,XRD研究渣料的物相变化。研究表明:用体积分数为1%~5%的硝酸溶液为浸提剂时浸取液中铜和镉的最高质量浓度分别为0.52、0.32 mg/L;用体积分数为1%~3%的硫酸溶液为浸提剂时浸取液中铜和镉的最高质量浓度分别为3.06、2.9 mg/L;镁渣固化/稳定污酸渣中重金属铜和镉的效果显著;污酸渣中掺杂镁渣后并没有引起渣料的物相变化,只是衍射峰的强弱发生了变化。

关键词: 镁渣, 污酸渣, 固化/稳定, 毒性浸出

Abstract: Heavy metal Cu and Cd in waste acid residue were solidified/stabilized by magnesium slag.Toxicity leaching experiment that mixed different concentrations of Cu and Cd with the mixer of waste acid residue and magnesium slag was carried out.The contents of Cu and Cd were tested by ICP and the phase changes of the slag were tested by XRD.Results showed that: The highest mass concentrations of Cu and Cd in leaching solution were 0.52 mg/L and 0.32 mg/L respectively when the leaching agent was nitric acid with volume fraction of 1%~5%.The maximum mass concentrations of Cu and Cd were 3.06 mg/L and 2.9 mg/L respectively with 1%~3% sulphuric acid as the leaching agent.The effect that magnesium slag solidified/stabilized Cu and Cd in waste acid residue was significant.With the addition of magnesium slag the phase of mixed slag had not changed,but the intensity of the diffraction peaks had changed.

Key words: magnesium slag, waste acid residue, solidification/stabilization, toxic leaching

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