无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2025, Vol. 57 ›› Issue (8): 58-64.doi: 10.19964/j.issn.1006-4990.2024-0476

• 研究与开发 • 上一篇    下一篇

硫酸镁/硅胶复合蜂窝胚体的制备及其除湿特性研究

张向京1(), 张美瑶1, 郑金海2, 徐晓阳1, 任鹏2   

  1. 1.河北科技大学化学与制药工程学院,河北 石家庄 050018
    2.拓蓝科技河北有限责任公司,河北 石家庄 051430
  • 收稿日期:2024-08-30 出版日期:2025-08-10 发布日期:2024-10-18
  • 通讯作者: 任鹏(1983— ),男,高级工程师,主要研究方向为环境吸附材料的研发和生产。
  • 作者简介:张向京(1970— ),男,博士研究生,教授,主要研究方向为化工新材料和过程强化;E-mail:zxj@hebust.edu.cn
  • 基金资助:
    河北省重大科技成果转化专项(22293701Z);河北省高等学校科学研究专项(产学研)项目(CXY2024008);河北省工业领域关键核心技术和产品“揭榜挂帅”拟定攻关项目(JGK241218)

Study on preparation and dehumidification characteristics of magnesium sulfate/silica gel composite honeycomb embryo

ZHANG Xiangjing1(), ZHANG Meiyao1, ZHENG Jinhai2, XU Xiaoyang1, REN Peng2   

  1. 1.School of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China
    2.Tuolan Technology Hebei Co. ,Ltd. ,Shijiazhuang 051430,China
  • Received:2024-08-30 Published:2025-08-10 Online:2024-10-18

摘要:

为了开发高性能除湿转轮,通过创新材料设计和工艺优化的方式,采用原位生长技术在圆柱形蜂窝载体上沉积硅胶基质,以硫酸镁(MgSO4)作为吸湿盐进行改性,成功制备了MgSO4/硅胶复合蜂窝胚体。采用单因素实验法,系统探究了增强载体机械强度的预处理条件和复合除湿材料的制备条件,确定了最优的预处理浆液配方为硅酸钠、聚乙烯醇(PVA)、铝溶胶的混合溶液(固体质量比1∶1∶1)。采用单因素实验法,确定了最佳负载工艺条件是硅酸钠质量分数为30%、分3次浸渍、酸化温度为90 ℃、酸质量分数为20%。胚体吸附测试结果表明,随着相对湿度从30%提升至80%,样品的吸附量从162 mg/g提升至251 mg/g,相对提高了54.93%,是单一硅胶的2~3倍。随着温度由15 ℃升高到35 ℃,样品的吸附平衡时间由835 s缩短至435 s,但吸附量由256 mg/g减少至133 mg/g。风速提高加快吸附速率,对平衡吸附量影响不大。循环吸脱附实验表明,材料具有优异的循环稳定性和再创性能。

关键词: 转轮除湿, 复合除湿材料, 原位生长技术, 除湿特性

Abstract:

In order to develop high-performance dehumidification runner,through innovative material design and process optimization,silica gel matrix was deposited on cylindrical honeycomb carrier by in-situ growth technology,and magnesium sulfate(MgSO4) was modified as hygroscopic salt.MgSO4/silica gel composite honeycomb embryo was successfully prepared.By using single factor experiment method,the pretreatment conditions of carrier to enhance mechanical strength and the preparation conditions of composite dehumidification materials were systematically explored,and the optimal pretreatment slurry formula was determined as sodium silicate,polyvinyl alcohol(PVA),aluminum sol(solid ratio 1∶1∶1).The optimal loading process conditions were determined by single factor experiment method as follows:the mass fraction of sodium silicate of 30%,impregnation for three times,acidification temperature of 90 ℃,the mass fraction of acid of 20%.The results of embryo adsorption test showed that with the increase of relative humidity from 50% to 80%,the moisture absorption of the sample was increased from 162 mg/g to 251 mg/g,increased by 54.93%,which was 2~3 times that of single silica gel.With the increase of temperature from 15 ℃ to 35 ℃,the adsorption equilibrium time of the sample was shortened from 835 s to 435 s,but the adsorption capacity was reduced from 256 mg/g to 133 mg/g.The increase of wind speed accelerated the adsorption rate and had little effect on the equilibrium adsorption capacity.The cyclic adsorption desorption experiments showed that the material had good cycling stability and renewability.

Key words: rotor dehumidification, composite desiccant materials, in-situ growth technology, dehumidification behavior

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