钇沉积的二氧化钛-SBA-15纳米催化剂制备及其应用

Abstract

Abstract:

In recent years,TiO₂ has been widely used in wastewater treatment.In order to reasonably improve the defects of TiO₂ in photocatalytic applications and improve the use scope of TiO₂,this paper first used hydrothermal synthesis to prepare SBA-15 mesoporous molecular sieves and deposit TiO₂ on them.Then a new photocatalyst Y-TiO₂-SBA-15 was prepared by impregnating yttrium nitrate deposit different amounts of yttrium on the molecular sieves.The catalysts were characterized by XRD,TEM,EDS,FT-IR and N₂ adsorption-desorption.The photo degradation ability of methyl orange was investigated under different conditions with methyl orange solution as the target degradant.The results showed that when the pH was 4 and the solution was irradiated by xenon lamp for 140 min at 300 w,the decolorization effect of orange was obvious and the degradation rate was 93.1%.

Key words: SBA-15 Zeolite, titanium dioxide, photocatalytic properties

CLC Number:

TQ134.11

Wang Shuo,Bai Liming. Preparation and application of yttrium-deposited TiO₂-SBA-15 nano-catalyst[J]. Inorganic Chemicals Industry, 2019, 51(3): 77-81.

Figures/Tables 6

References 16

[1]	Ren H, Koshy P . Photocatalytic materials and technologies for air purification[J]. Journal of Hazardous Materials, 2016,325:340-366. doi: 10.1016/j.jhazmat.2016.08.072 pmid: 27932035
[2]	Rogé V, Guignard C, Lamblin G , et al. Photocatalytic degradation behavior of multiple xenobiotics using MOCVD synthesized ZnO nanowires[J]. Catalysis Today, 2018,306:215-222.
[3]	Yu X, Ji Q, Zhang J , et al. Photocatalytic degradation of diesel pollu-tants in seawater under visible light[J]. Regional Studies in Marine Science, 2018,18:139-144.
[4]	da Silva A L, Dondi M, Raimondo M , et al. Photocatalytic ceramictiles:Challenges and technological solutions[J]. Journal of the Euro-pean Ceramic Society, 2018,38(4):1002-1017.
[5]	Anjum M, Al-Talhi H A .Visible light photocatalytic disintegration of waste activated sludge for enhancing biogas production[J]. Jo-urnal of Environmental Management, 2018,216:120-127. doi: 10.1016/j.jenvman.2017.07.064 pmid: 28874306
[6]	Pi Y, Li X . Adsorptive and photocatalytic removal of persistent organic pollutants(POPs) in water by metal-organic frameworks (MOFs)[J]. Chemical Engineering Journal, 2018,337:351-371.
[7]	Ma X J . Preparation of Mn-doped TiO₂ loaded on bamboo based acti-vated carbon fibers and its visible light photocatalytic properties[J]. Journal of Functional Materials, 2015,46(13):13121-13124.
[8]	Friedemann A E R, Thiel K, Gesing Th M , et al. Photocatalytic acti-vity of TiO₂ layers produced with plasma electrolytic oxidation[J]. Surface & Coatings Technology, 2018,344:710-721.
[9]	Zaine S N A, Mohamed N M, Samsudin A E , et al.Effect of metal doped-TiO₂ on the performance of dye solar cells(DSCs)[J].Spe-cialized Collections, 2014(925):548-552. doi: 10.1088/0957-4484/24/25/255401 pmid: 23727656
[10]	Reszczyńska J, Grzyb T . Lanthanide co-doped TiO₂:The effect of metal type and amount on surface properties and photocatalytic activity[J]. Applied Surface Science, 2014,307:333-345. doi: 10.1016/j.apsusc.2014.03.199
[11]	Yu J G, Su Y R, Cheng B . Template-free fabrication and enhanced photocatalytic activity of hierarchical macro-/mesoporous tita-nia[J]. Advanced Functional Materials, 2007,17(12):1984-1990.
[12]	Rahman M M, Khan S B .Selective Iron( Ⅲ) ion uptake using CuO-TiO₂,nanostructure by inductively coupled plasma-optical emission spectrometry[J]. Chemistry Central Journal, 2012,6(1):1-10.
[13]	Khedr T M, El-Sheikh S M, Hakki A ,et al.Highly active non-me-tals doped mixed-phase TiO₂ for photocatalytic oxidation of ibupro-fen under visible light[J]. Journal of Photochemistry and Photobi-ology A:Chemistry, 2017,346:530-540.
[14]	Bergamonti L, Predieri G, Paz Y , et al. Enhanced self-cleaning pro-perties of N-doped TiO₂ coating for Cultural Heritage[J]. Micro-chemical Journal, 2017,133:1-12.
[15]	Brindha A, Sivakumar T . Visible active N,S co-doped TiO₂/grap-hene photocatalysts for the degradation of hazardous dyes[J]. Jo-urnal of Photochemistry and Photobiology A:Chemistry, 2017,340:146-156.
[16]	Liu C H, Guan Y, Hensen E J M ,et al.Au/TiO₂@SBA-15 nanoco-mposites as catalysts for direct propylene epoxidation with O₂ and H₂ mixtures[J]. Journal of Catalysis, 2011,282(1):94-102.

样品	BET比表面积/ （m²·g^-1）	孔容/ （cm³·g^-1）	BJH孔径/ nm
SBA-15	676.43	1.40	7.92
TiO₂-SBA-15	593.48	0.93	6.55
Y-TiO₂-SBA-15	552.67	0.84	5.96

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Preparation and application of yttrium-deposited TiO₂-SBA-15 nano-catalyst

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 16

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Zhao Yang,He Sujiao,He Luhong. Fabriction and properties of flexible perovskite solar cells [J]. Inorganic Chemicals Industry, 2020, 52(7): 52-54.
[2]	Peng Wenbo,Yun Jianjun,Ding Bangchao,Bai Zuguo,Xiao Weiyi,Wang Xiaohu. Study on membrane integration technology in treatment of wastewater from chlorinated titanium dioxide [J]. Inorganic Chemicals Industry, 2020, 52(6): 76-79.
[3]	Gong Jiazhu,Lu Xiangfang,Wu Ninglan,Shao Guoxiong. Research and development of self-fitting nano-sized titanium dioxide catalytic wastewater treatment agent [J]. Inorganic Chemicals Industry, 2020, 52(5): 59-64.
[4]	Yin Haijiao,Xia Junjun,Quan Xiaoyu,Peng Tao,Tang Hao. Study on operation characteristics of mechanical flash cooling crystallization technology for titanium solution in summer [J]. Inorganic Chemicals Industry, 2020, 52(4): 93-95.
[5]	Chen Wen,Long Xiang,Li Haiyan,Yang Hui,Jia Guifa,Jin Yaqiu. Determination of particle size of gas phase oxided titanium dioxide by laser particle size analyzer [J]. Inorganic Chemicals Industry, 2020, 52(2): 69-71.
[6]	Gao Zengli,Li Qiuhong,Li Huaquan,Bi Hongyu. A new device for utilizing waste heat from calcination tail gas of titanium dioxide rotary kiln [J]. Inorganic Chemicals Industry, 2020, 52(2): 75-77.
[7]	Hu Min,Guo Jia,Wu Huadong,Zhang Linfeng. Photocatalytic oxidation of sodium sulfite in desulfurization wastewater by N-Zn/TiO₂ [J]. Inorganic Chemicals Industry, 2020, 52(10): 151-156.
[8]	Gong Jiazhu. Future trend and development course of titanium dioxide pigment industry for sixty years in China [J]. Inorganic Chemicals Industry, 2020, 52(10): 55-63.
[9]	Cao Peng. Effect of acid soluble main reverse on solubility of solid phase of titanium white production by sulfuric acid process [J]. Inorganic Chemicals Industry, 2019, 51(9): 54-56.
[10]	Lu Jie,Wu Huadong,Ma Shang,Zhang Linfeng,Yan Caicheng,Guo Jia. Preparation and characterization of nickel-based catalyst and its methanation performance [J]. Inorganic Chemicals Industry, 2019, 51(5): 78-81.
[11]	Lu Ruifang，Wu Jianchun，Liu Chan. Influence of titanyl sulfate solution hydrolysis process on tintreducing power of rutile titanium dioxide [J]. Inorganic Chemicals Industry, 2019, 51(12): 44-48.
[12]	Liao Xin1，2，Yang Shaoli1，Ma Lan1，Li Hong1. Comparison and analysis of sulfuric acid process titanium dioxide prepared with titanium concentrate and titanium slag as raw materials respectively [J]. Inorganic Chemicals Industry, 2019, 51(10): 7-11.
[13]	LIAO Xue-Feng, CHEN Guo, LIU Qian-Qian, CHANG Xiao-Dong, ZHANG Li-Bo, PENG Jin-Hui. Recent advances in phase transition of TiO₂ [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(8): 6-.
[14]	MA Guang-Qiang, ZOU Min, XIA Dong. Experimental study on titanium concentrate leaching to prepare Ti-rich material with titanium dioxide waste acid [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(8): 67-.
[15]	DU Jian-Qiao, XU Yu-Ting, ZHONG Ben-He. Technical analysis of green vitriol treatment in large-scale [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(5): 9-.

Preparation and application of yttrium-deposited TiO2-SBA-15 nano-catalyst