双酚A环氧树脂为硬模板剂制备等级孔β分子筛

Abstract

Abstract: Hierarchical β zeolite was synthesized by hydrothermal method with bisphenol A epoxy-resin as mesoporous template and with TEAOH（Tetraethyl ammonium hydroxide） as microporous template.The hierarchical β zeolite samples were characterized by X-ray diffraction，transmission electron microscopy，and nitrogen adsorption/desorption analysis.The results showed that the sample had rather high crystallinity and plenty of mesoporous structures were formed in the sample whose most probable pore size was about 20 nm.The effects of synthesis conditions，such as alkalinity，crystallizing time and water content in mother liquor，on the crystallinity and mesoporous structure of hierarchical β zeolite were also investigated.

Key words: bisphenol A epoxy-resin, mesoporous template, hierarchical pore, zeolite, hydrothermal synthesis

CLC Number:

SHAO Bi-Bo, ZHANG Ze-Kai, LIAO Bing-Bing, CHEN Yin-Fei. Synthesis of hierarchical β zeolite by bisphenol A epoxy-resin as premade rigid template[J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(12): 48-.

[1]	Zhang Yaori,Zang Jiazhong,Zhang Lijuan,Hong Meihua,Yu Haibin. Synthesis of NaY zeolite from preformed kaolin by dry gel conversion [J]. Inorganic Chemicals Industry, 2020, 52(8): 88-92.
[2]	Zang Yihua,Sheng Chunguang,Wu Wei,Liu Zongyuan,Li Yang,Chen Zan. Progress in synthesis of zeolite membranes in fluorine media [J]. Inorganic Chemicals Industry, 2020, 52(7): 12-17.
[3]	Chen Yanguang,Han Tong,Zhang Yanan,Yang Xiuqi,Han Hongjing,Wang Hao. Process regulation of ZSM-5 zeolite synthesis from hydrolyzed tetraethyl orthosilicate as silicon source in acidic medium [J]. Inorganic Chemicals Industry, 2020, 52(7): 88-93.
[4]	Zang Yihua,Chen Zan,Sheng Chunguang,Wu Wei,Zheng Qiuhong,Wang Liangming. Preparation of T-type zeolite membrane and its separation performance on acetonitrile-water containing acid [J]. Inorganic Chemicals Industry, 2020, 52(2): 50-53.
[5]	Li Xiaoguo,Mi Xiaotong,Hou Zhanggui. Synthesis of aggregated nano-sized ZSM-5 zeolite with ternary pore structure [J]. Inorganic Chemicals Industry, 2020, 52(12): 104-108.
[6]	Bian Xiaotong,Qiu Zhaofu,Yang Ji,Yan Ruiqi,Lü Shuguang. Study on fluoride removal by modified Y zeolite particles with sodium alginate-lanthanum hydroxide [J]. Inorganic Chemicals Industry, 2020, 52(12): 86-91.
[7]	Xiong Xiaoyun,Wei Zhaocheng,Wang Jiujiang,Gao Xionghou,Zhao Hongjuan,Hu Qingxun. Effect of synthesizing conditions on NaY zeolite prepared by in-situ crystallization from kaolin microspheres [J]. Inorganic Chemicals Industry, 2020, 52(1): 99-102.
[8]	Chang Jun,Jia Fukang,Hu Chengshan,Ye Qianxu. Adsorption of manganese ion by zeolite synthesized from electrolytic manganese residue [J]. Inorganic Chemicals Industry, 2019, 51(9): 61-66.
[9]	Xu Yuansheng,Li Jianwei,Ma Yan,Li Guowang,Zhang Maoliang,Shan Xueqiang. Study on preparation and property of CdS-TiO₂/zeolite composite catalysts [J]. Inorganic Chemicals Industry, 2019, 51(6): 83-87.
[10]	Wang Shuo,Bai Liming. Preparation and application of yttrium-deposited TiO₂-SBA-15 nano-catalyst [J]. Inorganic Chemicals Industry, 2019, 51(3): 77-81.
[11]	Fu Xin. Hydrothermal synthesis of TiO2 nanoparticles and photoluminescence properties thereof [J]. Inorganic Chemicals Industry, 2019, 51(10): 32-35.
[12]	HAN Yu, LIU Hong-Guang, PEI Ren-Yan, NIU Lin, ZHANG Yao-Ri, HUO Zhi-Ping, ZANG Jia-Zhong. Cheap and rapid synthesis of SSZ-13 zeolite with dual templates [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(9): 36-.
[13]	WANG Hong-Lei, XU Xue-Tang, WANG Fan. Transition metal cation doped Mn3O4 nanocatalysts [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(9): 79-.
[14]	LIU Ming-Hui, WEI Zhen-Hao, ZHOU Zhuo, ZHU Xue-Dong. Effect of alkali treatment on in-situ synthesis of ZSM-5 zeolite on calcined kaolin microspheres [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(7): 68-.
[15]	WANG Dong-Zhen, LIANG Sheng-Rong, SHEN Zhi-Bing, CUI Sheng-Hang. Synthesis and application progress of ZSM-5 molecular sieves [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(5): 1-.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Synthesis of hierarchical β zeolite by bisphenol A epoxy-resin as premade rigid template

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10