Inorganic Chemicals Industry ›› 2024, Vol. 56 ›› Issue (4): 1-7.doi: 10.19964/j.issn.1006-4990.2023-0481
• Reviews and Special Topics • Next Articles
YANG Yousheng(), YAO Zhihao, ZHAO Zhixing, FENG Xia, ZENG Ying, YU Xudong()
Received:
2023-10-09
Online:
2024-04-10
Published:
2024-04-18
Contact:
YU Xudong
E-mail:yangyoushengc413@126.com;xwdlyxd@126.com
CLC Number:
YANG Yousheng, YAO Zhihao, ZHAO Zhixing, FENG Xia, ZENG Ying, YU Xudong. Research progress of lithium-rich sulfate type salt lake brine evaporation experiment[J]. Inorganic Chemicals Industry, 2024, 56(4): 1-7.
Table 1
Names and chemical formulae of main precipitating salts of sulfate-type salt lakes"
序号 | 矿物名称 | 简称 | 化学式 | 序号 | 矿物名称 | 简称 | 化学式 |
---|---|---|---|---|---|---|---|
1 | 芒硝 | Mir | Na2SO4·10H2O | 11 | 钾盐镁矾 | Kai | KCl·MgSO4·3H2O |
2 | 硼砂 | Bor | Na2B4O7·10H2O | 12 | 泻利盐 | Eps | MgSO4·7H2O |
3 | 钠硼解石 | Ule | NaCaB5O9·8H2O | 13 | 六水泻盐 | Hex | MgSO4·6H2O |
4 | 石盐 | Ha | NaCl | 14 | 五水泻盐 | Pt | MgSO4·5H2O |
5 | 五水碳酸镁 | Lan | MgCO3·5H2O | 15 | 四水泻盐 | Lh | MgSO4·4H2O |
6 | 白钠镁矾 | Ast | Na2SO4·MgSO4·4H2O | 16 | 光卤石 | Car | KCl·MgCl2·6H2O |
7 | 钾石盐 | Sy | KCl | 17 | 锂复盐1 | Db1 | Li2SO4·3Na2SO4·12H2O |
8 | 钾芒硝 | Gla | 3K2SO4·Na2SO4 | 18 | 锂复盐2 | Db2 | LiNaSO4 |
9 | 钾镁矾 | Leo | K2SO4·MgSO4·4H2O | 19 | 一水硫酸锂 | Ls | Li2SO4·H2O |
10 | 软钾镁矾 | Pic | K2SO4·MgSO4·6H2O | 20 | 水氯镁石 | Bis | MgCl2·6H2O |
Table 2
Compositions of typical lithium-rich sulfate type salt lake and main order of salt precipitation"
盐湖 类型 | 盐湖 | 蒸发 温度/ ℃ | w (Li+)/ % | w (Na+)/ % | w (K+)/ % | w (Mg2+)/ % | w (Cl-)/ % | w (SO42-)/ % | w (B4O72-)/ % | w (CO32-)/ % | 主要析盐顺序 | 备注 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
硫酸钠亚型 | 扎北 | 0[ | 0.03 | 1.60 | 0.24 | 0.11 | 1.35 | 2.11 | 0.32 | 0.17 | Mir→Bor→Lan→Ha+Gla→Sy→Ule+Car+Ls (wLi=0.19%)→Bor | 7月卤水 |
5[ | 0.03 | 2.27 | 0.29 | 0.07 | 1.41 | 2.33 | 0.72 | 0.17 | Mir→Bor→Lan→Ha→Sy→Gla→Db2(Li+:14.03 g/L) | 10月卤水 | ||
自然 蒸发[ | 0.03 | 1.55 | 0.29 | 0.12 | 1.39 | 2.02 | 0.28 | 0.16 | Bor→Mir→Lan→Db1(wLi=0.1%)→Ha+Ast+ Ule→Gla→Leo→ Bor→Sy+Ls(wLi=0.3%) | 7月卤水 | ||
拉果错 | 15[ | 0.02 | 1.47 | 0.20 | 0.08 | 1.09 | 2.19 | 0.22 | 0.23 | Mir→Bor→Ha→Db1(wLi=0.19%)→Gla→Bor | 5月卤水 | |
硫酸镁亚型 | 东台 | 25[ | 0.06 | 7.24 | 1.16 | 2.03 | 13.62 | 6.55 | 0.08 | — | Ha→Eps→Pic→Sy→Hex→Car+Kai→Ls(Li+: 9 g/L) | 夏季卤水 |
25[ | 0.03 | 5.81 | 0.57 | 1.03 | 12.26 | 0.28 | 0.17 | — | Mir→Ha→Sy→Eps→Hex+Car | 冬季卤水 | ||
西台 | 25[ | 0.01 | 7.07 | 0.58 | 1.94 | 15.16 | 2.59 | 0.12 | — | Ha→Eps→Sy→Car→Bis | 4月卤水 | |
25[ | 0.14 | 0.46 | 0.32 | 8.04 | 21.73 | 3.47 | 0.62 | — | Ha→Car→Bis→Lh→Ls(wLi=0.4%) | 9月析 钾卤水 | ||
25[ | 0.16 | 0.15 | 0.04 | 7.68 | 22.97 | 0.35 | 0.65 | — | Ha→Bis→Lh→Ls(wLi=0.55%) | 冷冻析 钾卤水 | ||
乌尤尼 | 25[ | 0.05 | 7.66 | 1.26 | 1.41 | 15.75 | 1.88 | 0.002 | Ha→Sy→Eps→Car+Hex→Bis+Ls(wLi=0.49%) | — |
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