抗污染陶瓷膜改性及其在处理含油污水中的应用

doi:10.19964/j.issn.1006-4990.2022-0653

Abstract

Abstract:

Ceramic membrane is one of the most promising methods to treat oily wastewater.Membrane fouling is an inevitable phenomenon in the treatment process，leading to increased energy consumption and reduced life.Therefore，it is very important to improve the antifouling of ceramic membrane in oily wastewater treatment.Firstly，various modification methods of ceramic membranes were summarized，and the properties of modified ceramic membranes were compared.In addition to the traditional sol-gel method and dip coating method，the atomic layer deposition method was also expected to be used for ceramic membrane modification in terms of controlling the thickness of the layer and adjusting the pore diameter.Enhancing surface hydrophilicity and surface charge were two of the most commonly used strategies to improve the performance of ceramic membranes for oily wastewater treatment.Nanometer metal oxides，such as TiO₂，ZrO₂，Fe₂O₃ and graphene oxide，were considered as potential candidates for ceramic membrane modification to improve flux and reduce pollution.Passive antifouling ceramic membranes，such as photocatalysis and charged ceramic membranes，showed potential in fouling control，oil interception and flux enhancement.Finally，the market scale and development trend of ceramic membrane were prospected.It was pointed out that the research and production of high-end anti pollution ceramic membrane should be accelerated to meet the requirements of more complex oily wastewater treatment，such as oilfield polymer containing wastewater，fracturing flowback fluid，etc.

Key words: ceramic membrane, antifouling, modification, oily wastewater

CLC Number:

TQ174.7

LI Yang, ZANG Yihua, YUAN Biao, SHENG Chunguang. Modification of antifouling ceramic membrane and its application of oily wastewater treatment[J]. Inorganic Chemicals Industry, 2023, 55(9): 33-42.

Figures/Tables 6

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Table 1

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References 84

1	ZHANG Sui， WANG Peng， FU Xiuzhu，et al.Sustainable water recovery from oily wastewater via forward osmosis-membrane distillation（FO-MD）［J］.Water Research，2014，52：112-121.
2	许小兵，李旭，杨旭，等.烧成温度对MgO-TiO₂复合无机陶瓷微滤膜支撑体性能的影响［J］.无机盐工业，2022，54（8）：85-89.
	XU Xiaobing， LI Xu， YANG Xu，et al.Effect of firing temperature on properties of MgO-TiO₂ composite inorganic ceramic microfilter membrane support［J］.Inorganic Chemicals Industry，2022，54（8）：85-89.
3	滕厚开，刘宗园，吴巍，等.功能陶瓷膜处理含聚采油污水技术研究［J］.无机盐工业，2016，48（12）：75-77.
	TENG Houkai， LIU Zongyuan， WU Wei，et al.Study on ceramic functional membrane treatment of wastewater containing polymer［J］.Inorganic Chemicals Industry，2016，48（12）：75-77.
4	张诗洋，单历元，廖松义，等.陶瓷膜在废水处理领域中的研究进展［J］.工业水处理，2021，41（4）：31-36.
	ZHANG Shiyang， SHAN Liyuan， LIAO Songyi，et al.Research progress of ceramic membrane in wastewater treatment［J］.Industrial Water Treatment，2021，41（4）：31-36.
5	GU Qilin， NG T C A， BAO Yueping，et al.Developing better ceramic membranes for water and wastewater Treatment：Where microstructure integrates with chemistry and functionalities［J］.Chemical Engineering Journal，2022，428：130456.
6	LI Chen， SUN Wenjun， LU Zedong，et al.Ceramic nanocomposite membranes and membrane fouling：A review［J］.Water Research，2020，175：115674.
7	MILLER D J， DREYER D R， BIELAWSKI C W，et al.Surface modification of water purification membranes［J］.Angewandte Chemie International Edition，2017，56（17）：4662-4711.
8	ZHOU Jianer， CHANG Qibing， WANG Yongqing，et al.Separation of stable oil-water emulsion by the hydrophilic nano-sized ZrO₂ modified Al₂O₃ microfiltration membrane［J］.Separation and Purification Technology，2010，75（3）：243-248.
9	CHANG Qibing， ZHOU Jianer， WANG Yongqing，et al.Application of ceramic microfiltration membrane modified by nano-TiO₂ coating in separation of a stable oil-in-water emulsion［J］.Journal of Membrane Science，2014，456：128-133.
10	CHEN Mingliang， SHANG Ran， SBERNA P M，et al.Highly permeable silicon carbide-alumina ultrafiltration membranes for oil-in-water filtration produced with low-pressure chemical vapor deposition［J］.Separation and Purification Technology，2020，253：117496.
11	VRIJENHOEK E M， HONG S， ELIMELECH M.Influence of membrane surface properties on initial rate of colloidal fouling of reverse osmosis and nanofiltration membranes［J］.Journal of Membrane Science，2001，188（1）：115-128.
12	GOLSHENAS A， SADEGHIAN Z， ASHRAFIZADEH S N.Performance evaluation of a ceramic-based photocatalytic membrane reactor for treatment of oily wastewater［J］.Journal of Water Process Engineering，2020，36：101186.
13	PARK H， KIM Y， AN B，et al.Characterization of natural organic matter treated by iron oxide nanoparticle incorporated ceramic membrane-ozonation process［J］.Water Research，2012，46（18）：5861-5870.
14	GENG Ping， CHEN Guohua.Magnéli Ti₄O₇ modified ceramic membrane for electrically-assisted filtration with antifouling property［J］.Journal of Membrane Science，2016，498：302-314.
15	MAO Hengyang， BU Jiawei， Xiaowei DA，et al.High-performance self-cleaning piezoelectric membrane integrated with in situ ultrasound for wastewater treatment［J］.Journal of the European Ceramic Society，2020，40（10）：3632-3641.
16	MAO Hengyang， BU Jiawei， QIU Minghui，et al.PZT/Ti composite piezoceramic membranes for liquid filtration：Fabrication and self-cleaning properties［J］.Journal of Membrane Science，2019，581：28-37.
17	NAIR B N， YAMAGUCHI T， OKUBO T，et al.Sol-gel synthesis of molecular sieving silica membranes［J］.Journal of Membrane Science，1997，135（2）：237-243.
18	李晓光，丁书强，卓锦德，等.溶胶-凝胶法制备陶瓷膜研究进展［J］.无机盐工业，2019，51（1）：7-11.
	LI Xiaoguang， DING Shuqiang，JOW J，et al.Preparation and development of ceramic membrane prepared by sol-gel process［J］.Inorganic Chemicals Industry，2019，51（1）：7-11.
19	HENCH L L， WEST J K.The sol-gel process［J］.Chemical Reviews，1990，90（1）：33-72.
20	AMIN S K， ROUSHDY M H， EL-SHERBINY S A，et al.An overview of production and development of ceramic membran- es［J］.2016，11：7708-7721.
21	CAI Yuanyuan， WANG Yi， CHEN Xianfu，et al.Modified colloidal sol-gel process for fabrication of titania nanofiltration membranes with organic additives［J］.Journal of Membrane Science，2015，476：432-441.
22	BAYAT A， MAHDAVI H R， KAZEMIMOGHADDAM M，et al.Preparation and characterization of γ-alumina ceramic ultrafiltration membranes for pretreatment of oily wastewater［J］.Desalination and Water Treatment，2016，57（51）：24322-24332.
23	XIA Changrong， ZHA Shaowu， YANG Weiguang，et al.Preparation of yttria stabilized zirconia membranes on porous substrates by a dip-coating process［J］.Solid State Ionics，2000，133（3/4）：287-294.
24	BARATI N， HUSEIN M M， AZAIEZ J.Modifying ceramic membranes with in situ grown iron oxide nanoparticles and their use for oily water treatment［J］.Journal of Membrane Science，2021，617：118641.
25	YANG Chao， ZHANG Guosheng， XU Nanping，et al.Preparation and application in oil-water separation of ZrO₂/α-Al₂O₃ MF membrane［J］.Journal of Membrane Science，1998，142（2）：235- 243.
26	REZAKAZEMI M， DASHTI A， HOSSEIN R H，et al.Fouling-resistant membranes for water reuse［J］.Environmental Chemistry Letters，2018，16（3）：715-763.
27	FAIBISH R S， COHEN Y.Fouling-resistant ceramic-supported polymer membranes for ultrafiltration of oil-in-water microemulsions［J］.Journal of Membrane Science，2001，185（2）：129-143.
28	李丹，刘冰，孙浩，等.硅烷分子接枝ASZ陶瓷膜处理水中苯酚的研究［J］.水处理技术，2020，46（2）：25-28，32.
	LI Dan， LIU Bing， SUN Hao，et al.Study on silanemolecular grafted alumina supported zirconia（ASZ） ceramic membrane for phenol removal from aqueous solution［J］.Technology of Water Treatment，2020，46（2）：25-28，32.
29	KRAJEWSKI S R， KUJAWSKI W， BUKOWSKA M，et al.Application of fluoroalkylsilanes（FAS） grafted ceramic membranes in membrane distillation process of NaCl solutions［J］.Journal of Membrane Science，2006，281（1/2）：253-259.
30	FAIBISH R S， COHEN Y.Fouling and rejection behavior of ceramic and polymer-modified ceramic membranes for ultrafiltration of oil-in-water emulsions and microemulsions［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2001，
	191（1/2）：27-40.
31	ATALLAH C， MORTAZAVI S， TREMBLAY A Y，et al.Surface-modified multi-lumen tubular membranes for SAGD-produced water treatment［J］.Energy & Fuels，2019，33（6）：5766-5776.
32	JOU J D， YOSHIDA W， COHEN Y.A novel ceramic-supported polymer membrane for pervaporation of dilute volatile organic compounds［J］.Journal of Membrane Science，1999，162（1/2）：269-284.
33	NADY N， FRANSSEN M C R， ZUILHOF H，et al.Modification methods for poly（arylsulfone） membranes：A mini-review focusing on surface modification［J］.Desalination，2011，275（1/2/3）：1-9.
34	VATANPOUR V， MADAENI S S， KHATAEE A R，et al.TiO₂ embedded mixed matrix PES nanocomposite membranes：Influence of different sizes and types of nanoparticles on antifouling and performance［J］.Desalination，2012，292：19-29.
35	AHMAD A L， MAJID M A， OOI B S.Functionalized PSf/SiO₂ nanocomposite membrane for oil-in-water emulsion separation［J］.Desalination，2011，268（1/2/3）：266-269.
36	JEONG B H， HOEK E M V， YAN Yushan，et al.Interfacial polymerization of thin film nanocomposites：A new concept for reverse osmosis membranes［J］.Journal of Membrane Science，2007，294（1/2）：1-7.
37	KIM E S， HWANG G， GAMAL EL-DIN M，et al.Development of nanosilver and multi-walled carbon nanotubes thin-film nanocomposite membrane for enhanced water treatment［J］.Journal of Membrane Science，2012，394/395：37-48.
38	LIU Ruochen， RAMAN A K Y， SHAIK I，et al.Inorganic microfiltration membranes incorporated with hydrophilic silica nanoparticles for oil-in-water emulsion separation［J］.Journal of Water Process Engineering，2018，26：124-130.
39	SURESH K， SRINU T， GHOSHAL A K，et al.Preparation and characterization of TiO₂ and γ-Al₂O₃ composite membranes for the separation of oil-in-water emulsions［J］.RSC Advances，2016，6（6）：4877-4888.
40	PAIMAN S H， RAHMAN M A， UCHIKOSHI T，et al. In situ growth of α-Fe₂O₃ on Al₂O₃/YSZ hollow fiber membrane for oily wastewater［J］.Separation and Purification Technology，2020，236：116250.
41	KHATIB S J， OYAMA S T.Silica membranes for hydrogen separation prepared by chemical vapor deposition（CVD）［J］.Separation and Purification Technology，2013，111：20-42.
42	ZHANG Xiaoliang， YAMADA H， SAITO T，et al.Development of hydrogen-selective triphenylmethoxysilane-derived silica membranes with tailored pore size by chemical vapor deposition［J］.Journal of Membrane Science，2016，499：28-35.
43	ZHANG Feng， SHI Zhenwu， CHEN Linsen，et al.Porous superhydrophobic and superoleophilic surfaces prepared by template assisted chemical vapor deposition［J］.Surface and Coatings Technology，2017，315：385-390.
44	CHEN Xinwei， HONG Liang， XU Yanfang，et al.Ceramic pore channels with inducted carbon nanotubes for removing oil from water［J］.ACS Applied Materials & Interfaces，2012，4（4）：1909-1918.
45	KUKLI K， SALMI E， JÕGIAAS T，et al.Atomic layer deposition of aluminum oxide on modified steel substrates［J］.Surface and Coatings Technology，2016，304：1-8.
46	LI Fengbin， LI Ling， LIAO Xingzhi，et al.Precise pore size tuning and surface modifications of polymeric membranes using the atomic layer deposition technique［J］.Journal of Membrane Science，2011，385/386：1-9.
47	LESKELÄ M， RITALA M.Atomic layer deposition chemistry：Recent developments and future challenges［J］.Angewandte Chemie International Edition，2003，42（45）：5548-5554.
48	LI Fengbin， YANG Yang， FAN Yiqun，et al.Modification of ceramic membranes for pore structure tailoring：The atomic layer deposition route［J］.Journal of Membrane Science，2012，397/398：17-23.
49	SHANG Ran， GOULAS A， TANG C Y，et al.Atmospheric pressure atomic layer deposition for tight ceramic nanofiltration membranes：Synthesis and application in water purification［J］.Journal of Membrane Science，2017，528：163-170.
50	ZHANG Qi， FAN Yiqun， XU Nanping.Effect of the surface properties on filtration performance of Al₂O₃-TiO₂ composite membrane［J］.Separation and Purification Technology，2009，66（2）：306-312.
51	ZHANG Wenxiang， LUO Jianquan， DING Luhui，et al.A review on flux decline control strategies in pressure-driven membrane processes［J］.Industrial & Engineering Chemistry Research，2015，54（11）：2843-2861.
52	LU Dongwei， ZHANG Tao， MA Jun.Ceramic membrane fouling during ultrafiltration of oil/water emulsions：Roles played by stabilization surfactants of oil droplets［J］.Environmental Science & Technology，2015，49（7）：4235-4244.
53	HE Can， VIDIC R D.Application of microfiltration for the treatment of marcellus shale flowback water：Influence of floc breakage on membrane fouling［J］.Journal of Membrane Science，2016，510：348-354.
54	ZHU Xiaoying， LOO H E， BAI Renbi.A novel membrane showing both hydrophilic and oleophobic surface properties and its non-fouling performances for potential water treatment applications［J］.Journal of Membrane Science，2013，436：47-56.
55	MARZOUK S S， NADDEO V， BANAT F，et al.Preparation of TiO₂/SiO₂ ceramic membranes via dip coating for the treatment of produced water［J］.Chemosphere，2021，273：129684.
56	LU Dongwei， ZHANG Tao， GUTIERREZ L，et al.Influence of surface properties of filtration-layer metal oxide on ceramic membrane fouling during ultrafiltration of oil/water emulsion［J］.Environmental Science & Technology，2016，50（9）：4668-4674.
57	CUI Jiaoying， ZHANG Xiongfu， LIU Haiou，et al.Preparation and application of zeolite/ceramic microfiltration membranes for treatment of oil contaminated water［J］.Journal of Membrane Science，2008，325（1）：420-426.
58	LEE J， CHAE H R， WON Y J，et al.Graphene oxide nanoplatelets composite membrane with hydrophilic and antifouling properties for wastewater treatment［J］.Journal of Membrane Science，2013，448：223-230.
59	HU Xuebing， YU Yun， ZHOU Jianer，et al.The improved oil/water separation performance of graphene oxide modified Al₂O₃ microfiltration membrane［J］.Journal of Membrane Science，2015，476：200-204.
60	LOU Yueyun， LIU Gongping， LIU Sainan，et al.A facile way to prepare ceramic-supported graphene oxide composite membrane via silane-graft modification［J］.Applied Surface Science，2014，307：631-637.
61	CHEN Ting， DUAN Ming， FANG Shenwen.Fabrication of novel superhydrophilic and underwater superoleophobic hierarchically structured ceramic membrane and its separation performance of oily wastewater［J］.Ceramics International，2016，42（7）：8604-8612.
62	ZHU Yuzhang， WANG Dong， JIANG Lei，et al.Recent progress in developing advanced membranes for emulsified oil/water separation［J］.NPG Asia Materials，2014，6（5）：e101.
63	WEI Yibin， QI Hong， GONG Xiao，et al.Specially wettable membranes for oil-water separation［J］.Advanced Materials Interfaces，2018，5（23）：1800576.
64	ZHANG Dawei， WANG Gang， ZHI Shudi，et al.Superhydrophilicity and underwater superoleophobicity TiO₂/Al₂O₃ composite membrane with ultra low oil adhesion for highly efficient oil-in-water emulsions separation［J］.Applied Surface Science，2018，458：157-165.
65	MAGUIRE-BOYLE S J， HUSEMAN J E， AINSCOUGH T J，et al.Superhydrophilic functionalization of microfiltration ceramic membranes enables separation of hydrocarbons from frac and produced water［J］.Scientific Reports，2017，7（1）：1-9.
66	DICKHOUT J M， MORENO J， BIESHEUVEL P M，et al.Produced water treatment by membranes：A review from a colloidal perspective［J］.Journal of Colloid and Interface Science，2017，487：523-534.
67	ATALLAH C， TREMBLAY A Y， MORTAZAVI S.Silane surface modified ceramic membranes for the treatment and recycling of SAGD produced water［J］.Journal of Petroleum Science and Engineering，2017，157：349-358.
68	CHEN Mingliang， HEIJMAN S G J， RIETVELD L C.State-of-the-art ceramic membranes for oily wastewater treatment：Modification and application［J］.Membranes，2021，11（11）：888.
69	AL-HARBI O A， MUJTABA KHAN M， ÖZGÜR C.Improving the performance of silica-based crossflow membranes by surface crystallization for treatment of oily wastewater［J］.Journal of the Australian Ceramic Society，2017，53（2）：883-894.
70	XU Man， XU Chenxi， RAKESH K P，et al.Hydrophilic SiC hollow fiber membranes for low fouling separation of oil-in-water emulsions with high flux［J］.RSC Advances，2020，10（8）：4832-4839.
71	ABADIKHAH H， ZOU Caineng， HAO Youzhi，et al.Application of asymmetric Si₃N₄ hollow fiber membrane for cross-flow microfiltration of oily waste water［J］.Journal of the European Ceramic Society，2018，38（13）：4384-4394.
72	JIAO Kai， YU Xiangtao， YUAN Zhangfu，et al.Enhanced filtration performance of Al₂O₃-SiC porous ceramic composite tube depending on microstructure and surface properties［J］.Desalination and Water Treatment，2019，150：99-104.
73	MOZIA S.Photocatalytic membrane reactors（PMRs） in water and wastewater treatment.A review［J］.Separation and Purification Technology，2010，73（2）：71-91.
74	李昆，辛佳期，丁梓尧，等.光催化剂表面修饰陶瓷超滤膜的抗污染性能［J］.南昌大学学报（理科版），2021，45（5）：485-493.
	LI Kun， XIN Jiaqi， DING Ziyao，et al.Anti-fouling properties and performance of ceramic membrane modified by photocatalyst-supported montmorillonite［J］.Journal of Nanchang University （Natural Science），2021，45（5）：485-493.
75	AZMI N F A N， ABDULLAH N， PAUZI M Z M，et al.Highly permeable photo-catalytic mesoporous aluminum oxide membrane for oil emulsion separation［J］.Journal of the Australian Ceramic Society，2019，55（2）：323-335.
76	ALIAS N H， JAAFAR J， SAMITSU S，et al.Photocatalytic nanofiber-coated alumina hollow fiber membranes for highly efficient oilfield produced water treatment［J］.Chemical Engineering Journal，2019，360：1437-1446.
77	卜佳伟，毛恒洋，邱鸣慧，等.高通量自清洁多孔PZT压电陶瓷膜的制备［J］.膜科学与技术，2020，40（1）：72-77.
	BU Jiawei， MAO Hengyang， QIU Minghui，et al.Preparation of high permeability self-cleaning PZT piezoelectric ceramic membrane［J］.Membrane Science and Technology，2020，40（1）：72-77.
78	MAO Hengyang， QIU Minghui， BU Jiawei，et al.Self-cleaning piezoelectric membrane for oil-in-water separation［J］.ACS Applied Materials & Interfaces，2018，10（21）：18093-18103.
79	FAN Xinfei， ZHAO Huimin， LIU Yanming，et al.Enhanced permeability，selectivity，and antifouling ability of CNTs/Al₂O₃ membrane under electrochemical assistance［J］.Environmental Science & Technology，2015，49（4）：2293-2300.
80	MANTEL T， JACKI E， ERNST M.Electrosorptive removal of organic water constituents by positively charged electrically conductive UF membranes［J］.Water Research，2021，201：117318.
81	YANG Yang， LI Jianxin， WANG Hong，et al.An electrocatalytic membrane reactor with self-cleaning function for industrial wastewater treatment［J］.Angewandte Chemie International Edition，2011，50（9）：2148-2150.
82	YANG Bin， GENG Ping， CHEN Guohua.One-dimensional structured IrO₂ nanorods modified membrane for electrochemical anti-fouling in filtration of oily wastewater［J］.Separation and Purification Technology，2015，156：931-941.
83	张超，樊震坤，杨东亮，等.无机陶瓷膜技术优势及市场分析［J］.山东陶瓷，2016，39（6）：6-9.
	ZHANG Chao， FAN Zhenkun， YANG Dongliang，et al.Advantages and market analysis of inorganic ceramic membrane technology［J］.Shandong Ceramics，2016，39（6）：6-9.
84	湖南贝哲斯信息咨询有限公司.2022年全球陶瓷膜行业市场趋势报告［R/OL］.（2022-2-05）［2022-2-25］..

改性方法	膜厚	适用材料	优点	缺点
溶胶-凝胶^［21-22］	0.05~4 μm	γ-Al₂O₃、ZrO₂、TiO₂或其混合物	孔径分布窄、组分简单、易于规模化生产	易产生缺陷、颗粒易聚集
浸凃^［25］	0.1~100 μm	绝大多数无机材料	工艺简单	易产生缺陷，厚度较厚
表面接枝^［33］	—	有机硅材料	膜厚可控、化学性质可调	应用范围窄
掺杂^［50］	—	绝大多数无机材料	工艺简单、成本低	膜孔径较大，仅适用于超滤膜和微滤膜
水热^［40］	1~10 μm	金属氧化物	工艺简单	合成时间长、能耗高
CVD^{［10，43-44］}	4 nm~10 μm	绝大多数材料	膜层均匀性好、缺陷少	运行温度高、成本高
ALD^［45-49］	≤10 nm	绝大多数材料	膜层均匀性好、缺陷少、厚度薄、沉积温度低（相比于CVD）	成本高、难以规模化生产

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Inorganic Acid-Base-Salt Committee of CIESC

Modification of antifouling ceramic membrane and its application of oily wastewater treatment

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