基于氧化铁/生物质碳复合材料的高性能超级电容器研究

doi:10.19964/j.issn.1006-4990.2021-0352

Abstract

Abstract:

To improve the low specific capacitance of carbon materials as well as the poor electrical conductivity and low cyclic stability of ferric oxide（Fe₂O₃）,Fe₂O₃ was used to modify the surface of biomass-derived carbon to prepare Fe₂O₃/bio-mass carbon composites,which achieved higher specific capacitance and better stability by the synergistic effect of Fe₂O₃ and biomass-derived carbon.The samples were characterized by scanning electron microscopy（SEM）、X-ray photoelectron spec-troscopy（XPS） and Raman spectra.The results demonstrated that the prepared composites had a certain pore struc-ture,with Fe₂O₃ nanoparticles anchored on the carbon surface.When the mass ratio of Fe₂O₃ and biomass-derived carbon was 1:1,the prepared composites possessed the best electrochemical performance,showing a high specific capacitance of 430.8 F/g（1.0 A/g） in 3.0 mol/L KOH.The capacitance retention was still greater than 60% when the current density was increased by 20 times.The asymmetric supercapacitor constructed by using it as the negative electrode had a high voltage window（0~1.6 V） and achieved a high energy density of 39.1 W·h/kg.While,it also exhibited excellent cycling stability with 111% capacitance retention after 5 000 cycles at 10 A/g.

Key words: biomass, Fe₂O₃, composite materials, specific capacitance, supercapacitor

CLC Number:

WANG Dian,SU Qiong,PANG Shaofeng,CAO Shijun,KANG Lihui,LIANG Lichun,WANG Yanbin,LI Zhaoxia. Study on high-performance supercapacitors based on Fe₂O₃/biomass carbon composites[J]. Inorganic Chemicals Industry, 2022, 54(3): 59-65.

Figures/Tables 7

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References 31

[1]	DINH K N, LIANG Q, DU C F, et al. Nanostructured metallic transi-tion metal carbides,nitrides,phosphides,and borides for energy sto-rage and conversion[J]. Nano Today, 2019, 25:99-121. doi: 10.1016/j.nantod.2019.02.008
[2]	MURALEEGOPI C V V, VINODH R, SAMBASIVAM S, et al. Rec-ent progress of advanced energy storage materials for flexible and wearable supercapacitor:From design and development to applicat-ions[J]. Journal of Energy Storage, 2020, 27.Doi: 10.1016/j.est.2019.101035. doi: 10.1016/j.est.2019.101035
[3]	SETHURAMAN B, PURUSHOTHAMAN K K, MURALIDHARAN G. Synjournal of mesh-like Fe₂O₃/C nanocomposite via greener route for high performance supercapacitors[J]. RSC Advances, 2014, 4(9):4631-4637. doi: 10.1039/C3RA45025B
[4]	SHENG L, JIANG L, WEI T, et al. Spatial charge storage within ho-neycomb-carbon frameworks for ultrafast supercapacitors with high energy and power densities[J]. Advanced Energy Materials, 2017, 7(19).Doi: 10.1002/aenm.201700668. doi: 10.1002/aenm.201700668
[5]	PAN Z, ZHONG J, ZHANG Q, et al. Ultrafast all-solid-state coaxial asymmetric fiber supercapacitors with a high volumetric energy den-sity[J]. Advanced Energy Materials, 2018, 8(14).Doi: 10.1002/aenm.201702946. doi: 10.1002/aenm.201702946
[6]	HAN J, HIRATA A, DU J, et al. Intercalation pseudocapacitance of amorphous titanium dioxide@nanoporous graphene for high-rate and large-capacity energy storage[J]. Nano Energy, 2018, 49:354-362. doi: 10.1016/j.nanoen.2018.04.063
[7]	LI Y, ZHANG H, WANG S, et al. Facile low-temperature synjournal of hematite quantum dots anchored on a three-dimensional ultra-po-rous graphene-like framework as advanced anode materials for asy-mmetric supercapacitors[J]. Journal of Materials Chemistry A, 2016, 4(29):11247-11255. doi: 10.1039/C6TA02927B
[8]	JI W, JI J, CUI X, et al. Polypyrrole encapsulation on flower-like po-rous NiO for advanced high-performance supercapacitors[J]. Che-mical Communications, 2015, 51(36):7669-7672.
[9]	HAO J, PENG S, LI H, et al. A low crystallinity oxygen-vacancy-rich Co₃O₄ cathode for high-performance flexible asymmetric supercapa-citors[J]. Journal of Materials Chemistry A, 2018, 6(33):16094-16100. doi: 10.1039/C8TA06349D
[10]	何启贤, 袁学韬. 基于纳米片状二氧化锰的柔性固态超级电容的性能研究[J]. 无机盐工业, 2018, 50(2):43-45.
[11]	QI Z, YOUNIS A, CHU D, et al. A facile and template-free one-pot synjournal of Mn₃O₄ nanostructures as electrochemical supercapaci-tors[J]. Nano-Micro Letters, 2016, 8(2):165-173. doi: 10.1007/s40820-015-0074-0
[12]	JIA H, WANG Z, LI C, et al. Designing oxygen bonding between reduced graphene oxide and multishelled Mn₃O₄ hollow spheres for enhanced performance of supercapacitors[J]. Journal of Materi-als Chemistry A, 2019, 7(12):6686-6694.
[13]	XU W, DAI S, LIU G, et al. CuO nanoflowers growing on carbon fiber fabric for flexible high-performance supercapacitors[J]. Elec-trochimica Acta, 2016, 203:1-8.
[14]	CHO E C, CHANG-JIAN C W, LEE K C, et al. Ternary composite based on homogeneous Ni(OH)₂ on graphene with Ag nanoparticles as nanospacers for efficient supercapacitor[J]. Chemical Engineer-ing Journal, 2018, 334:2058-2067.
[15]	ZHANG H, GAO Q, YANG K, et al. Solvothermally induced α-Fe₂O₃/graphene nanocomposites with ultrahigh capacitance and excellent rate capability for supercapacitors[J]. Journal of Materi-als Chemistry A, 2015, 3(44):22005-22011.
[16]	张硕嘉, 杨玉彬, 唐宇, 等. 高活性Fe₂O₃@Ni复合电极制备及电化学性能研究[J]. 无机盐工业, 2019, 51(7):24-27.
[17]	HE T, TU M, ZHANG J, et al. Nanoparticles of iron nitride encaps-ulated in nitrogen-doped carbon bulk derived from polyaniline/Fe₂O₃ blends and its electrochemical performance[J]. Particle & Particle Systems Characterization, 2020, 37(7).Doi: 10.1002/ppsc.202000132. doi: 10.1002/ppsc.202000132
[18]	FU C, MAHADEVEGOWDA A, GRANT P S. Production of hollow and porous Fe₂O₃ from industrial mill scale and its potential for large-scale electrochemical energy storage applications[J]. Journal of Materials Chemistry A, 2016, 4(7):2597-2604. doi: 10.1039/C5TA09141A
[19]	HUANG X, YU H, CHEN J, et al. Ultrahigh rate capabilities of li-thium-ion batteries from 3D ordered hierarchically porous electro-des with entrapped active nanoparticles configuration[J]. Advan-ced Materials, 2014, 26(8):1296-1303.
[20]	CHEN J, XU J, ZHOU S, et al. Template-grown graphene/porous Fe₂O₃ nanocomposite：A high-performance anode material for pseu-docapacitors[J]. Nano Energy, 2015, 15:719-728. doi: 10.1016/j.nanoen.2015.05.021
[21]	FANG K, CHEN J, ZHOU X, et al. Decorating biomass-derived po-rous carbon with Fe₂O₃ ultrathin film for high-performance super-capacitors[J]. Electrochimica Acta, 2018, 261:198-205. doi: 10.1016/j.electacta.2017.12.140
[22]	ZHAO P, WANG N, HU W, et al. Anode electrodeposition of 3D mesoporous Fe₂O₃ nanosheets on carbon fabric for flexible solid-state asymmetric supercapacitor[J]. Ceramics International, 2019, 45(8):10420-10428. doi: 10.1016/j.ceramint.2019.02.101
[23]	SONG Z, LIU W, WEI W, et al. Preparation and electrochemical properties of Fe₂O₃/reduced graphene oxide aerogel(Fe₂O₃/rGOA) composites for supercapacitors[J]. Journal of Alloys and Compo-unds, 2016, 685:355-363.
[24]	SHAN D, YANG J, LIU W, et al. Biomass-derived three-dimensio-nal honeycomb-like hierarchical structured carbon for ultrahigh energy density asymmetric supercapacitors[J]. Journal of Materi-als Chemistry A, 2016, 4(35):13589-13602.
[25]	LI P, XIE H, WANG X, et al. Sustainable production of nano α-Fe₂O₃/N-doped biochar hybrid nanosheets for supercapacitors[J]. Sustainable Energy & Fuels, 2020, 4(9):4522-4530.
[26]	WANG Y, SHEN C, NIU L, et al. Hydrothermal synjournal of CuCo₂O₄/CuO nanowire arrays and RGO/Fe₂O₃ composites for high-perfor-mance aqueous asymmetric supercapacitors[J]. Journal of Materi-als Chemistry A, 2016, 4(25):9977-9985.
[27]	DONG T, DENG T, CHU X, et al. Carbon intermediate boosted Fe-ZIF derived alpha-Fe₂O₃ as a high-performance negative electrode for supercapacitors[J]. Nanotechnology, 2020, 31(13).Doi: 10.1088/1361-6528/ab5baf. doi: 10.1088/1361-6528/ab5baf
[28]	DESHMUKH P R, SOHN Y, SHIN W G. Electrochemical perfor-mance of facile developed aqueous asymmetric(Fe,Cr)₂O₃//MnO₂ supercapacitor[J]. Electrochimica Acta, 2018, 285:381-392. doi: 10.1016/j.electacta.2018.07.197
[29]	LI Y, KANG L, BAI G, et al. Solvothermal synjournal of Fe₂O₃ loaded activated carbon as electrode materials for high-performance elec-trochemical Capacitors[J]. Electrochimica Acta, 2014, 134:67-75. doi: 10.1016/j.electacta.2014.04.094
[30]	ZHANG S, YIN B, WANG Z, et al. Super long-life all solid-state asymmetric supercapacitor based on NiO nanosheets and α-Fe₂O₃ nanorods[J]. Chemical Engineering Journal, 2016, 306:193-203. doi: 10.1016/j.cej.2016.07.057
[31]	KARTHIKEYAN K, AMARESH S, LEE S N, et al. Fluorine-doped Fe₂O₃ as high energy density electroactive material for hybrid su-percapacitor applications[J]. Chemistry:An Asian Journal, 2014, 9(3):852-857. doi: 10.1002/asia.v9.3

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Study on high-performance supercapacitors based on Fe₂O₃/biomass carbon composites

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