磷酸锰锂锂离子电池正极材料研究进展

doi:10.19964/j.issn.1006-4990.2020-0540

Abstract

Abstract:

Lithium ion battery（LIB） is considered as the best choice for power battery because of its advantages such as high working voltage and energy density,long cycle life,no memory effect and small self-discharge.Lithium manganese phosphate（LiMnPO₄,LMP） is a promising cathode material for lithium-ion batteries,which has good thermal stability and high operating voltage,but still need to overcome some technical bottlenecks such as insufficient conductivity and poor cycling stability.In order to improve the electrochemical performance of LMP,LMP with uniform particle size and controllable morphology can be prepared by liquid phase method,which can effectively shorten the transmission distance of Li⁺,fully alleviate the problem of excessive stress at the phase interface in the process of charging and discharging.It is conducive to improve the rate perfor-mance and cyclic stability.Bulk phase doping has unique advantages in improving intrinsic conductivity,Li⁺ diffusion coefficient and stabilizing material structure,among which Fe doping has important research significance.In addition,improving the synthesis process to prepare composite cathode materials with specific structure and specific element distribution has signi-ficant advantages to improve the comprehensive performance of the materials.The research progress of the modification of LMP in the aspects of material nanocrity,ion doping and material composite in recent years was summarized systematically.It was considered that the development of nano-LiFe_xMn_1-_xPO₄（0<x<0.5） composites would become a new development trend.

Key words: lithium manganese（Ⅱ） phosphate, cathode materials, electrochemical performance, bulk doping, surface Modification

CLC Number:

TQ131.11

Jian Mengqi,Zhang Kun,Xie Xin,Chen Xiyong. Research progress of LiMnPO₄ cathode material for lithium ion batteries[J]. Inorganic Chemicals Industry, 2021, 53(9): 18-23.

Figures/Tables 3

References 44

[1]	Shi Ming, Li Ruiwen, Liu Yulin. In situ preparation of LiFePO₄/C with unique copolymer carbon resource for superior performance li-thium-ion batteries[J]. Journal of Alloys and Compounds, 2021, 854.Doi: 10.1016/j.jallcom.2020.157162. doi: 10.1016/j.jallcom.2020.157162
[2]	Li Jiwen, Liu Yong, Yao Wenli, et al. Li₂TiO₃ and Li₂ZrO₃ co-modi-fication LiNi_0.8Co_0.1Mn_0.1O₂ cathode material with improved high volt-age cycling performance for lithium-ion batteries[J]. Solid State Io-nics, 2020, 349.Doi: 10.1016/j.ssi.2020.115292. doi: 10.1016/j.ssi.2020.115292
[3]	Padhi A K, Nanjundaswamy K S, Goodenough J B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J]. Journal of the Electrochemical Society, 1997, 144(4):1188-1192. doi: 10.1149/1.1837571
[4]	Li Yong, Wang Juan, Yao Jia, et al. Enhanced cathode performance of LiFePO₄/C composite by novel reaction of ethylene glycol with different carboxylic acids[J]. Materials Chemistry and Physics, 2019, 224:293-300. doi: 10.1016/j.matchemphys.2018.12.042
[5]	Kirsanova Maria A, Ryazantsev Sergey V, Abakumov Artem M. An-ionic substitution in LiMnPO₄:The Li₁-_xMn₁+_x(PO₄)₁-_y-_z(VO₄)₄_z(OH)₄ solid solutions prepared with a microwave-assisted hydrothermal method[J]. Journal of Solid State Chemistry, 2020, 286.Doi: 10.1016/j.jssc.2020.121294. doi: 10.1016/j.jssc.2020.121294
[6]	李卫, 田文怀, 鲁其. 锂离子电池正极材料技术研究进展[J]. 无机盐工业, 2015, 47(6):1-5.
[7]	Ragupathi Veena, Panigrahi Puspamitra, Nagarajan Ganapathi Subramaniam. Enhanced electrochemical performance of nanopyramid-like LiMnPO₄/C cathode for lithium-ion batteries[J]. Applied Surface Science, 2019, 495.Doi: 10.1016/j.apsusc.2019.143541. doi: 10.1016/j.apsusc.2019.143541
[8]	Alsamet Mohammed A M M, Burgaz Engin. Synjournal and charac-terization of nano-sized LiFePO₄ by using consecutive combination of sol-gel and hydrothermal methods[J]. Electrochimica Acta, 2021, 367.Doi: 10.1016/j.electacta.2020.137530. doi: 10.1016/j.electacta.2020.137530
[9]	Li Rong, Fan Changling, Zhang Weihua, et al. Structure and perfor-mance of Na⁺ and Fe²⁺ co-doped Li_1-_xNa_xMn_0.8Fe_0.2PO₄/C nanocapsule synthesized by a simple solvothermal method for lithium ion batteries[J]. Ceramics International, 2019, 45(8):10501-10510. doi: 10.1016/j.ceramint.2019.02.112
[10]	Omidi Amir Hossein, Babaei Alireza, Ataie Abolghasem. Low temperature synjournal of nanostructured LiFePO₄/C cathode material for lithium ion batteries[J]. Materials Research Bulletin, 2020, 125. Doi: 10.1016/j.materresbull.2020.110807. doi: 10.1016/j.materresbull.2020.110807
[11]	Zhang Yingtang, Xin Pengyang, Yao Qiufeng. Electrochemical performance of LiFePO₄/C synthesized by sol-gel method as cathode for aqueous lithium ion batteries[J]. Journal of Alloys and Compounds, 2018, 741:404-408. doi: 10.1016/j.jallcom.2018.01.083
[12]	Guo H, Wu C, Liao L, et al. Performance improvement of lithium manganese phosphate by controllable morphology tailoring with acid-engaged nano engineering[J]. Inorganic Chemistry, 2015, 54(2):667-674. doi: 10.1021/ic5026075
[13]	Cao Yanbing, Xu Lian, Xie Xiaoming, et al. Controllable synjournal of micronano-structured LiMnPO₄/C cathode with hierarchical spindle for lithium ion batteries[J]. Ceramics International, 2019, 45(4):4886-4893. doi: 10.1016/j.ceramint.2018.11.186
[14]	Zhang Wenxuan, Shan Zhongqiang, Zhu Kunlei, et al. LiMnPO₄ nanoplates grown via a facile surfactant-mediated solvothermal reaction for high-performance Li-ion batteries[J]. Electrochimica Acta, 2015, 153:385-392. doi: 10.1016/j.electacta.2014.12.012
[15]	Zhu Chongjia, Wu Zhiqiu, Xie Jian, et al. Solvothermal-assisted morphology evolution of nanostructured LiMnPO₄ as high-perfor-mance lithium-ion batteries cathode[J]. Journal of Materials Science & Technology, 2018, 34(9):1544-1549.
[16]	Pan Xiaoliang, Zeng Yingying, Gao Zhi, et al. Effects of Li₂SO₄·H₂O amounts on morphologies of hydrothermal synthesized LiMnPO₄ cathodes[J]. RSC Advances, 2016, 105(6):103232-103237.
[17]	Li Junzhe, Luo Shaohua, Ding Xueyong, et al. NaCl-template assisted synjournal of 3D honeycomb-like LiMnPO₄/C with high rate and stable performance as lithium-ion battery cathodes[J]. ACS Sus-tainable Chemistry & Engineering, 2018, 12(6):16683-16691.
[18]	Pan Xiaoliang, Gao Zhi, Liu Lijun, et al. Self-templating preparation and electrochemical performance of LiMnPO₄ hollow microspheres[J]. Journal of Alloys and Compounds, 2019, 783:468-477. doi: 10.1016/j.jallcom.2018.12.348
[19]	El Khalfaouy Redouan, Addaou Abdellah, Laajeb Ali, et al. Synjournal and characterization of Na-substituted LiMnPO₄ as a cathode material for improved lithium ion batteries[J]. Journal of Alloys and Compounds, 2019, 775:836-844. doi: 10.1016/j.jallcom.2018.10.161
[20]	Ni Jiangfeng, Gao Lijun. Effect of copper doping on LiMnPO₄ prepared via hydrothermal route[J]. Journal of Power Sources, 2011, 196(15):6498-6501. doi: 10.1016/j.jpowsour.2011.03.073
[21]	Lv Xiaoyan, Huang Qiaoying, Wu Zhi, et al. Li_0.995Nb_0.005Mn_0.85Fe_0.15PO₄/C as a high-performance cathode material for lithium-ion batteries[J]. Journal of Solid State Electrochemistry, 2017, 21(5):1499-1507. doi: 10.1007/s10008-016-3495-x
[22]	Rajammal K, Sivakumar D, Duraisamy Navaneethan, et al. Na-do-ped LiMnPO₄ as an electrode material for enhanced lithium ion batteries[J]. Bulletin of Materials Science, 2017, 40(1):171-175. doi: 10.1007/s12034-017-1365-5
[23]	施立钦, 袁正勇, 彭振博. 氟掺杂磷酸锰锂正极材料的性能研究[J]. 电源技术, 2014, 38(8):1453-1455.
[24]	Clemens Oliver, Bauer Matthias, Haberkorn Robert, et al. Synjournal and characterization of vanadium-doped LiMnPO₄-compounds:LiMn(PO₄)_x(VO₄)₁-_x(0.8≤x≤1.0)[J]. Chemistry of Materials, 2012, 24(24):4717-4724. doi: 10.1021/cm303005d
[25]	Lei Z, Wang J, Yang J, et al. Nano-microhierarchical structured LiMn_0.85Fe_0.15PO₄ cathode material for advanced lithium ion battery[J]. ACS Appllied Materials & Interfaces, 2018, 10(50):43552-43560.
[26]	Dong Youzhong, Wang Long, Zhang Shouliang, et al. Two-phase interface in LiMnPO₄ nanoplates[J]. Journal of Power Sources, 2012, 215:116-121. doi: 10.1016/j.jpowsour.2012.03.077
[27]	Sronsri Chuchai, Boonchom Banjong. Thermal kinetic analysis of a complex process from a solid-state reaction by deconvolution procedure from a new calculation method and related thermodynamic functions of Mn_0.90Co_0.05-Mg_0.05HPO₄·3H₂O[J]. Transactions of Nonferrous Metals Society of China, 2018, 28(9):1887-1902. doi: 10.1016/S1003-6326(18)64834-4
[28]	Vásquez F A, Calderón J A. Vanadium doping of LiMnPO₄ cathode material:Correlation between changes in the material lattice and the enhancement of the electrochemical performance[J]. Electrochimica Acta, 2019, 325.Doi: 10.1016/j.electacta.2019.134930. doi: 10.1016/j.electacta.2019.134930
[29]	Yang Hao, Fu Cuimei, Sun Yijian, et al. Fe-doped LiMnPO₄@C nanofibers with high Li-ion diffusion coefficient[J]. Carbon, 2020, 158:102-109. doi: 10.1016/j.carbon.2019.11.067
[30]	Wang Ruijie, Zheng Jinyun, Feng Xiangming, et al. Highly[010]-oriented,gradient Co-doped LiMnPO₄ with enhanced cycling sta-bility as cathode for Li-ion batteries[J]. Journal of Solid State Electrochemistry, 2020, 24(3):511-519. doi: 10.1007/s10008-019-04485-1
[31]	El Khalfaouy Redouan, Turan Servet, Dermenci Kamil Burak, et al. Nickel-substituted LiMnPO₄/C olivine cathode material:Combustion synjournal,characterization and electrochemical performances[J]. Ceramics International, 2019, 45(14):17688-17695. doi: 10.1016/j.ceramint.2019.05.336
[32]	Luo Shaohua, Sun Yang, Bao Shuo, et al. Synjournal of Er-doped LiMnPO₄/C by a sol-assisted hydrothermal process with superior rate capability[J]. Journal of Electroanalytical Chemistry, 2019, 832:196-203. doi: 10.1016/j.jelechem.2018.10.062
[33]	Kou Liqin, Chen Fangjie, Tao Fen, et al. High rate capability and cycle performance of Ce-doped LiMnPO₄/C via an efficient solvo-thermal synjournal in water/diethylene glycol system[J]. Electrochi-mica Acta, 2015, 173:721-727.
[34]	Lee Jongwon, Park Minsik, Anass Benayad, et al. Electrochemical lithiation and delithiation of LiMnPO₄:Effect of cation substitu-tion[J]. Electrochimica Acta, 2010, 55(13):4162-4169. doi: 10.1016/j.electacta.2010.02.097
[35]	Zhang Hongliang, Gong Yang, Li Jie, et al. Selecting substituent elements for LiMnPO₄ cathode materials combined with density functional theory(DFT) calculations and experiments[J]. Journal of Alloys and Compounds, 2019, 793:360-368. doi: 10.1016/j.jallcom.2019.04.191
[36]	Deng Ziwei, Wang Qi, Peng Dachun, et al. Fast precipitation-indu-ced LiFe_0.5Mn_0.5PO₄/C nanorods with a fine size and large exposure of the(010) faces for high-performance lithium-ion batteries[J]. Journal of Alloys and Compounds, 2019, 794:178-185. doi: 10.1016/j.jallcom.2019.04.184
[37]	Hu Lingjun, Qiu Bao, Xia Yonggao, et al. Solvothermal synjournal of Fe-doping LiMnPO₄ nanomaterials for Li-ion batteries[J]. Journal of Power Sources, 2014, 248:246-252. doi: 10.1016/j.jpowsour.2013.09.048
[38]	Wang Yan, Yang Hao, Wu Chengyu, et al. Facile and controllable one-pot synjournal of nickel-doped LiMn_0.8Fe_0.2PO₄ nanosheets as high performance cathode materials for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2017, 5(35):18674-18683. doi: 10.1039/C7TA05942F
[39]	El Khalfaouy Redouan, Turan Servet, Rodriguez Miguel A, et al. Solution combustion synjournal and electrochemical properties of yttrium-doped LiMnPO₄/C cathode materials for lithium ion batte-ries[J]. Journal of Rare Earths, 2020, 38(9):976-982. doi: 10.1016/j.jre.2019.06.004
[40]	Gutierrez Arturo, Qiao Ruimin, Wang Liping, et al. High-capacity,aliovalently doped olivine LiMn_1-3_x_/2V_x□_x_/2PO₄ cathodes without carbon coating[J]. Chemistry of Materials, 2014, 26(9):3018-3026. doi: 10.1021/cm500924n
[41]	Nguyen Van Hiep, Lee Dong-Hee, Baek Sae-Yane, et al. Silicon and its effect on the electrochemical properties of Li₃V₂(PO₄)₃ cathode material[J]. Ceramics International, 2018, 44(11):12504-12510. doi: 10.1016/j.ceramint.2018.04.043
[42]	Wang Fei, Yang Jun, Nuli Yanna, et al. Composites of LiMnPO₄ with Li₃V₂(PO₄)₃ for cathode in lithium-ion battery[J]. Electrochimica Acta, 2013, 103:96-102. doi: 10.1016/j.electacta.2013.03.201
[43]	Zhang Zhijian, Hu Guorong, Cao Yanbing, et al. Enhanced electro-chemical performance of nano LiMnPO₄ with multifunctional surface co-coating of Li₂TiO₃ and carbon[J]. Solid State Ionics, 2015, 283:115-122. doi: 10.1016/j.ssi.2015.10.007
[44]	Xu Xiaoyue, Wang Tao, Bi Yujing, et al. Improvement of electro-chemical activity of LiMnPO₄ based cathode by surface iron enrichment[J]. Journal of Power Sources, 2017, 341:175-182. doi: 10.1016/j.jpowsour.2016.12.001

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Research progress of LiMnPO₄ cathode material for lithium ion batteries

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