无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2020, Vol. 52 ›› Issue (6): 8-12.doi: 10.11962/1006-4990.2019-0417

• 综述与专论 • 上一篇    下一篇

锂资源提取与回收及锂制备工艺研究现状

王冬斌,梁精龙,邓孝纯,王晶   

  1. 华北理工大学冶金与能源学院,现代冶金技术教育部重点实验室,河北唐山 063210
  • 收稿日期:2020-01-20 出版日期:2020-06-01 发布日期:2020-06-12
  • 作者简介:王冬斌(1994— ),男,硕士研究生,主要研究方向为固体废弃物资源再生;E-mail: wangdb_ncst@126.com
  • 基金资助:
    国家自然科学基金项目(51774143);河北省自然科学基金资助项目(E2016209163);河北省高等学校科学技术研究项目(BJ2017050)

Research status of extraction and recovery of lithium resources and preparation process of lithium

Wang Dongbin,Liang Jinglong,Deng Xiaochun,Wang Jing   

  1. Key Laboratory of Modern Metallurgy Technology of Ministry of Education,College of Metallurgy and Energy,North China University of Science and Technology,Tangshan 063210,China
  • Received:2020-01-20 Online:2020-06-01 Published:2020-06-12

摘要:

随着锂电池市场需求的不断扩大,锂资源的提取与回收成为研究的热点。介绍了盐湖卤水提锂工艺中沉淀法和萃取法的研究进展。重点阐述了废旧锂离子电池正极材料回收锂资源的研究现状。介绍了金属锂的制备工艺,包括熔盐电解法和真空热还原法,其中真空热还原法包括硅热还原法、铝热还原法和铁热还原法。目前盐湖卤水萃取法提锂的工业化是需要解决的重点问题;废旧锂离子电池锂资源的绿色回收是当前研究的热点,在保证锂回收效率的同时尽量选用有机酸以减少污染,同时废旧锂离子电池的工业化回收前景广阔;真空热还原制备锂单质目前仍处于实验室研究阶段,连续化生产是研究的主要方向。

关键词: 锂资源提取, 废旧锂电池, 真空热还原, 锂资源回收

Abstract:

With the continuous expansion of the demand for lithium batteries,the extraction and recycling of lithium reso-urces has become a research hotspot.The research progress of precipitation and extraction methods in the lithium extraction process of salt lake brine was introduced,and the research status of lithium resources in the waste lithium ion battery cathode material was highlighted.The preparation process of metallic lithium,such as molten salt electrolysis method and vacuum thermal reduction method,was also introduced.Vacuum thermal reduction method included silicon thermal reduction method,aluminothermic reduction method and iron thermal reduction method.At present,the industrialization of salt lake brine extraction method is a key issue to be solved.The green recycling of waste lithium-ion batteries is a hot research topic.When ensuring the recovery efficiency,organic acids should be used as much as possible to reduce pollution.The industrial recycling of waste lithium-ion batteries has broad prospects.The vacuum thermal reduction method is still in the laboratory research stage and needs further research.The continuous production is the main researching direction.

Key words: lithium resource extraction, waste lithium battery, vacuum heat reduction, lithium resource recycling

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