无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (4): 42-.

• 论文 • 上一篇    下一篇

氯化亚铜团聚体的微观分散研究

严世成   

  1. 吉林工业职业技术学院,吉林吉林 132013
  • 出版日期:2014-04-10 发布日期:2014-04-08

Micro disperse research for cuprous chloride conglomeration

 YAN  Shi-Cheng   

  1. Jilin Vocational College,Jilin 132013,China
  • Published:2014-04-10 Online:2014-04-08

摘要: 用3种方法对氯化亚铜团聚体的微观分散进行了研究,目的是能以较小的代价破碎氯化亚铜团聚体,并将它们分散到硅粒表面即实现所谓的“微观分散”及探索实验中所用方法能否推广到流化床反应器的进料系统。实验中利用超声分散法、在氯化亚铜合成中加入分散剂及引入硅粉等方法,从而制得高分散性硅-铜触体。并对催化剂的活性进行了评价对比,得出在氯化亚铜合成中引入硅粉法为最佳方案,通过该工艺制得的硅-铜触体可作为大规模工业化生产有机硅单体的催化剂。

关键词: 氯化亚铜, 团聚, 分散

Abstract: The micro disperse for conglomeration of cuprous chloride was researched by 3 ways,with the purpose of destroying the aggregates of cuprous chloride at the least cost and dispersing them onto the surface of silicon particle,which was so called micro disperse,and also exploring the possibility whether the experimental method can be applied to the feeding system of the fluidized bed reactor.Silicon-copper contacts with high dispersion were prepared by using the methods,such as ultrasonic dispersion method,cuprous chloride synthesis method,and introduction of silicon powder etc..The activity of the catalysts was compared and evaluated.It was concluded that the method of introduction of silicon powder into cuprous chloride was the best way.The prepared silicon-copper contacts through this method can be used for catalyst in large-scale industrialized production of organosilicon monomer.

Key words: cuprous chloride, conglomeration, dispersion

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