无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (12): 27-.

• 论文 • 上一篇    下一篇

LSC-500螯合树脂脱除钙离子的工艺研究

谢英惠,赵 欣,袁俊生   

  1. 河北工业大学海水资源高效利用化工技术教育部工程研究中心,天津 300130
  • 出版日期:2013-12-10 发布日期:2013-12-09

Study on removal of calcium ions by chelating resin LSC-500

 XIE  Ying-Hui, ZHAO   Xin, YUAN  Jun-Sheng   

  1. Engineering Research Center of Seawater Utilization Technology,Ministry of Education,
    Hebei University of Technology,Tianjin 300130,China
  • Published:2013-12-10 Online:2013-12-09

摘要: 通过比较LSC-500、D152、D401、D418、001×7、001×14.5型6种离子交换树脂对钙离子的吸附效果,得出LSC-500螯合树脂对钙离子的吸附量最高,故选用LSC-500螯合树脂对富钾液中的钙离子进行静态吸附实验。实验结果表明:在25 ℃条件下,LSC-500树脂对钙离子的静态饱和吸附量为23.42 mg/g;实验得出的最佳吸附条件是反应时间为180 min、反应温度为65 ℃,在此条件下树脂对钙离子的脱除率达到92.86%。通过动力学实验,得出了树脂吸附钙离子的动力学曲线,并用液膜扩散模型和颗粒扩散模型对吸附动力学数据进行了拟合。动力学实验表明:温度升高有利于吸附过程的进行;液膜扩散是LSC-500树脂吸附钙离子的主要速控步骤。

关键词: 吸附, LSC-500螯合树脂, 钙离子, 动力学

Abstract: Due to the largest adsorption capacity to calcium ions,chelating resin LSC-500 was chosen as the optimum adsorbent after comparing with D152,D401,D418,001×7, and 001×14.5 resins.The static adsorption experiments were carried out to absorb calcium ions in the potassium?鄄rich solution.Experiment results showed that the saturated adsorption capacity of calcium ion was found to be 23.42 mg/g at 25 ℃.The optimum conditions for removing Ca2+ were:the reaction time was 180 min and the adsorption temperature was 65 ℃.Under the conditions,the removal rate of calcium ions with LSC-500 resin was 92.86%.Through the dynamic experiment, kinetic curve of resin absorbing calcium ions was obtained,and the absorption kinetics data were fitted by liquid film diffusion model and intra-particle diffusion model respectively.Dynamic experiment results showed that increasing temperature was good for the adsorption process,and the liquid film diffusion was the main rate-control step of absorbing calcium ions by chelating resin LSC-500.

Key words: adsorption, chelating resin LSC-500, calcium ion, kinetics

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