无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (9): 68-.

• 论文 • 上一篇    下一篇

低成本制备纳米氧化锌工艺条件研究

徐素鹏,汤长青,李晓乐,苏小莉,许银霞   

  1. 济源职业技术学院,河南济源 459000
  • 出版日期:2016-09-10 发布日期:2016-09-18

Study on process conditions of low cost preparation of nanometer zinc oxide

 XU  Su-Peng, TANG  Chang-Qing, LI  Xiao-Le, SU  Xiao-Li, XU  Yin-Xia   

  1. Jiyuan Vocational and Technical College,Jiyuan 459000,China
  • Online:2016-09-10 Published:2016-09-18

摘要: 以氯化锌和碳酸钠为原料,通过均匀沉淀法制备纳米氧化锌。借助激光粒度分析仪及透射电镜等分析手段,探索制备工艺条件对纳米氧化锌粒径及形貌的影响规律。最佳工艺条件:锌离子(Zn2+)初始浓度为0.74 mol/L,碳酸根与锌离子浓度比[c(CO32-)/c(Zn2+)]为1.1,反应温度为90 ℃,反应时间为40 min,煅烧温度为600 ℃,煅烧时间为1 h。在此条件下制备纳米氧化锌颗粒形貌为球形,粒度均匀,粒径约为25 nm,二次粒径(D50)为549.9 nm,分散性好。该工艺条件为低成本工业化制备纳米氧化锌提供了基础数据。

关键词: 纳米氧化锌, 形貌, 二次粒径, 工艺条件

Abstract: Nanometer zinc oxide was synthesized by the homogeneous precipitation method from zinc chloride and sodium carbonate.The affecting law of preparation conditions on nanometer zinc oxide particle size and morphology was investigated by laser particle size analyzer and TEM etc..The optimum process conditions were found as follows:the initial Zn2+ concentra- tion was 0.74 mol/L,c(CO32-)/c(Zn2+)=1.1,the reaction time was 40 min,the reaction temperature was 90 ℃,the calcina- tion temperature was 600 ℃,and the calcination time was 1 h.Under these conditions nanometer zinc oxide had spherical morphologies,uniform granularity,and good dispersivity with particles size of 25 nm and second particle size(D50) of 549.9  nm.The study results can provide basic data for studying team to industrially produce nanometer zinc oxide in low cost.

Key words: nanometer zinc oxide, morphology, second particle size, process conditions

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