无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (6): 67-.

• 论文 • 上一篇    下一篇

两种不同结构锰酸锂电化学性能对比

张沿江,武行兵,姜雨恒   

  1. 合肥国轩高科动力能源有限公司,安徽合肥 230011
  • 出版日期:2016-06-10 发布日期:2016-06-02

Comparison of electrochemical properties of manganese lithium with two different structures

 ZHANG  Yan-Jiang, WU  Xing-Bing, JIANG  Yu-Heng   

  1. Hefei Guoxuan High-Tech Power Energy Co.,Ltd.,Hefei 230011,China
  • Online:2016-06-10 Published:2016-06-02

摘要: 比较了层状锰酸锂(LiMnO2)和尖晶石型锰酸锂(LiMn2O4)在电池容量发挥、首次效率、高温存储及循环性能等方面的差异。结果表明:层状锰酸锂具有较高的容量发挥,但其高温存储性能不如尖晶石型锰酸锂;在高温(55 ℃)循环性能方面,由于高温条件下锰的溶解,导致两种结构锰酸锂电池的高温循环性能均很差,0.5C循环 400次后容量保持率低于80%;在常温循环性能方面,尖晶石型锰酸锂具有较好的容量保持率。因此,在动力电池应用方面,尖晶石型锰酸锂相对于层状锰酸锂更具有优势。

关键词: 锰酸锂, 容量保持, 高温存储, 循环

Abstract: Layered LiMnO2 and spinel LiMn2O4 were compared on specific capacity,initial efficiency,storage at high tem-perature,and cycle performance.Results showed that the layered LiMnO2 had higher capacity,but its performance of storage at high temperature was not better than spinel LiMn2O4.On cyclic performance at high temperature,because manganese dissolved at high temperature,both layered LiMnO2 and spinel LiMn2O4 had bad performance,their capacity retention ratios were below 80% after 400 cycles at 0.5C.In respect of cycles at room temperature,the spinel LiMn2O4 had better capacity retention.Finally,on the using at power battery,spinel LiMn2O4 had better advantage than layered LiMnO2.

Key words: lithium manganate, capacity retention, storage at high temperature, cycle

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