无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (3): 59-.

• 论文 • 上一篇    下一篇

碳化法制备高比表面积白炭黑工艺研究

王苗捷1,郝雅娟2,杨恒权2,程芳琴1   

  1. 1.山西大学资源与环境工程研究所,国家环境保护煤炭废弃物资源化高效利用技术重点实验室,
    山西太原030006;2.山西大学化学化工学院
  • 出版日期:2016-03-10 发布日期:2016-03-11

Preparation technology of white carbon black with high specific surface area by carbonation

Wang Miaojie1,Hao Yajuan2,Yang Hengquan2,Cheng Fangqin1   

  1. 1.State Environmental Protection Key Laboratory of Efficient Utilization Technology of Coal Waste Resources,
    Institute of Resources and Environment Engineering,Shanxi University,Taiyuan 030006 China;
    2.College of Chemistry & Chemical Engineering,Shanxi University
  • Online:2016-03-10 Published:2016-03-11

摘要: 采用煤矸石制得的水玻璃为原料,通过二氧化碳碳化工艺制备出高比表面积的白炭黑。研究了工艺条件对白炭黑BET法比表面积及DBP吸收值的影响。研究结果表明,在水玻璃密度为1.074 5 g/mL、二氧化碳通气速率为80 mL/min、反应温度为80 ℃、乙醇浸泡10 h后常压干燥条件下,可得到比表面积为279.74 m2/g、DBP吸收值为 2.93 mL/g且分散性较好的白炭黑颗粒。

关键词: 水玻璃, 碳化法, 白炭黑, 比表面积

Abstract: The raw material was sodium silicate prepared by using coal gangue, and the white carbon black with high specific surface area was prepared by carbonation process.The effect of carbonation process conditions on the BET specific surface area and DBP absorption value of white carbon black were investigated.The conclusions showed that,the conditions of carbonation process were:the density of sodium silicate solution was 1.074 5 g/mL,CO2 flow rate was 80 mL/min,reaction temperature was 80 ℃,and drying at ambient pressure after ethanol soaking for 10 h.The specific surface area of 279.74 m2/g,DBP absorp- tion of 2.93 mL/g,and well dispersive of white carbon black particles were successfully prepared under these conditions.

Key words: sodium silicate, carbonation, white carbon black, specific surface area

中图分类号: