无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (1): 39-.

• 论文 • 上一篇    下一篇

磷酸法分解磷钾矿过程中钾硅分解率的研究

张光旭,彭 宇,张 平,李荣杰,石 瑞   

  1. 武汉理工大学化学工程学院,湖北武汉 430070
  • 出版日期:2015-01-10 发布日期:2015-01-14

Decomposition rate of potassium and silicon from low grade phosphate-potassium ore with phosphoric acid

 ZHANG  Guang-Xu, PENG   Yu, ZHANG   Ping, LI  Rong-Jie, SHI   Rui   

  1. School of Chemical Engineering and Technology,Wuhan University of Technology,Wuhan 430070,China
  • Online:2015-01-10 Published:2015-01-14

摘要: 针对四川雅安的低品位磷钾矿采用磷酸和某添加剂分解,分解残渣通过盐酸浸取溶出钾,考察了影响该体系钾、硅分解率的各种因素。得出较优工艺条件是:分解反应温度为250 ℃,反应时间为2 h,85%磷酸加入量为22.23 g,添加剂加入量为理论用量的1.2倍,浸取反应盐酸用量为95 mL。在此条件下,钾的分解率达到95%以上,硅的分解率达到91%以上。本法为低品位磷钾矿的综合利用奠定了一定基础。

关键词: 磷钾矿, 磷酸法, 盐酸, 分解率

Abstract: The decomposition of low grade of phosphate-potassium ore in Yaan,Sichuan was carried out by means of phosphoric acid and a kind of additive.Potassium was then dissolved out from the decomposition residue by leaching process of hydrochloric acid.The influence factors of decomposition rate of potassium and silicon were investigated.The optimum reaction conditions were considered to be 2 h of decomposition reaction at 250 ℃,with a 22.23 g of 85% phosphoric acid,the amount of additive was 120% of the theoretical amount,and the volume of hydrochloric acid in leaching process was 95 mL. The potassium decomposition rate can get above 95%,and the silicon decomposition rate can get above 91%.This method laid a certain foundation for the utilization of low grade of phosphate-potassium ore.

Key words: phosphate-potassium ore, phosphoric acid by wet-process, hydrochloric acid, decomposition rate

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