无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (5): 52-.

• 论文 • 上一篇    下一篇

纳米氧化锌的制备及光催化应用

董乾英,张保林,程 亮,戴启军,朱法厅,袁 琳   

  1. 郑州大学化工与能源学院,河南郑州 450001
  • 发布日期:2013-05-03

Preparation and photocatalytic applications of nanometer zinc oxide

DONG  Qian-Ying, ZHANG  Bao-Lin, CHENG   Liang, DAI  Qi-Jun, ZHU  Fa-Ting, YUAN   Lin   

  1. School of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou 450001,China
  • Online:2013-05-03

摘要: 以硫酸锌和碳酸钠为原料,采用液相沉淀法制备了平均粒径为60 nm的氧化锌,通过正交试验得出制备纳米氧化锌的最佳工艺条件。用激光粒度分析、热重分析(TG-DTA)、X射线衍射分析(XRD)及扫描电子显微镜(SEM)等物理手段对纳米氧化锌的粒径分布、热性能、晶形结构及微观形貌进行表征。结果表明:产品颗粒大小均匀,分散性较好,平均粒径为60 nm,前驱体的煅烧温度为400 ℃,形貌呈球形或类球形。纳米氧化锌作光催化剂对酸性品红和甲基橙进行光催化的实验表明:纳米氧化锌的光催化能力较强,对酸性品红和甲基橙的降解率分别为98.75%和92.37%。

关键词: 纳米氧化锌, 液相沉淀法, 光催化, 降解

Abstract: Zinc oxide(ZnO) with average particle size of 60 nm was prepared by liquid precipitation method with zinc sulfate and sodium carbonate as raw materials.The optimum technological conditions to prepare nanometer ZnO were obtained through orthogonal experiment.The particle size distribution,thermal performance,crystal shape structure,and micro-morphology were characterized by physical methods of laser particle size analysis,thermo-gravimetric analysis(TG-DTA),X-ray diffraction analysis(XRD),and scanning electron microscope(SEM).Results showed that: the grain size of the products was well-distributed with good dispersivity,and the average particle size was 60 nm;the precursor calcining temperature was 400 ℃,morphology was spherical or spherical-like.Photocatalytic experiments were made with nanometer ZnO as photochemical catalyst,for degradation of acidic magenta and methyl orange,and results showed that: the photocatalytic ability of nanometer ZnO was quite strong,and the degradation rates of acidic magenta and methyl orange were 98.75% and 92.37%, respectively.

Key words: Nanometer ZnO, Liquid precipitation, photocatalysis, degradation

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