无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (2): 45-.

• 论文 • 上一篇    下一篇

太阳能硅片切割废砂浆的分离及回收研究

杨荣华,赵传华,张春雪,杜金逢,程盼霞   

  1. 泰山医学院化工学院,山东泰安 271016
  • 出版日期:2013-02-10 发布日期:2013-02-21

Research on separation and recycling of waste mortar produced in solar silicon cutting

YANG  Rong-Hua, ZHAO  Chuan-Hua, ZHANG  Chun-Xue, DU  Jin-Feng, CHENG  Pan-Xia   

  1. School of Chemical Engineering,Taishan Medical University,Taian 271016,China
  • Online:2013-02-10 Published:2013-02-21

摘要: 以太阳能硅片切割废砂浆为原料,采用固液分离、酸溶和碱溶提纯等方法,除去废砂浆中的铁及不锈钢粉等杂质,回收聚乙二醇、硅和碳化硅微粉。结果表明,以水为溶剂,按液固体积质量比(mL/g)为10∶1、常温下搅拌10 min溶出废砂浆中的聚乙二醇,精馏回收;用盐酸处理废砂浆中铁及不锈钢粉的最佳工艺条件:c(盐酸)=3.0 mol/L、温度为40 ℃、反应时间为1 h、液固比为10∶1;采用酸溶和碱溶方法除硅,可使碳化硅微粉中硅的质量分数降到0.5%以下。

关键词: 废砂浆, 碳化硅, 硅, 聚乙二醇

Abstract: Impurities of iron and stainless steel powder etc. in the waste mortar produced in solar silicon cutting were removed and polyethylene glycol(PEG),silicon,and silicon carbide were recovered by liquid-solid separation,acid-dissolve,and alkali-dissolve depuration methods.Results indicated,using water as solvent,with liquid volume to solid mass ratio(mL/g) of 10∶1, stirring time of 10 min at room temperature,PEG in waste mortar could be dissolved and it could be recovered by the following distillation method;the optimal process conditions of removing iron and stainless steel powder with hydrochloric acid were: c(HCl)=3.0 mol/L, temperature was 40 ℃,reaction time was 1 h,and liquid/solid ratio was 10∶1;using acid-dissolve and alkali-dissolve methods to remove silicon,could make the mass fraction of silicon in silicon carbide powder drop to 0.5% below.

Key words: waster mortar, silicon carbide, silicon, polyethylene glycol

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