无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (2): 47-.

• 论文 • 上一篇    下一篇

低品位硫铁矿生产硫磺的工业实验研究

张跃1,扬守明2,王国良2,魏思敏1,幸典成1,张勇2,龚家竹3   

  1. 1.四川化工职业技术学院,四川泸州 646005;2.四川宏达集团;3.成都千砺金科技创新有限公司
  • 发布日期:2011-04-19

Industrial experimental study on production of sulfur with low-grade pyrite

Zhang Yue1,Yang Shouming2,Wang Guoliang2,Wei Simin1,Xing Diancheng1,Zhang Yong2,Gong Jiazhu3   

  1. 1.Sichuan College of Chemical Technology,Luzhou 646005,China;2.Sichuan Hongda Group Co.,Ltd.;3.Chengdu Challenge Technology Co.,Ltd.
  • Published:2011-04-19

摘要: 研究了低品位硫铁矿采用二段硫化床与劣质高硫煤还原反应生产硫磺的工艺过程。用低品位硫铁矿中的硫与铁资源和高硫煤中的煤与硫资源生产硫磺和还原铁粉,实现了资源的充分利用;克服了品位在17%~20%(质量分数,下同)的硫铁矿,在原矿选矿生产硫精砂工艺过程中产生的尾矿对环境造成污染的问题,弥补了硫精砂生产过程中的缺陷。中间实验产品硫磺达到GB/T 2449—2006《工业硫磺》国家标准,副产品铁矿粉含量高于60%,是用于炼钢厂的优质铁原料。该研究工艺使资源利用达到最大化,符合循环经济的法则,是弥补中国硫、铁资源短缺,多方法寻求资源来源的一种有效途径。

关键词:  , 低品位硫铁矿, 流化床, 高硫煤, 硫磺

Abstract: Technological process of producing sulfur by reduction reaction between low-grade pyrite and inferior high-sulfur coal in a two-stage fluidized bed was studied.Technology realized the effective utilization of resources,because it used the sulfur and iron resources in low-grade pyrite and the coal and sulfur resources in the high-sulfur coal to produce sulfur and reduced iron powder.It overcame the pollution problems of mine tailings generated from the production process of pyrite concentrate by flotation of 17%~20% pyrite (mass fraction) and it compensate the deficiency of pyrite concentrate production process.Sulfur product from the pilot plant reached the national standard GB/T 2449—2006 Sulphur for Industrial Use,and the by-product contained more than 60% (mass fraction) iron ore powder,which was an excellent raw material for steel-making.This research was in line with the circular economy law and maximized the utilization of resources.It was also an effective way to find resources and to make up China′s shortage of sulfur and iron resources. 

Key words: low-grade pyrite, fluidized bed, high-sulfur coal, sulfur

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