离子液体协同微通道调控纳米氢氧化镁的制备研究

doi:10.19964/j.issn.1006-4990.2024-0629

Abstract

Abstract:

Polymer materials are widely used，but their flammability poses safety concerns.Adding magnesium hydroxide flame retardants can enhance the flame retardancy of composite materials.This study was aimed to prepare nano-magnesium hydroxide with good dispersion，fine particle size and stable performance.Nano-magnesium hydroxide was prepared by using sodium hydroxide and magnesium sulfate as raw materials，with 1-butyl-3-methylimidazolium acrylate ionic liquid as a regulator in a microchannel reactor.The effects of ionic liquid addition amount，sodium-magnesium molar ratio，reaction temperature and injection rate on the particle size of magnesium hydroxide were investigated，and the products were characterized by laser particle size analyzer and other methods.The results showed that the optimal preparation process parameters were ionic liquid addition amount of 10 g/mol，sodium-magnesium molar ratio of 2.5，reaction temperature of 50 ℃，and injection rate of 5.000 mL/min.Under these conditions，the average particle size of the product was 50 nm，and the microscopic morphology was hexagonal plate-like crystals with strong structure and thermal stability.The research confirmed that the synergy of ionic liquid and microchannel reactor could effectively control the crystal structure，morphology，particle size distribution and thermal stability of magnesium hydroxide.The nano-magnesium hydroxide prepared in this study showed better performance than traditional processes and commercial products，and had great application potential in polymer flame retardancy and other fields.

Key words: nanoscale magnesium hydroxide, microchannel reactor, ionic liquid, synergistic effect

CLC Number:

TQ132.2

LUO Peiyao, LI Xinqi, BU Zhaoshuang, GAO Xi, ZHOU Yicheng, SHEN Chunyu, LI Cuili, WANG Baoming. Study on preparation of nanoscale magnesium hydroxide regulated by ionic liquids in microchannels[J]. Inorganic Chemicals Industry, 2025, 57(11): 52-58.

Figures/Tables 9

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Table 1

Fig.8

References 21

[1]	BAR M， ALAGIRUSAMY R，DAS A.Flame retardant polymer composites［J］.Fibers and Polymers，2015，16（4）：705-717.
[2]	SALMEIA K A， GAAN S.An overview of some recent advances in DOPO-derivatives：Chemistry and flame retardant applications［J］.Polymer Degradation and Stability，2015，113：119-134.
[3]	韩森森.二维纳米杂化阻燃剂制备及阻燃聚合物的性能与机理研究［D］.合肥：中国科学技术大学，2024.
	HAN Sensen.Research on the preparation of two-dimensional nano-hybrid flame retardants and the properties and mechanisms of flame-retarded polymers［D］.Hefei：University of Science and Tech-nology of China，2024.
[4]	靳昕怡，魏丽菲，窦娟，等.无卤阻燃剂在聚合物阻燃中的应用研究进展［J］.高科技纤维与应用，2022，47（6）：67-73.
	JIN Xinyi， WEI Lifei， DOU Juan，et al.Research on the application of halogen-free flame retardants in polymer flame retardan-ts［J］.Hi-Tech Fiber and Application，2022，47（6）：67-73.
[5]	王清硕，惠岚峰，张宜宜，等.新型无卤素阻燃剂研究及应用进展［J］.现代化工，2024，44（6）：35-40.
	WANG Qingshuo， HUI Lanfeng， ZHANG Yiyi，et al.Research and application progress on novel halogen-free flame retardant［J］.Modern Chemical Industry，2024，44（6）：35-40.
[6]	马立群，肖添远，孟爽，等.磷系阻燃剂在常用塑料中的应用进展［J］.工程塑料应用，2017，45（11）：136-139.
	MA Liqun， XIAO Tianyuan， MENG Shuang，et al.Application progress of phosphorous flame retardant in common plastics［J］.Engineering Plastics Application，2017，45（11）：136-139.
[7]	王淼.氢氧化镁透明分散体及其聚合物基阻燃材料的制备和性能研究［D］.北京：北京化工大学，2016.
	WANG Miao.Research on the preparation and properties of transparent magnesium hydroxide dispersions and their polymer-based flame-retardant materials［D］.Beijing：Beijing University of Che-mical Technology，2016.
[8]	刘立平.微化反应器在制备阻燃剂氢氧化镁上的应用［J］.镁化合物科技（生产）信息，2017（1/2）：71-79.
	LIU Liping.Application of micro-reactor in the preparation of magnesium hydroxide flame retardant［J］.Magnesium Compound Technology（Production） Information，2017（1/2）：71-79.
[9]	申纯宇，李翠利，汤建伟，等.纳米氢氧化镁制备及其阻燃应用进展［J］.化工进展，2024，43（9）：4980-4995.
	SHEN Chunyu， LI Cuili， TANG Jianwei，et al.Progress in preparation and flame retardant application of nano magnesium hydroxi-de［J］.Chemical Industry and Engineering Progress，2024，43（9）：4980-4995.
[10]	牛跃同，李慧良，吴敬礼.氢氧化镁阻燃剂的研究应用［J］.盐科学与化工，2023，52（11）：1-3.
	NIU Yuetong， LI Huiliang， WU Jingli.Research and application of magnesium hydroxide flame retardant［J］.Journal of Salt Science and Chemical Industry，2023，52（11）：1-3.
[11]	HE Wentao， SONG Pingan， YU Bin，et al.Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants［J］.Progress in Materials Science，2020，114：100687.
[12]	武俊，钱永芳，吕丽华，等.静电纺PVP/Mg（OH）₂阻燃纳米纤维材料的制备及性能［J］.上海纺织科技，2022，50（7）：23-26，52.
	WU Jun， QIAN Yongfang， Lihua LYU，et al.Preparation of electrospun PVP/Mg（OH）₂ flame retardant nanofiber material and its performance［J］.Shanghai Textile Science & Technology，2022，50（7）：23-26，52.
[13]	马鸣杨.纳米氢氧化镁的制备与改性及阻燃性能研究［D］.武汉：武汉工程大学，2023.
	MA Mingyang.Research on Preparation，Modification and Flame-Retardant Properties of Nano-magnesium Hydroxide［D］.Wuhan：Wuhan Institute of Technology，2023.
[14]	宋春雨，聂普选，马守涛，等.典型过程强化技术在纳米材料制备中的应用进展［J］.过程工程学报，2021，21（4）：373-382.
	SONG Chunyu， NIE Puxuan， MA Shoutao，et al.Application progress of typical process intensification technologies applied for nanomaterials preparation［J］.The Chinese Journal of Process Engineering，2021，21（4）：373-382.
[15]	张靖，柯昌美，段国权，等.新型聚丙烯酸酯乳液对纳米氢氧化镁的改性研究［J］.无机盐工业，2021，53（9）：35-39.
	ZHANG Jing， KE Changmei， DUAN Guoquan，et al.Study on modification of nano-magnesium hydroxide by new polyacrylate emulsion［J］.Inorganic Chemicals Industry，2021，53（9）：35-39.
[16]	叶欣然，吴赞，王海鸥，等.气液两相流体系下微反应器技术研究进展［J］.过程工程学报，2024，24（9）：1001-1015.
	YE Xinran， WU Zan， WANG Haiou，et al.Research progress of microreactor technology in gas-liquid two-phase flow systems［J］.The Chinese Journal of Process Engineering，2024，24（9）：1001-1015.
[17]	周琳，杨炜，吕阳成.微反应器在含能材料合成中的应用及展望［J］.含能材料，2024，32（3）：325-344.
	ZHOU Lin， YANG Wei， Yangcheng LÜ.Review on the application of microreactor in the synthesis processes of energetic materials［J］.Chinese Journal of Energetic Materials，2024，32（3）：325-344.
[18]	武向前，李伟波，高志强.微通道反应器制备纳米硫酸钡的工艺研究［J］.盐科学与化工，2024，53（2）：23-25.
	WU Xiangqian， LI Weibo， GAO Zhiqiang.Study on the preparation of nano barium sulfate by micro-channel reactor［J］.Journal of Salt Science and Chemical Industry，2024，53（2）：23-25.
[19]	曹志军.金属离子液体调控制备功能性纳米复合材料及应用研究［D］.无锡：江南大学，2023.
	CAO Zhijun.Research on the preparation of functional nanocomposites via metal ionic liquid-mediated regulation and their applications［D］.Wuxi：Jiangnan University，2023.
[20]	郑文君.离子液体在无机合成中的应用［J］.大学化学，2024，39（8）：163-168.
	ZHENG Wenjun.Application in inorganic synthesis of ionic liquids［J］.University Chemistry，2024，39（8）：163-168.
[21]	江玮，王瑞，薛伟，等.离子液体辅助合成纳米金属氧化物的研究进展［J］.石油化工，2024，53（1）：105-114.
	JIANG Wei， WANG Rui， XUE Wei，et al.Research progress in synthesis of nano metal oxides assisted by ionic liquids［J］.Petrochemical Technology，2024，53（1）：105-114.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation of nanoscale magnesium hydroxide regulated by ionic liquids in microchannels

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 21

Related Articles 15

Metrics

Comments

Recommended 0

[1]	WANG Yiren, DUO Xinghong. Study on trimethyl phosphate-mixed salt flame retardant electrolytes performance [J]. Inorganic Chemicals Industry, 2025, 57(6): 85-92.
[2]	MA Shuqing, LI Changwen, SHI Chenglong, QIN Yaru. Kinetic study of lithium extraction from solution with iron-based ionic liquid system [J]. Inorganic Chemicals Industry, 2024, 56(9): 60-66.
[3]	ZHOU Wanji, LI Sixia. Study on extraction lithium from brine with high magnesium using ionic liquid/metal salt extraction system [J]. Inorganic Chemicals Industry, 2024, 56(9): 54-59.
[4]	SHEN Haiyan, LI Fangqin, REN Jianxing, WU Jiang, GUAN Zhenzhen, PAN Weiguo. Research progress on chemical absorption method for capturing carbon dioxide [J]. Inorganic Chemicals Industry, 2024, 56(5): 11-19.
[5]	HU Mingliang, ZHOU Wei, LI Bin, LAI Xiaoling. Research progress of synergistic effect catalytic reforming of methane and carbon dioxide [J]. Inorganic Chemicals Industry, 2024, 56(1): 23-32.
[6]	LU Nana, QIN Yaru, MA Shuqing, WANG Qihui, LIU Bing, SHI Chenglong. Study on extraction of lithium from simulated old brine of salt lake by pyridine ionic liquid system [J]. Inorganic Chemicals Industry, 2023, 55(7): 45-50.
[7]	WU Taolong, ZHANG Shengjiang, LIU Jinyang, HONG Xiaobo, LI Limin, QIN Xiaoyu, TAN Xiaoying, ZHOU Yan. Research progress of bimetallic-organic frameworks materials [J]. Inorganic Chemicals Industry, 2023, 55(6): 8-17.
[8]	MI Xiaotong, LI Xiaoguo, CHANG Yang, ZHANG Yongkun, LI Yongheng, CAO Hui, HOU Zhanggui. Collaborative construction of nanoscale ZSM-5 aggregates by crystal seeds and templates [J]. Inorganic Chemicals Industry, 2023, 55(6): 130-135.
[9]	LI Songhong,ZHOU Songhua,ZHAO Aiming,DONG Wenyan,JIANG Chunyan,CAO Yang,AO Xianquan. Study on catalytic gasification reaction of distillers′grains under H₂O/CO₂ atmosphere [J]. Inorganic Chemicals Industry, 2023, 55(2): 132-140.
[10]	LI Xiangyang,LIU Ziwei,LI Keyan,GUO Xinwen. Study on preparation and performance of FeMn-MOF/CN heterojunction photo-Fenton catalyst [J]. Inorganic Chemicals Industry, 2022, 54(12): 126-132.
[11]	KANG Jin,WEI Lina,CHENG Huaigang. Research progress on application of ionic liquids in extracting lithium from salt lakes [J]. Inorganic Chemicals Industry, 2022, 54(1): 1-6.
[12]	Wang Jia,Liu Jinyan,Gao Jun,Wang Lu,Wang Yongli. Study on properties and extraction efficiency of quaternary phosphonium salt ionic liquid/Surfactant/salt aqueous two phase systems [J]. Inorganic Chemicals Industry, 2021, 53(4): 43-47.
[13]	Qin Yaru,Shi Chenglong,Wang Xingquan,Song Guixiu,Li Hongxia,Zhang Jingjing. Study on scrubbing process of lithium extraction from brine in ionic liquid system [J]. Inorganic Chemicals Industry, 2020, 52(3): 55-58.
[14]	Li Xiaoguo,Mi Xiaotong,Hou Zhanggui. Synthesis of aggregated nano-sized ZSM-5 zeolite with ternary pore structure [J]. Inorganic Chemicals Industry, 2020, 52(12): 104-108.
[15]	SHEN Ming-Le, ZHANG Fu-Gang, ZHANG Gang. Synergistic effect of treating acidic waste water containing metal ions by lime stone powder [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(4): 51-.