工业钛液合成钛酸钠负极及其储钠性能

doi:10.19964/j.issn.1006-4990.2023-0055

Abstract

Abstract:

When traditional methods are used to prepare sodium titanate materials，the titanium sources used（such as TiO₂，titanium tetrisopropyl alcohol，etc.） are all pure analytical reagents，which are processed by titanium-bearing minerals through multiple processes.The cost is high and the process of preparing sodium titanate is lengthy.Using industrial titanium liquid as the raw material，the metatitanic acid precursor prepared by atmospheric pressure hydrolysis was used as the titanium source，and the sodium titanate anode was synthesized by the high-temperature solid-phase method，which shortened the preparation process of sodium titanate.The results showed that the synthesized sodium titanate was mainly a mixed phase of Na₂Ti₃O₇ and Na₂Ti₆O₁₃，and its initial discharge specific capacity could reach 233.77 mA·h/g at a low current density of 17.7 mA/g.After 200 times at the current density of 88.5 mA/g，the discharge specific capacity of the prepared sodium titanate material was 26.87 mA·h/g，its capacity retention rate was 47.56%，and its charge-discharge efficiency was 99.54%.After further analysis，the sodium storage process of the prepared mixed sodium titanate was dominated by pseudocapacitive behavior.

Key words: metatilinic acid, sodium titanate, anode material, sodium-ion battery, energy storage

CLC Number:

TQ134.11

ZHANG Rui, WANG Zhenghao, CHEN Liang, GUO Xiaodong, LUO Dongmei. Synthesis of sodium titanate anode from industrial titanium liquid and its sodium storage performance[J]. Inorganic Chemicals Industry, 2023, 55(12): 66-73.

Figures/Tables 11

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制备方法	原料	产物物相	电流密度/循环次数/放电比容量
水热法^［20］（850 ℃，焙烧12 h）	锐钛TiO₂，NaOH	Na₂Ti₃O₇/Na₂Ti₆O₁₃	20 mA/g，100次，约80 mA·h/g；2 000 mA/g， 4 000次，19.45 mA·h/g
溶胶-凝胶法^［24］（780 ℃，焙烧10 h）	丁醇钛，NaOH	Na₂Ti₃O₇；Na₂Ti₃O₇/MWCNT	0.2C，50次，8 mA·h/g；0.2C，50次，160 mA·h/g
喷雾干燥法^［25］（800 ℃，8 h； 1 000 ℃，8 h）	TiO₂，Na₂CO₃	800 ℃：Na₂Ti₃O₇； 1 000 ℃：Na₂Ti₃O₇	35.6 mA/g，500次，44 mA·h/g；178 mA/g， 500次，32 mA·h/g
高温固相法^［26］（800 ℃，24 h；800 ℃，20 h）	TiO₂和Na₂CO₃·H₂O，TiO₂和NaOH	24 h：CO-Na₂Ti₃O₇； 20 h：OH-Na₂Ti₃O₇	0.1C，100次，<10 mA·h/g；0.1C，100次，约 76.9 mA·h/g
高温固相法^［27］（800 ℃，20 h；1 000 ℃，20 h）	TiO₂（锐钛与金红石混合）和Na₂CO₃	m-Na₂Ti₃O₇；t-Na₂Ti₃O₇	20 mA/g，20次，35.5 mA·h/g；20 mA/g，20次，约92 mA·h/g
高温固相法（800 ℃，20 h）	工业钛液水解得到的偏钛酸，Na₂CO₃	Na₂Ti₃O₇/Na₂Ti₆O₁₃	88.5 mA/g，200次，26.87 mA·h/g

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Synthesis of sodium titanate anode from industrial titanium liquid and its sodium storage performance

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