基于生命周期评价法的黄磷产品碳足迹分析

doi:10.19964/j.issn.1006-4990.2023-0222

Abstract

Abstract:

Yellow phosphorus，as a high energy consumption and high carbon emission product，to find out its carbon emission footprint and promote its low carbon development is of great significance to our “double carbon” strategy.Taking a 50 000 t/a yellow phosphorus enterprise in Guizhou province as an example，Life Cycle Assessment（LCA） was adopted to quantitatively analyze the carbon footprint of yellow phosphorus products in the production process，and proposed corresponding energy-saving and carbon reduction measures for its green and low-carbon development.The research results showed that the carbon footprint of each ton of yellow phosphorus in the production process was 1.580×10⁴ kg CO₂.The carbon emissions were concentrated in the two aspects of tail gas treatment and power consumption，which was accounted for 90.08% of the total.Based on its carbon footprint accounting results，it was proposed to adopt green power production，rational use of the geographical advantages of phosphorus resources，strengthen process control，and comprehensive utilization of yellow phosphorus tail gas and other emission reduction measures to reduce the carbon footprint of yellow phosphorus production process.

Key words: “dual carbon” strategy, life cycle assessment, yellow phosphorus, carbon footprint, energy conservation and carbon reduction

CLC Number:

TQ127.1

WANG Xuemeng, AN Yan, LIU Hai, TIAN Mengkui. Carbon footprint analysis of yellow phosphorus products based on LCA[J]. Inorganic Chemicals Industry, 2023, 55(12): 36-42.

Figures/Tables 11

Fig.1

Fig.2

Fig.3

Table 1

Carbon footprint calculation method of yellowphosphorus production process"

统计类别	碳足迹核算
原材料消耗	$E 原材料$ =AD_原材料×EF_原材料
生产过程	$E 过程$ 尾气监测数据
净购入电力	$E 电$ =AD_电×EF_电
净购入热力	$E 热$ =AD_热×EF_热
原材料运输	$E 运输$ =AD_运输×EF_运输
尾气处理	$E 尾气$ 根据尾气监测数据计算
磷渣处理	$E 炉渣$ 根据炉渣电力、热力消耗数据计算
总计	$E 总 = E 原材料 + E 过程 + E 电 + E 热 + E 运输 + E 尾气 + E 炉渣$

Table 1

Table 2

Table 3

Table 4

Table 5

Table 6

Fig.4

Fig.5

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物料名称	碳排放因子	数据来源
磷矿石	0.013 34 kg/kg	CLCD中国生命周期基础数据库
焦炭	0.133 65 kg/kg	CLCD中国生命周期基础数据库
硅石	0.039 30 kg/kg	CLCD中国生命周期基础数据库
运输	0.177 20 kg/（t·km）	ECLC3.0&Encoinvent
电力（南方区域）	0.508 85 kg/（kW·h）	省级温室气体清单编制指南
热力	0.110 00 kg/MJ	CLCD中国生命周期基础数据库

项目	CO₂的排放量/kg	项目	CO₂的排放量/kg
磷矿石	1.293×10²	热力	2.464×10²
焦炭	2.459×10²	过程排放	2.165×10²
硅石	76.64	尾气处理	7.592×10³
运输	37.55	磷渣处理	6.178×10²
电力	6.642×10³	总计	1.580×10⁴

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Carbon footprint analysis of yellow phosphorus products based on LCA

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