金属元素掺杂尖晶石型镓酸镁的研究进展

doi:10.11962/1006-4990.2019-0330

Abstract

Abstract:

Magnesium gallate（MgGa₂O₄） is a kind of gallate with spinel structure,which is composed of magnesium oxide （MgO） and gallium oxide（Ga₂O₃）.It has good dielectric properties,optical properties,radiation resistance and high tempera-ture stability etc..Due to the existence of a self-activated emission band in the blue visible light region,it has received exten-sive attention in luminescence research.The doping of rare earth and transition metal elements can change the energy transfer process,improve the luminescence efficiency and broaden the luminescence range,which can be applied in many fields such as display,illumination,medical diagnosis and laser,and it has broad application prospect.The research progress on the structure and optical properties of MgGa₂O₄ single doped and co-doped with metal elements such as chromium（Cr）,cobalt（Co）,manganese（Mn）,dysprosium（Dy） and europium（Eu） in recent years was summarized,the main problems existing in the current researches were analyzed,and the research directions and development applications of MgGa₂O₄ doped with metal elements in the future were also prospected.

Key words: MgGa₂O₄, metal doping, optical property, research progress

CLC Number:

TQ132.2

Yao Yong,Guo Rui. Research progress of metal element doped spinel type MgGa₂O₄[J]. Inorganic Chemicals Industry, 2020, 52(4): 23-28.

Figures/Tables 1

References 40

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掺杂样品	激发波段/ nm	发射波段/ nm	应用
MgGa₂O₄： Cr^{3+[10,11,12,13,14]}	230	707	生物成像探针、可调谐激光器
MgGa₂O₄： Co^2+[19,20,21]	545	680	可调谐介质、高寿命光学器件
MgGa₂O₄： Dy^3+[26,27]	350	480、575、665	白色LED荧光粉
MgGa₂O₄：Eu^3+[28]	257	613	固态激光器件、低能量
MgGa₂O₄：Pr^3+[28]	247	497	激发荧光粉
MgGa₂O₄：Mn^2+[29]	300/532	501/642	绿色/红色光源材料、荧光显示器
MgGa₂O₄：Ni^2+[30]	974	1 260	近红外可调谐激光器
MgGa₂O₄： Co²⁺,Cr^3+[31]	585	680、700	红色光源材料
MgGa₂O₄： Er³⁺,Yb^3+[32]	980	522、545、 651、1 530	激光器、光纤放大器
MgGa₂O₄： Mn²⁺,Eu^2+[33]	254	503	等离子体显示器
MgGa₂O₄： Mn²⁺,Ce^3+[33]	254	503	等离子体显示器
MgGa₂O₄： Mn²⁺,Yb^3+[34]	976	507	高效光电器件
MgGa₂O₄： Mn²⁺,Eu^3+[35]	260	430、505、617	白光高效荧光粉
MgGa₂O₄：Er³⁺, Yb³⁺,Mn^2+[36]	980	507、1 500	温度传感器、光传输

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Research progress of metal element doped spinel type MgGa₂O₄

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