配锂量对LiNi0.90Mn0.07Al0.03O2正极材料电化学性能影响的研究

doi:10.19964/j.issn.1006-4990.2024-0238

Abstract

Abstract:

With the increasing demand for battery energy density in modern society，researchers have focused on high-nickel layered cathode materials with high specific capacity.However，the calcination conditions of high-nickel materials are very harsh and the material synthesis is complicated，so it is necessary to explore their synthesis conditions.Three kinds of LiNi_0.90Mn_0.07Al_0.03O₂（NMA973） cathode materials with different lithium contents（1.02，1.04，1.06） were successfully prepared by the coprecipitation method，and the effects of different lithium contents on the structural morphology and electrochemical properties of the cathode material NMA973 were investigated.NMA973-1.04 cathode material had a good layered structure as determined by XRD and SEM characterization.The XPS test showed that the Ni³⁺ of NMA973-1.04 cathode material was high，which further proved that the Li⁺/Ni²⁺ mixing degree was low.The ICP test confirmed that the Li content of NMA973-1.04 cathode material was the closest to the design value.The electrochemical tests showed that NMA973-1.04 cathode material had high discharge specific capacity at different rates，the discharge specific capacity of small rate 0.2C could reach 199.00 mA·h/g，and the discharge specific capacity from large rate 5.0C and back to small rate 0.2C could reach 198.60 mA·h/g，with a capacity retention rate of 99.0%.The capacity retention of 89.0% after 100 cycles at 1.0C demonstrated the excellent cycling performance and structural stability of NMA973-1.04 cathode material.The results indicated that the NMA973 cathode material with a lithium distribution of 1.04 had excellent performance.

Key words: lithium-ion battery, Ni-rich ternary cathodes, lithium content, coprecipitation method

CLC Number:

TQ131.11

SHEN Qirongxin, AI Dengdeng, JIN Shengping, XI Ruheng, HOU Xiaoyi. Study on effect of lithium concent on electrochemical performance of LiNi_0.90Mn_0.07Al_0.03O₂ cathode materials[J]. Inorganic Chemicals Industry, 2025, 57(7): 50-56.

Figures/Tables 6

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References 27

[1]	CHU Binbin， GUO Yujie， SHI Jilei，et al.Cobalt in high-energy-density layered cathode materials for lithium ion batteries［J］.Journal of Power Sources，2022，544：231873.
[2]	刘培松，宋利君，黄朝连，等.锰源对尖晶石LiMn₂O₄高温性能的影响［J］.无机化学学报，2023，39（1）：55-62.
	LIU Peisong， SONG Lijun， HUANG Chaolian，et al.Effects of manganese sources on the high temperature performance of spinel LiMn₂O₄ ［J］.Chinese Journal of Inorganic Chemistry，2023，39（1）：55-62.
[3]	HU Jiangtao， HUANG Weiyuan， YANG Luyi，et al.Structure and performance of the LiFePO₄ cathode material：From the bulk to the surface［J］.Nanoscale，2020，12（28）：15036-15044.
[4]	王峰，赵桓，吴红峰，等.镍酸锂系正极材料倍率性能的研究进展［J］.中国稀土学报，2023，41（3）：497-519.
	WANG Feng， ZHAO Huan， WU Hongfeng，et al.Research progress on C-rate performance of LiNiO₂ series cathode materials［J］.Journal of the Chinese Society of Rare Earths，2023，41（3）：497- 519.
[5]	CHENG Yong， ZHANG Xiaozhen， LENG Qianyi，et al.Boosting electrochemical performance of Co-free Ni-rich cathodes by combination of Al and high-valence elements［J］.Chemical Engineering Journal，2023，474：145869.
[6]	LIU Zhedong， WANG Chunying， ZHANG Jingchao，et al.Co-free/Co-poor high-Ni cathode for high energy，stable and low-cost lithium-ion batteries［J］.Rare Metals，2023，42（7）：2214-2225.
[7]	LI Wangda， LEE S， MANTHIRAM A.High-nickel NMA：A cobalt-free alternative to NMC and NCA cathodes for lithium-ion batteries［J］.Advanced Materials，2020，32（33）：2002718.
[8]	RYU H H， SUN H H， MYUNG S T，et al.Reducing cobalt from lithium-ion batteries for the electric vehicle era［J］.Energy & Environmental Science，2021，14（2）：844-852.
[9]	CHENG Fangyuan， ZHANG Wen， QIN Daomin，et al.Reinterpreting the correlation between cycling stability of Ni-rich layered oxide cathode and the charging cut-off voltage in Li-ion batteries［J］.Nano Energy，2023，115：108699.
[10]	黄丽颖，陆冬楚，宁玉雪，等.锂离子电池正极材料铌掺杂LiNiO₂的制备与电化学性能［J］.无机盐工业，2022，54（11）：52-58.
	HUANG Liying， LU Dongchu， NING Yuxue，et al.Preparation and electrochemical performance of Nb-doped LiNiO₂ cathode material for lithium-ion batteries［J］.Inorganic Chemicals Industry，2022，54（11）：52-58.
[11]	SONG Yijun， CUI Yongpeng， GENG Lin，et al.Li/Ni intermixing：The real origin of lattice oxygen stability in Co-free Ni-rich cathode materials［J］.Advanced Energy Materials，2024，14（7）：2303207.
[12]	MA Mingyuan， YANG Dan， JI Yongsheng，et al.Achieving enhanced electrochemical performance for cobalt-free layered cathode material by aluminum doping［J］.Batteries & Supercaps，2023，6（6）：e202300103.
[13]	CUI Zehao， GUO Zezhou， MANTHIRAM A.Assessing the intrinsic roles of key dopant elements in high-nickel layered oxide cathodes in lithium-based batteries［J］.Advanced Energy Materials，2023，13（12）：2203853.
[14]	YAO Meng， TAO Zemin， LIU Guobiao，et al.A novel calcination method towards layered Ni-rich cathode with enhanced electrochemical performances and regulated oxygen vacancies［J］.Che- mical Engineering Journal，2023，473：145090.
[15]	XIAO Peng， LI Wenhao， CHEN Shuai，et al.Effects of oxygen pressurization on Li⁺/Ni²⁺ cation mixing and the oxygen vacancies of LiNi_0.8Co_0.15Al_0.05O₂ cathode materials［J］.ACS Applied Materials & Interfaces，2022，14（28）：31851-31861.
[16]	冯准.B/Al/Zr协同策略改善高镍单晶正极材料高温稳定性［J］.无机盐工业，2023，55（8）：59-64，70.
	FENG Zhun.Improvement of high temperature stability of high nickel single crystal cathode materials by B/Al/Zr synergistic strategy［J］.Inorganic Chemicals Industry，2023，55（8）：59-64， 70.
[17]	LI Yingying， ZHANG Yang， LIU Jie，et al.Inducing favorable dual-substitution reactivity by doping Mo⁶⁺ and F^- to enhance electrochemical performance of LiNi_0.6Co_0.2Mn_0.2O₂ cathode materials［J］.Ceramics International，2022，48（16）：23016-23023.
[18]	孔祥泽，李东林，王子匀，等.钨掺杂对锂离子电池LiNiO₂正极材料性能的影响［J］.无机化学学报，2019，35（7）：1169-1175.
	KONG Xiangze， LI Donglin， WANG Ziyun，et al.Effect of W-doping on electrochemical performance of LiNiO₂ cathode for lithium-ion batteries［J］.Chinese Journal of Inorganic Chemistry，2019，35（7）：1169-1175.
[19]	TAN Xinxin， PENG Wenjie， WANG Meng，et al.Al，Zr dual-doped cobalt-free nickel-rich cathode materials for lithium-ion batteries［J］.Progress in Natural Science：Materials International，2023，33（1）：108-115.
[20]	王征荣，张海朗.过锂量对富锂锰基正极材料Li_1.2+ _x Ni_0.1Co_0.2Mn_0.5O₂结构与电化学性能的影响［J］.稀有金属材料与工程，2019，48（3）：941-946.
	WANG Zhengrong， ZHANG Hailang.Effect of extra lithium amount on the structure and electrochemical properties of Li-rich manganese-based cathode material of Li_1.2+ _x Ni_0.1Co_0.2Mn_0.5O₂ ［J］.Rare Metal Materials and Engineering，2019，48（3）：941-946.
[21]	ESSEHLI R， PAREJIYA A， MURALIDHARAN N，et al.Hydrothermal synthesis of Co-free NMA cathodes for high performance Li-ion batteries［J］.Journal of Power Sources，2022，545：231938.
[22]	ZHONG Shengwen， CHEN Peng， YAO Wenli.Ni-rich layered oxide Li_1.05（Ni_0.7Mn_0.3）O₂ as a highly reversible cathode material for lithium-ion batteries［J］.ECS Electrochemistry Letters，2015，4（6）：A45-A48.
[23]	NOEROCHIM L， GUNAWAN E A， PINTOWANTORO S，et al.High-rate capability of LiNi_0.9Mn_0.1– _x Al _x O₂（NMA）（x=0.01，0.03，0.05） as cathode for lithium-ion batteries［J］.Batteries，2023，9（8）：420.
[24]	YU S A， SEO J K， YUN J M，et al.Hybrid surface coating layers comprising boron and phosphorous compounds on LiNi_0.90Co_0.05Mn_0.05O₂ cathode materials to ensure the reliability of lithium-ion batteries［J］.Materials Today Energy，2023，37：101377.
[25]	BROW R， DONAKOWSKI A， MESNIER A，et al.Mechanical pulverization of Co-free nickel-rich cathodes for improved high-voltage cycling of lithium-ion batteries［J］.ACS Applied Energy Materials，2022，5（6）：6996-7005.
[26]	XI Ruheng， ZHANG Jianru， LAN Ziwei，et al.High-nickel and cobalt-free layered LiNi_0.90Mn_0.06Al_0.04O₂ cathode for lithium-ion batteries［J］.Ceramics International，2022，48（24）：36690-36696.
[27]	SONG Jinshang， ZHU Lingzhi， LI Yudong，et al.W modification of nickel-rich ternary cathode material for efficient lithium-ion batteries［J］.Journal of The Electrochemical Society，2023，170（1）：010523.

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Study on effect of lithium concent on electrochemical performance of LiNi_0.90Mn_0.07Al_0.03O₂ cathode materials

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Study on effect of lithium concent on electrochemical performance of LiNi0.90Mn0.07Al0.03O2 cathode materials