铜仁地区菱锰矿矿物学特征及其元素赋存状态研究

doi:10.19964/j.issn.1006-4990.2023-0507

Abstract

Abstract:

Tongren Guizhou is located in the“Manganese Triangle” region of China.The reserves of manganese ore are abundant，mainly in the form of rhodochrosite.X-ray fluorescence spectrometer（XRF），X-ray diffractometer（XRD），simultaneous thermal analyzer（TG-DSC），scanning electron microscope（SEM），X-ray photoelectron spectroscopy（XPS） and other modern characterization and analysis methods were used to study the occurrence state，mineralogical characteristics and pyrolysis properties of C，O，Mn，Ca and other elements in rhodochrosite.The results showed that the mass percentage of manganese in the mineral was 14.656 %，and the mass percentage of manganese/iron was about 4.22，which belonged to low-grade medium-iron acid rhodochrosite.The chemical composition and phase composition of the ore were relatively complex.Among them，the existence form of manganese element was mainly manganese carbonate，and a small amount was manganese dioxide.The calcium and magnesium elements were mainly in the form of dolomite，and a small amount existed in the form of silicate.At temperature ranging from 500 ℃ to 600 ℃，rhodochrosite was decomposed to MnO and CO₂.When the temperature was higher than 600 ℃，dolomite in rhodochrosite was decomposed into CaCO₃，MgO and CO₂.At the same time，MgO reacted with a small amount of MnO to form magnesium manganese oxides.When the temperature reached 800 ℃，CaCO₃ was decomposed to form CaO and CO₂.The research results could provide reference for the development and utilization of rhodochrosite in Tongren area.

Key words: rhodochrosite, mineralogical characteristics, occurrence state, manganese carbonate, pyrolysis characteristic

CLC Number:

TQ137.12

LIN Weizhi, FU Chengbing, HU Ping, YANG Kaixu, CAO Jianxin. Study on mineralogical characteristics and occurrence state of elements of rhodochrosite in Tongren area[J]. Inorganic Chemicals Industry, 2024, 56(6): 73-79.

Figures/Tables 11

Fig.1

Table 1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

References 21

1	文馨蓓.浅谈中国锰矿资源的现状与潜力［J］.西部资源，2015（5）：142-143.
	WEN Xinbei.Present situation and potential of manganese resources in China［J］.Western Resources，2015（5）：142-143.
2	任辉，刘敏，王自国，等.我国锰矿资源及产业链安全保障问题研究［J］.中国工程科学，2022，24（3）：20-28.
	REN Hui， LIU Min， WANG Ziguo，et al.Security of manganese resources and industrial chain in China［J］.Strategic Study of CAE，2022，24（3）：20-28.
3	王彦，李艳军.某菱锰矿石工艺矿物学研究［J］.金属矿山，2019（2）：188-191.
	WANG Yan， LI Yanjun.Research on process mineralogy of a carbonaceous rhodochrosite ore［J］.Metal Mine，2019（2）：188-191.
4	程湘，胡鹏，张海坤，等.锰矿主要类型、分布特点及开发现状［J］.中国地质，2021，48（1）：102-119.
	CHENG Xiang， HU Peng， ZHANG Haikun，et al.The main types，distribution and current development of manganese ore deposi-ts［J］.Geology in China，2021，48（1）：102-119.
5	高艺，刘宏杰.锰矿资源现状及潜力预测［J］.中国锰业，2020，38（2）：1-5.
	GAO Yi， LIU Hongjie.A current situation of manganese resources and its technical research progress［J］.China′s Manganese Industry，2020，38（2）：1-5.
6	张兴然.低品位复杂锰矿浸出与电解过程的强化研究［D］.重庆：重庆大学，2017.
	ZHANG Xingran.Research on intensification of leaching and electrolysis process for low grade and complex manganese ore［D］.Chongqing：Chongqing University，2017.
7	WANG Kui， ZHANG Qiwu， HE Xiaoman，et al.A cleaner and efficient extraction of Mn from low-grade Mn carbonate ores by ball milling-enhanced Fe₂（SO₄）₃ leaching：Acid consumption reduction［J］.Cleaner Engineering and Technology，2021，4：100220.
8	XU Fuyuan， JIANG Linhua， DAN Zhigang，et al.Water balance analysis and wastewater recycling investigation in electrolytic manganese industry of China：A case study［J］.Hydrometallurgy，2014，149：12-22.
9	张周位，陈文祥，黄苑龄，等.贵州某低品位碳酸锰矿工艺矿物学及选矿试验研究［J］.矿产综合利用，2018（3）：66-69.
	ZHANG Zhouwei， CHEN Wenxiang， HUANG Yuanling，et al.Experimental study on process mineralogy and mineral processing of a low-grade manganese carbonate ore in Guizhou［J］.Multipurpose Utilization of Mineral Resources，2018（3）：66-69.
10	代典，梁欢，何东升，等.湘西地区微细粒级难选菱锰矿浮选试验研究［J］.矿产综合利用，2020（4）：76-81.
	DAI Dian， LIANG Huan， HE Dongsheng，et al.Experimental study on the flotation of a micro-grained refractory rhodochrosite in western Hunan Area［J］.Multipurpose Utilization of Mineral Resources，2020（4）：76-81.
11	常征.锰三角地区电解锰压滤渣高温可控脱硫生产活性微粉项目经济效益与社会效益分析［J］.地质与勘探，2020，56（4）：845-851.
	CHANG Zheng.Economic and social benefits of the project of producing active micropowder from electrolytic manganese slag through high-temperature desulfurization and activation in manganese triangle area［J］.Geology and Exploration，2020，56（4）：845-851.
12	SONG K，BAE J， LEE G.Determination of Mn oxidation state in Mn-（hydr）oxides using X-ray photoelectron spectroscopy （XPS）［J］.2009，42（5），91635473.
13	PHILIPP T， HUITTINEN N， AZZAM S S A，et al.Effect of Ca（Ⅱ） on U（Ⅵ） and Np（Ⅵ） retention on Ca-bentonite and clay minerals at hyperalkaline conditions-New insights from batch sorption experiments and luminescence spectroscopy［J］.The Science of the Total Environment，2022，842：156837.
14	杜沛佞，罗仕忠，谭仁俊，等.钇掺杂三氧化二铁催化剂的脱硝性能研究［J］.无机盐工业，2022，54（11）：137-142.
	DU Peining， LUO Shizhong， TAN Renjun，et al.Study on denitration performance of Y doped Fe₂O₃ catalyst［J］.Inorganic Chemicals Industry，2022，54（11）：137-142.
15	李少平.菱锰矿与钙镁碳酸盐矿物晶体结构、表面特性和浮选行为研究［D］.赣州：江西理工大学，2019.
	LI Shaoping.Study on the crystal chemistry，surface characteristics and flotation behavior between rhodochrosite and calcium-magnesium carbonate minerals［D］.Ganzhou：Jiangxi University of Science and Technology，2019.
16	何静，李崇瑛，张清雨.碳酸盐岩的矿物单体解离研究进展［J］.辽宁化工，2021，50（9）：1311-1314.
	HE Jing， LI Chongying， ZHANG Qingyu.Research progress in the dissociation of mineral monomers in carbonate rocks［J］.Liaoning Chemical Industry，2021，50（9）：1311-1314.
17	王帆，田英良.热重-差热分析仪器验证方法与实践［J］.玻璃搪瓷与眼镜，2020，48（6）：1-7.
	WANG Fan， TIAN Yingliang.Verification and practice of thermogravimetry-differential thermal analyzor［J］.Glass Enamel & Ophthalmic Optics，2020，48（6）：1-7.
18	邹飞，黄春荣，蹇攀，等.中空球形碳酸锰合成及热分解制备MnO_x研究［J］.矿冶工程，2021，41（4）：156-160.
	ZOU Fei， HUANG Chunrong， JIAN Pan，et al.Synthesis of hollow spherical manganese carbonate and its thermal decomposition for preparation of MnO_x［J］.Mining and Metallurgical Engineering，2021，41（4）：156-160.
19	周强，武斌，陈葵，等.磷尾矿热分解动力学机理与煅烧工艺研究［J］.无机盐工业，2023，55（3）：47-54.
	ZHOU Qiang， WU Bin， CHEN Kui，et al.Study on thermal decomposition kinetic mechanism and calcination process of phosphorus tailings［J］.Inorganic Chemicals Industry，2023，55（3）：47-54.
20	马玉文，冯雅丽，李浩然.硫酸锰室温固相球磨制备四氧化三锰［J］.无机盐工业，2013，45（2）：17-19.
	MA Yuwen， FENG Yali， LI Haoran.Preparation of Mn₃O₄from manganese sulfate by solid-state ball milling reaction at room tem-perature［J］.Inorganic Chemicals Industry，2013，45（2）：17-19.
21	吉国荣.添加剂对固相合成镁铝尖晶石材料的影响［D］.太原：太原科技大学，2020.
	JI Guorong.Effect of additives on solid phase synthesis of magnesium-alumina spinel materials［D］.Taiyuan：Taiyuan University of Science and Technology，2020.

项目	w（SiO₂）	w（MnO）	w（CaO）	w（Al₂O₃）	w（Fe₂O₃）	w（SO₃）	w（MgO）	w（K₂O）	w（PbO）	w（CrO）	w（其他）
未筛分	37.372	18.920	15.306	11.057	4.973	4.610	3.536	2.408	0.029	0.009	1.780
≥48 μm	36.865	20.034	15.742	11.141	4.542	4.137	3.669	2.190	0.025	0.006	1.649
23~< 48 μm	38.573	18.700	14.513	11.469	5.410	4.245	3.674	2.519	0.026	0.009	0.862
<23 μm	38.088	17.015	13.377	12.915	5.655	4.473	3.688	3.077	0.023	0.007	1.682
极差	1.708	3.019	2.365	1.774	1.113	0.336	0.019	0.887	0.003	0.003	0.820
平均值	37.842	18.583	14.544	11.842	5.202	4.285	3.677	2.595	0.025	0.007	1.398

[1]	ZHENG Kexin, WANG Haifeng, WANG Jiawei, ZHOU Xingjie, PEI Zhengqing, LU Ju, MA Dehua. Study on leaching and kinetics of rhododengite in Jingxi area of Guangxi [J]. Inorganic Chemicals Industry, 2025, 57(1): 51-57.
[2]	WANG Ruirui, ZHU Chaoliang, MU Bing, MA Wanxia, FAN Jie, XU Guowang, SHI Yifei, DENG Xiaochuan, QING Binju. Preparation of cubic manganese carbonate by hydrothermal method and its application in extraction of lithium [J]. Inorganic Chemicals Industry, 2024, 56(12): 94-103.
[3]	YANG Junjie, DONG Yonggang, ZHANG Jing, ZHANG Yu, CAO Jianxin. Occurrence and distribution of matter elements in phosphorus tailings [J]. Inorganic Chemicals Industry, 2023, 55(12): 111-118.
[4]	Huang Jiming,Liu Runqing,Wu Sizhan,Song Juan. Optimization of extraction process of chlorination roasting-water leaching process for low-grade rhodochrosite by response surface methodology [J]. Inorganic Chemicals Industry, 2019, 51(3): 34-37.
[5]	TAN Jian-Hong, WAN Bang-Jiang, LI Bing. Study on preparation process of manganese sulfate with iron rich rhodochrosite [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(8): 50-.
[6]	WU Jun. Effect of nano barium titanate doping on properties of ceramics [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(8): 14-.
[7]	LIN Qing-Quan, LIU You-Cai, LI Li-Feng, WANG Yun-Qiu, WANG Jia-Yi, XU Jing-Yan, XI Han-Xia, PENG Bin-Jiang, ZHU Zhong-Si. Study on technology of preparing high purity manganese sulfate with low-grade manganese carbonate ores [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(11): 35-.
[8]	MA Yu-Wen, FENG Ya-Li, LI Hao-Ran. Preparation of Mn₃O₄ from manganese sulfate by solid-state ball milling reaction at room temperature [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(2): 17-.
[9]	FENG Ru, TONG Zhang-Fa, ZHENG Shuai-Fei, CHEN Zhi-Chuan, GAO Da-Ming. Preparation of high-purity manganese carbonate from rhodochrosite by ammonium chloride roasting method [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(8): 33-.
[10]	Ma Yao;Zhuo Changsheng;Huang Zhijun;Liao Wenhuei. Development of high purity manganese carbonate from low-grade manganese oxidized ore [J]. INORGANICCHEMICALSINDUSTRY, 2008, 0(6): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on mineralogical characteristics and occurrence state of elements of rhodochrosite in Tongren area

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 21

Related Articles 10

Metrics

Comments

Recommended 0