固态无机电解质Li7La3Zr2O12的改性研究进展

doi:10.19964/j.issn.1006-4990.2020-0666

Abstract

Abstract:

As a solid inorganic electrolyte material,Li₇La₃Zr₂O₁₂ in cubic garnet phase has advantages of high lithium ion con-ductivity at room-temperature,wide electrochemical window and excellent thermal stability,which is the key to the commer-cial application of solid lithium ion batteries with high safety and high energy density.The crystal structure and lithium con-duction mechanism of Li₇La₃Zr₂O₁₂were described,and the recent advances in modification of phase structure stability,interfa-cial impedance and compatibility,sintering activity and ionic conductivity of Li₇La₃Zr₂O₁₂ by means of element doping,poly-mer electrolyte compounding,sintering additives introduction,surface coating or modification were reviewed.Finally,aiming at the obstacles and challenges in the industrial application of Li₇La₃Zr₂O₁₂,the countermeasures including development of new preparation process,multiple modification of ionic conductivity,and structure design and optimization of flexible compo-site electrolyte membrane were proposed, which could provide a basis for promoting the development of high-performance solid state lithium ion batteries.

Key words: Li₇La₃Zr₂O₁₂, lithium ion battery, solid state electrolyte, ion conductivity

CLC Number:

TQ131.11

LU Chao,LI Mingming,WU Xiaoqiang,AN Xuguang,KONG Qingquan,WANG Xiaolian. Research progress on modification of solid inorganic electrolyte of Li₇La₃Zr₂O₁₂[J]. Inorganic Chemicals Industry, 2021, 53(11): 10-16.

Figures/Tables 2

References 52

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Research progress on modification of solid inorganic electrolyte of Li₇La₃Zr₂O₁₂

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Research progress on modification of solid inorganic electrolyte of Li7La3Zr2O12