铂基有序纳米催化剂的制备方法研究进展

doi:10.19964/j.issn.1006-4990.2021-0401

Abstract

Abstract:

The development of low?cost and long?life platinum based catalysts is the key to the commercialization of proton exchange membrane fuel cells.Platinum based intermetallic compounds are considered to be the ideal choice for fuel cell catalysts because of their atomic ordered structure and unique catalytic properties.The latest progress on the preparation of platinum based intermetallic compounds catalysts was reviewed，including direct annealing，shell?assisted annealing，template?assisted annealing and solvothermal method.The application of platinum based intermetallic compounds catalysts in catalytic oxygen reduction reaction was discussed.There is still a lack of simple and efficient preparation methods and large?scale production technology for the preparation of intermetallic compound catalysts.Therefore，it is of great significance to accelerate the development of new preparation methods for the preparation of intermetallic compound catalysts to promote the practical application of platinum-based ordered catalysts.

Key words: fuel cell, catalyst, intermetallic compounds, heat treatment

CLC Number:

TQ138.26

HAN Xiudong. Research progress on preparation method of platinum based ordered nano catalysts[J]. Inorganic Chemicals Industry, 2022, 54(5): 47-53.

Figures/Tables 5

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

References 41

1	邵志刚，衣宝廉.氢能与燃料电池发展现状及展望［J］.中国科学院院刊，2019，34（4）：469-477.
	SHAO Zhigang， YI Baolian.Developing trend and present status of hydrogen energy and fuel cell development［J］.Bulletin of Chinese Academy of Sciences，2019，34（4）：469-477.
2	MA Zhong， CANO Z P， YU Aiping，et al.Enhancing oxygen reduction activity of Pt-based electrocatalysts：From theoretical mechanisms to practical methods［J］.Angewandte Chemie International Edition，2020，59（42）：18334-18348.
3	马洋博，干林.燃料电池铂合金纳米晶催化剂的形貌控制及稳定性研究进展［J］.科学通报，2017，62（25）：2905-2918.
	MA Yangbo， GAN Lin.Progress in the morphology control and stability of shaped Pt alloy nanocrystal catalysts for fuel cells［J］.Chinese Science Bulletin，2017，62（25）：2905-2918.
4	WANG Xiaoxia， SOKOLOWSKI J， LIU Hui，et al.Pt alloy oxygen-reduction electrocatalysts：Synthesis，structure，and property［J］.Chinese Journal of Catalysis，2020，41（5）：739-755.
5	SUN Shouheng， MURRAY C B， WELLER D，et al.ChemInform abstract：Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices［J］.ChemInform，2000，31（27）.Doi：10.1002/ chin.200027244 . doi: 10.1002/ chin.200027244
6	CHUNG D Y， JUN S W， YOON G，et al.Highly durable and active PtFe nanocatalyst for electrochemical oxygen reduction reaction［J］.Journal of the American Chemical Society，2015，137（49）：15478-15485.
7	LIU Zhufang， JACKSON G S， EICHHORN B W.Tuning the CO-tolerance of Pt-Fe bimetallic nanoparticle electrocatalysts through architectural control［J］.Energy & Environmental Science，2011，4（5）：1900-1903.
8	WANG D， XIN H L， HOVDEN R，et al.Structurally ordered intermetallic platinum⁃cobalt core⁃shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts［J］.Nature Materials，2013，12（1）：81-87.
9	LEONARD B M， ZHOU Qin， WU Diane，et al.Facile synthesis of PtNi intermetallic nanoparticles：Influence of reducing agent and precursors on electrocatalytic activity［J］.Chemistry of Materials，2011，23（5）：1136-1146.
10	XIA Baoyu， WU Haobin， WANG Xin，et al.One-pot synthesis of cubic PtCu₃ nanocages with enhanced electrocatalytic activity for the methanol oxidation reaction［J］.Journal of the American Chemical Society，2012，134（34）：13934-13937.
11	HODNIK N， JEYABHARATHI C， MEIER J C，et al.Effect of ordering of PtCu nanoparticle structure on the activity and stability for the oxygen reduction reaction［J］.Physical Chemistry Chemical Physics，2014，16（27）：13610-13615.
12	ZHANG Zhicheng， LUO Zhimin， CHEN Bo，et al.One-pot synthesis of highly anisotropic five⁃fold⁃twinned PtCu nanoframes used as a bifunctional electrocatalyst for oxygen reduction and methanol oxidation［J］.Advanced Materials，2016，28（39）：8712-8717.
13	ZHAO Xiao， GUNJI Takao， KANEKO T，et al.Evidence for interfacial geometric interactions at metal⁃support interfaces and their influence on the electroactivity and stability of Pt nanoparticles［J］.Journal of Materials Chemistry A，2020，8（3）：1368-1377.
14	GALEANO C， MEIER J C， PEINECKE V，et al.Toward highly stable electrocatalysts via nanoparticle pore confinement［J］.Journal of the American Chemical Society，2012，134（50）：20457-20465.
15	李峥嵘，申涛，胡冶州，等.有序金属间化合物电催化剂在燃料电池中的应用进展［J］.物理化学学报，2021，37（9）：187-208.
	LI Zhengrong， SHEN Tao， HU Yezhou，et al.Progress on ordered intermetallic electrocatalysts for fuel cells application［J］.Acta Physico-Chimica Sinica，2021，37（9）：187-208.
16	NAJAFISHIRTARI S， BRESCIA R， GUARDIA P，et al.Nanoscale transformations of alumina⁃supported AuCu ordered phase nanocrystals and their activity in CO oxidation［J］.ACS Catalysis，2015，5（4）：2154-2163.
17	LI Junrui， SHARMA S， LIU Xiaoming，et al.Hard-magnet L1₀-CoPt nanoparticles advance fuel cell catalysis［J］.Joule，2019，3（1）：124-135.
18	ZOU Liangliang， FAN Jing， ZHOU Yi，et al.Conversion of PtNi alloy from disordered to ordered for enhanced activity and durability in methanol⁃tolerant oxygen reduction reactions［J］.Nano Research，2015，8（8）：2777-2788.
19	WANG Deli， YU Yingchao， XIN H L，et al.Tuning oxygen reduction reaction activity via controllable dealloying：A model study of ordered Cu₃Pt/C intermetallic nanocatalysts［J］.Nano Letters，2012，12（10）：5230-5238.
20	MIURA A， WANG Hongsen， LEONARD B M，et al.Synthesis of intermetallic PtZn nanoparticles by reaction of Pt nanoparticles with Zn vapor and their application as fuel cell catalysts［J］.Chemistry of Materials，2009，21（13）：2661-2667.
21	GUNJI Takao， TANABE T， JEEVAGAN A J，et al.Facile route for the preparation of ordered intermetallic Pt₃Pb-PtPb core⁃shell nanoparticles and its enhanced activity for alkaline methanol and ethanol oxidation［J］.Journal of Power Sources，2015，273：990- 998
22	SUN S， MURRAY C B， WELLER D，et al.Monodisperse FePt nano⁃
	particles and ferromagnetic FePt nanocrystal superlattices［J］.Sci⁃
	ence，2000，287（5460）：1989-1992.
23	KOCKRICK E， KRAWIEC P， SCHNELLE W，et al.Space-con⁃
	fined formation of FePt nanoparticles in ordered mesoporous silica SBA- 15［J］.Advanced Materials，2007，19（19）：3021-3026.
24	JI X， LEE K T， HOLDEN R，et al.Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes［J］.Nature Chemistry，2010，2（4）：286-293.
25	KANG E， JUNG H， PARK J G，et al.Block copolymer directed one⁃pot simple synthesis of L1₀-phase FePt nanoparticles inside ordered mesoporous aluminosilicate/carbon composites［J］.ACS Nano，2011，5（2）：1018-1025.
26	KIM J， LEE Y， SUN Shouheng.Structurally ordered FePt nanoparticles and their enhanced catalysis for oxygen reduction reaction［J］.Journal of the American Chemical Society，2010，132（14）：4996-4997.
27	WANG Tanyuan， LIANG Jiashun， ZHAO Zhonglong，et al.Sub-6 nm fully ordered L1₀-Pt-Ni-Co nanoparticles enhance oxygen reduction via Co doping induced ferromagnetism enhancement and optimized surface strain［J］.Advanced Energy Materials，2019，9（17）.Doi：10.1002/aenm.201803771 . doi: 10.1002/aenm.201803771
28	KIM H Y， CHO S， SA Y J，et al.Self⁃supported mesostructured Pt-based bimetallic nanospheres containing an intermetallic phase
	as ultrastable oxygen reduction electrocatalysts［J］.Small，2016，12（38）：5347-5353.
29	KIM H Y， KIM J M，HA Y，et al.Activity origin and multifunctionality of Pt-based intermetallic nanostructures for efficient electrocatalysis［J］.ACS Catalysis，2019，9（12）：11242-11254.
30	LEE J， YOO J M， YE Y，et al.Development of highly stable and mass transfer⁃enhanced cathode catalysts：Support⁃free electrospun intermetallic FePt nanotubes for polymer electrolyte membrane fuel cells［J］.Advanced Energy Materials，2015，5（11）.Doi：10.1002/aenm.201402093 . doi: 10.1002/aenm.201402093
31	KIM H Y， JOO S H.Recent advances in nanostructured intermetallic electrocatalysts for renewable energy conversion reactions［J］.Journal of Materials Chemistry A，2020，8（17）：8195-8217.
32	YAN Yucong， DU J S， GILROY K D，et al.Intermetallic nanocrystals：Syntheses and catalytic applications［J］.Advanced Materials，2017，29（14）.Doi：10.1002/adma.201605997 . doi: 10.1002/adma.201605997
33	LEONARD B M， BHUVANESH N S P， SCHAAK R E.Low⁃temperature polyol synthesis of AuCuSn₂ and AuNiSn₂：Using solution chemistry to access ternary intermetallic compounds as nanocrystals［J］.Journal of the American Chemical Society，2005，127（20）：7326-7327.
34	CHEN Wei， YU Rong， LI Lingling，et al.A seed⁃based diffusion route to monodisperse intermetallic CuAu nanocrystals［J］.Angewandte Chemie，2010，122（16）：2979-2983.
35	FENG Quanchen， ZHAO Shu， HE Dongsheng，et al.Strain engineering to enhance the electrooxidation performance of atomic⁃layer Pt on intermetallic Pt₃Ga［J］.Journal of the American Chemical Society，2018，140（8）：2773-2776.
36	SRA A K， EWERS T D， SCHAAK R E.Direct solution synthesis of intermetallic AuCu and AuCu₃ nanocrystals and nanowire networks［J］.Chemistry of Materials，2005，17（4）：758-766.
37	CABLE R E， SCHAAK R E.Low⁃temperature solution synthesis of nanocrystalline binary intermetallic compounds using the polyol process［J］.Chemistry of Materials，2005，17（26）：6835-6841.
38	RONG Hongpan， MAO Junjie， XIN Pingyu，et al.Kinetically controlling surface structure to construct defect⁃rich intermetallic nanocrystals：Effective and stable catalysts［J］.Advanced Materials，2016，28（13）：2540-2546.
39	BU Lingzheng， ZHANG Nan， GUO Shaojun，et al.Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis［J］.Science，2016，354（6318）：1410-1414.
40	SINGH K， TETTEH E B， LEE H Y，et al.Tailor⁃made Pt catalysts with improved oxygen reduction reaction stability/durabili⁃ ty［J］.ACS Catalysis，2019，9（9）：8622-8645.
41	ZHOU Ming， LI Can， FANG Jiye.Noble-metal based random alloy and intermetallic nanocrystals：Syntheses and applications［J］.Chemical Reviews，2021，121（2）：736-795.

[1]	LUO Chengling, FAN Xiaofan. Research progress of microstructure-regulated catalysts for urea oxidation reactions [J]. Inorganic Chemicals Industry, 2025, 57(2): 26-35.
[2]	ZHU Jicheng, YANG Qixin, LIANG Haoquan, WANG Zengkun, OUYANG Fugui, DI Jing, GAI Xikun. Effect of confined catalyst Ni@S2 on performance of methane dry reforming reaction [J]. Inorganic Chemicals Industry, 2025, 57(2): 138-146.
[3]	LIU Qingcui, LI Yunqing, PANG Ruiqi, TIAN Yaping, CHEN Yiying, LI Fang, LI Qiming. Preparation of Zn/Co-ZIF derived porous carbon supported Pd as catalyst and its application to formic acid dehydrogenation [J]. Inorganic Chemicals Industry, 2024, 56(6): 147-152.
[4]	LI Jiangpeng, ZHANG Huibin. Synergistic degradation of methylene blue by photo-Fenton and photocatalytic with 3D porous LaFeO₃/CeO₂/SrTiO₃ [J]. Inorganic Chemicals Industry, 2024, 56(5): 141-148.
[5]	WANG Chao, SONG Guoliang, XIAO Han. Industrial application of THFS-2 sulfurized reforming prehydrogenation catalysts [J]. Inorganic Chemicals Industry, 2024, 56(5): 94-100.
[6]	JIN Suna, LÜ Ruiliang. Research progress of heterogeneous catalytic ozonation for industrial wastewater treatment [J]. Inorganic Chemicals Industry, 2024, 56(3): 28-38.
[7]	CHEN Xingliang, FAN Wenjuan, CHANG Hui, HUANG Haiping, JIANG Zhiqiang. Study on collaborative strategy between Fe³⁺ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution [J]. Inorganic Chemicals Industry, 2024, 56(2): 152-158.
[8]	HOU Zhanggui, WU Chongchong, ZHANG Siran. Research progress of CO₂ conversion via Reverse Water-Gas Shift reaction [J]. Inorganic Chemicals Industry, 2024, 56(11): 105-115.
[9]	MA Yihong, CHEN Xingtao, TANG Lei. Treatment of printing wastewater by chemical coagulation-TiO₂/g-C₃N₅ photocatalytic degradation [J]. Inorganic Chemicals Industry, 2024, 56(10): 151-158.
[10]	JIN Shengshi, LIU Kaijie, LIU Qiuwen, ZHANG Yibo, YANG Xiangguang. Study on catalytic performance of phosphoric acid modified CeO₂ nanorod supported Pt catalyst for propane combustion [J]. Inorganic Chemicals Industry, 2024, 56(1): 141-148.
[11]	GUO Zini, QU Jiyan, LUO Jianhong. Oxidation of NO _x by low-temperature plasma using catalysts with different band gaps [J]. Inorganic Chemicals Industry, 2023, 55(9): 126-133.
[12]	LIU Wei, XU Yan, CHEN Yongsheng, SUN Chunhui, ZHANG Jingcheng, ZHU Jinjian, LIU Yang. Effect of alkaline earth metals on performance of Cu/Al₂O₃ ester hydrogenation catalyst [J]. Inorganic Chemicals Industry, 2023, 55(9): 140-144.
[13]	MA Chao, HU Jieqiong, XIE Ming, CHEN Yongtai, ZHANG Qiao, CHEN Song, FANG Jiheng, QIU Leqi. Research progress of preparation of Pt-Au-Ni nanoalloys [J]. Inorganic Chemicals Industry, 2023, 55(9): 26-32.
[14]	YANG Bo, LIANG Zhiyan, LIU Wenyuan, CAO Jiazhen, LIU Xinyue, XING Mingyang. Research progress of application of molybdenum-based catalytic materials for water pollution control [J]. Inorganic Chemicals Industry, 2023, 55(8): 1-12.
[15]	MA Zhiyuan, LÜ Dawei, WANG Hui, JIN Nannan, ZHU Jinjian, ZHANG Jingcheng. Industrial application of THDS-2/3 catalyst in capacity expansion of hydrofining plant [J]. Inorganic Chemicals Industry, 2023, 55(8): 140-144.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress on preparation method of platinum based ordered nano catalysts

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 41

Related Articles 15

Metrics

Comments

Recommended 0