无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (9): 55-.

• 论文 • 上一篇    下一篇

利用电石渣和氯化镁制氢氧化镁工艺研究

李阳1,姜丽娜2,李洪玲1,但建明1   

  1. 1.石河子大学化学化工学院,新疆石河子 832003;2.新疆伊利职业技术学院
  • 出版日期:2011-09-10 发布日期:2011-09-07

Study on preparation magnesium hydroxide by using carbide slag and magnesium chloride

Li Yang1,Jiang Lina2,Li Hongling1,Dan Jianming1   

  1. 1.School of Chemistry and Chemical Engineering,Shihezi University,Shihezi 832003,China;2.Xinjiang Yili Vocational College of Technology
  • Published:2011-09-10 Online:2011-09-07

摘要: 采用电石渣和盐湖氯化镁为原料制取氢氧化镁。电石渣(氢氧化钙)与氯化铵反应生成氨气,将氨气通入氯化镁溶液中制备氢氧化镁。通过单因素实验和正交实验得出最佳工艺条件:氯化铵与氯化镁物质的量比为5.0,氯化镁浓度为2.0 mol/L,反应时间为60 min,反应温度为25 ℃,陈化时间为2 h。在该条件下氢氧化镁的生成率可达到89%,纯度也可达到98%以上。通过X射线衍射(XRD)及扫描电镜(SEM)表征表明,氢氧化镁产品为片状,粒径在800 nm左右。采用该方法制备氢氧化镁,不仅可以解决电石渣和盐湖氯化镁的大量堆放问题,而且可以制备出高品质的氢氧化镁产品。

关键词: 电石渣, 氯化铵, 氯化镁, 氢氧化镁

Abstract: Magnesium hydroxide was obtained by using carbide slag and magnesium chloride as raw materials.Through reaction of carbide slag(calcium hydroxide)and ammonium chloride to prepare ammonia air,then put ammonia air into magnesium chloride solution to get magnesium hydroxide.Through single factor experiments,the optimum technology conditions were obtained:amount-of-substance ratio of ammonium chloride to magnesium chloride was 5.0,concentration of magnesium chloride was 2.0 mol/L,reaction time was 60 min,reaction temperature was 25 ℃,and aging time was 2 h.Under those conditions productive rate of magnesium hydroxide could reach 89% and its purity was higher than 98%.XRD and SEM results showed the product was flaky powder with about 800 nm in particle size.Method of preparing Mg(OH)2 not only solves the stacked carbide slag,but also can get high-quality Mg(OH)2.

Key words: carbide slag, ammonium chloride, magnesium chloride, magnesium hydroxide

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