无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (5): 35-.

• 论文 • 上一篇    下一篇

有机改性膨润土用于含铬废水处理和 铬污染土壤修复的探究

刘 旦1,平成君1,肖 磊1,金士威1,2,徐旺生1,邹 彬1   

  1. 1.武汉工程大学化工与制药学院,绿色化工过程教育部重点实验室,湖北武汉 430073;
    2.中南民族大学化学与材料科学学院
  • 出版日期:2016-05-10 发布日期:2016-05-16

Study on disposal of chromium wastewater and remediation of chromium-contaminated soil by organo-bentonite

Liu Dan1,Ping Chengjun1,Xiao Lei1,Jin Shiwei1,2,Xu Wangsheng1,Zou Bin1   

  1. 1.Key Laboratory for Green Chemical Process of Ministry of Education,School of Chemical Engineering &
     Pharmacy,Wuhan Institute of Technology,Wuhan 430073,China;
    2.School of Chemistry & Materials Science,South-Central University for Nationalities
  • Published:2016-05-10 Online:2016-05-16

摘要: 用有机改性剂十六烷基三甲基溴化铵(CTMAB)对钠基膨润土进行改性,研究了钠基膨润土改性前后对废水中Cr(Ⅵ)的吸附效果。探讨了吸附时间、溶液pH、膨润土投加量、吸附温度等对吸附效果的影响。实验得到钠基膨润土的最佳吸附条件:40 min、pH=7.0、15 g/L、20~30 ℃;改性膨润土的最佳吸附条件:40 min、pH=6.0、10 g/L、30 ℃。通过有机改性,吸附效果从50%显著提升至95%以上,表明改性膨润土对废水中Cr(Ⅵ)具有更好的去除效果。实验进一步探讨了改性膨润土对Cr(Ⅵ)的吸附规律,改性膨润土对Cr(Ⅵ)的吸附行为符合Langmuir方程,还初步考察了改性膨润土应用于铬污染土壤的修复效果,对铬污染土壤的修复效果明显优于钠基膨润土,去除率达90%以上。

关键词: 钠基膨润土, 有机改性, 铬离子, 土壤修复

Abstract: Na-based bentonite was modified with cetyl trimethyl ammonium bromide(CTMAB)as the modifier.The absorption efficiency of Na-bentonite to chromium ion(Ⅵ) in wastewater before and after organic modification was investigated.The influences of absorption time,solution pH,feeding amount of bentonite,and temperature etc.on the absorption effect were studied.The optimal adsorption conditions for Na-based bentonite were obtained by experiment as follows:40 min,pH=7.0, 15 g/L,and 20~30 ℃;and for organic modified bentonite were as follows:40 min,pH=6.0,10 g/L,and 30 ℃.After modifica- tion the adsorption rate significantly increased from 50% to 95% above.Then the adsorption isotherms of organic bentonite was studied in chromium wastewater and proved the adsorption process met the Langmuir isotherm model.The remediation effect of organic modified bentonite applied to Cr(Ⅵ) contaminated soil was also investigated preliminarily.Results showed organic modified bentonite′s remediation effect to Cr(Ⅵ) contaminated soil was obviously better than that of Na-based bentonite and the removal rates could be up to 90% above.

Key words: Na-bentonite, organic modification, chromium ions, soil remediation

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