无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (11): 44-.

• 论文 • 上一篇    下一篇

废浆零排放的石灰-烟道气卤水净化新工艺

颜 鑫1,卢云峰2,阳铁建1   

  1. 1.湖南化工职业技术学院,湖南株洲 412004;2.石家庄市科林威尔环保科技有限公司
  • 出版日期:2016-11-10 发布日期:2016-11-28

New technology of lime and flue-gas brine purification with waste-slurry zero discharge

Yan Xin1,Lu Yunfeng2,Yang Tiejian1   

  1. 1.Hunan Chemical Technology College,Zhuzhou 412004,China;
    2.Shijiazhuang City Colin Weir Environmental Protection Technology Co.,Ltd.
  • Published:2016-11-10 Online:2016-11-28

摘要: 首先指出了目前石灰-烟道气卤水净化工艺存在将含有大量钙镁泥和轻质碳酸钙(PCC)的“废浆”埋入废井的重大工艺缺陷,然后提出了废浆零排放的石灰-烟道气卤水净化新工艺。该工艺用专业消化机代替乳化桶,实现石灰乳连续生产、石灰渣自动剔除,通过添加聚丙烯酸钠为结晶助剂、静置陈化等手段使氢氧化镁浮于饱和食盐水表面,从而与沉于底部的二水石膏分离,实现了对氢氧化镁、二水石膏、PCC和卤水的几乎全部回收利用。以年产1×106 t精制盐的盐企为例,可回收氢氧化镁4 000 t、回收二水石膏1.39×105 t、回收PCC 2.6×104 t、回收卤水6.25× 105 t,具有显著的经济效益和社会效益。

关键词: 石灰-烟道气卤水净化工艺, 废浆, 氢氧化镁, 二水石膏, 轻质碳酸钙

Abstract: Firstly,it pointed out the lime-flue gas brine purification technology had an significant defect that there was a lot of calcium and magnesium mud and light calcium carbonate(PCC) ‘waste-slurry’ having been buried in abandoned wells.It then proposed a new technology of lime-flue gas brine purification with waste-slurry zero discharge.This new technology used a professional digestion machine instead of emulsifying barrel,so as to achieve continuous production of lime milk and lime slag automatic elimination.Also by adding sodium polyacrylate as a crystallization additive,standing,and maturing etc.to make magnesium hydroxide float on the surface of saturated salt water,so as to realize the separation from dehydrate-gypsum settled in the bottom.Finally the all recycling of magnesium hydroxide,dehydrate-gypsum,PCC,and brine almost was realized. With a refined salt enterprise with annual output of 1×106 t as an example,4 000 t magnesium hydroxide,1.39×105 t dehy- drate-gypsum,26 000 t PCC,and 6.25×105 t brine could be recycled,with remarkable economic and social benefits.

Key words: lime flue gas brine purification process, waste-slurry, magnesium hydroxide, dehydrate-gypsum, PCC

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