无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2010, Vol. 0 ›› Issue (12): 23-.

• 论文 • 上一篇    下一篇

西宁盆地坡缕石黏土对铅离子吸附性能的研究

张兴儒,崔明鑫,郭会宾,赵启文,王晓宁   

  1. 青海大学化工学院
  • 发布日期:2011-04-18

Study on adsorption performance of Pb2+ onto palygorskite clay in Xining basin

Zhang Xingru,Cui Mingxin,Guo Huibin,Zhao Qiwen,Wang Xiaoning   

  1. School of Chemical Engineering,Qinghai University
  • Online:2011-04-18

摘要: 以西宁盆地坡缕石黏土为吸附剂,研究了其对铅离子吸附性能的影响。考察了黏土的改性方法、搅拌时间、黏土投加量、吸附温度、溶液初始铅离子质量浓度等因素对吸附效果的影响。结果表明:西宁盆地坡缕石黏土对铅离子具有良好的吸附性能。适宜的吸附条件:采用硫酸为改性剂,硫酸用量为10 g黏土加入0.049 g硫酸;搅拌时间为50 min,黏土投加量为100 mL铅液加入0.10~0.15 g黏土,吸附温度为室温。在此条件下,当溶液中铅离子初始质量浓度为107.65 mg/L时,黏土对铅离子的吸附容量达到107 mg/g以上,铅离子去除率接近100%。在实验质量浓度范围内,铅离子在黏土上的吸附符合Langmuir等温线。

关键词: 西宁盆地, 坡缕石黏土, 铅离子, 吸附性能

Abstract: As the adsorbent,the adsorption performance of palygorskite clay in Xining basin to Pb2+ was studied.Influences of the factors,such as modified methods of clay,stirring time,clay dosage,adsorption temperature,and initial Pb2+ mass concentration of the solution,on adsorption effects were investigated.Results showed that the palygorskite clay in Xining basin exhibited good adsorption performance to Pb2+;when using sulfuric acid modifying the clay,the appropriate amount of sulfuric acid was 0.049 g per 10 g clay;and the appropriate adsorption conditions were that stirring time of 50 min,clay dosage of 0.10~0.15 g/100 mL Pb2+ solution,and room temperature.Under these conditions,the adsorption capacity of Pb2+ onto the clay reached over 107 mg/g when the initial mass concentration of Pb2+ in the solution was 107.65 mg/L and the removal ratio of Pb2+ was about 100%.Within the range of experimental mass concentration,the adsorption of Pb2+ onto the clay was consistent with Langmuir isotherm.

Key words: Xining basin, palygorskite clay, Pb2+, adsorption performance

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