工业钛液合成钛酸钠负极及其储钠性能

doi:10.19964/j.issn.1006-4990.2023-0055

Abstract

Abstract:

When traditional methods are used to prepare sodium titanate materials，the titanium sources used（such as TiO₂，titanium tetrisopropyl alcohol，etc.） are all pure analytical reagents，which are processed by titanium-bearing minerals through multiple processes.The cost is high and the process of preparing sodium titanate is lengthy.Using industrial titanium liquid as the raw material，the metatitanic acid precursor prepared by atmospheric pressure hydrolysis was used as the titanium source，and the sodium titanate anode was synthesized by the high-temperature solid-phase method，which shortened the preparation process of sodium titanate.The results showed that the synthesized sodium titanate was mainly a mixed phase of Na₂Ti₃O₇ and Na₂Ti₆O₁₃，and its initial discharge specific capacity could reach 233.77 mA·h/g at a low current density of 17.7 mA/g.After 200 times at the current density of 88.5 mA/g，the discharge specific capacity of the prepared sodium titanate material was 26.87 mA·h/g，its capacity retention rate was 47.56%，and its charge-discharge efficiency was 99.54%.After further analysis，the sodium storage process of the prepared mixed sodium titanate was dominated by pseudocapacitive behavior.

Key words: metatilinic acid, sodium titanate, anode material, sodium-ion battery, energy storage

CLC Number:

TQ134.11

ZHANG Rui, WANG Zhenghao, CHEN Liang, GUO Xiaodong, LUO Dongmei. Synthesis of sodium titanate anode from industrial titanium liquid and its sodium storage performance[J]. Inorganic Chemicals Industry, 2023, 55(12): 66-73.

Figures/Tables 11

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References 31

1	DONG Shengyang， LV Nan， WU Yulin， et al. Titanates for sodium-ion storage［J］. Nano Today， 2022， 42：101349. doi: 10.1016/j.nantod.2021.101349
2	DELMAS C. Sodium and sodium-ion batteries：50 years of resear-ch［J］. Advanced Energy Materials， 2018， 8（17）：1703137. doi: 10.1002/aenm.v8.17
3	PLACKE T， KLOEPSCH R， DÜHNEN S， et al. Lithium ion，lithium metal，and alternative rechargeable battery technologies：The odyssey for high energy density［J］. Journal of Solid State Electrochemistry， 2017， 21（7）：1939-1964. doi: 10.1007/s10008-017-3610-7
4	MATSUMOTO K， HWANG J， KAUSHIK S， et al. Advances in sodium secondary batteries utilizing ionic liquid electrolytes［J］. Energy & Environmental Science， 2019， 12（11）：3247-3287.
5	LIBICH J， MINDA J， SEDLAŘÍKOVÁ M， et al. Sodium-ion batteries：Electrochemical properties of sodium titanate as negative electrode［J］. Journal of Energy Storage， 2020， 27：101150. doi: 10.1016/j.est.2019.101150
6	HASA I， MARIYAPPAN S， SAUREL D， et al. Challenges of today for Na-based batteries of the future：From materials to cell metri-cs［J］. Journal of Power Sources， 2021， 482：228872. doi: 10.1016/j.jpowsour.2020.228872
7	LI Shiyou， WEN Shuxiang， DING Hao， et al. Improve the electrochemical performance of Na₂Ti₃O₇ nanorod through pitch coat-ing［J］. ACS Sustainable Chemistry & Engineering， 2022， 10（13）：4247-4257.
8	MUKHERJEE A， DAS D， BANERJEE S， et al. Synthesis and electrochemical performance of in situ and ex-situ carbon-coated Na₂Ti₃O₇，as a promising anode for sodium-ion batteries［J］. Electrochemical Science Advances， 2022. Doi：10.1002/elsa.202100118 .
9	张希，杨军，乔志军，等. 炭负极材料储钠机理的研究进展［J］. 化工新型材料， 2023， 51（1）：51-55.
	ZHANG Xi， YANG Jun， QIAO Zhijun， et al. Application progress of carbon anode materials in sodium-ion batteries［J］. New Chemical Materials， 2023， 51（1）：51-55.
10	王祺. 钠离子电池负极材料的研究进展［J］. 化工技术与开发， 2022， 51（8）：52-54，5.
	WANG Qi. Research progress of anode materials for sodium ion batteries［J］. Technology & Development of Chemical Industry， 2022， 51（8）：52-54，5.
11	马存双，万延华，许永开，等. 超薄氮硫掺杂碳包覆二硫化铁的制备及储钠性能［J］. 无机盐工业， 2022， 54（6）：55-60.
	MA Cunshuang， WAN Yanhua， XU Yongkai， et al. Preparation and sodium storage properties of ultra-thin N and S doped carbon coated FeS₂ ［J］. Inorganic Chemicals Industry， 2022， 54（6）：55-60.
12	包科杰，路凌然. 新能源汽车电池负极材料的制备与性能研究［J］. 无机盐工业， 2021， 53（3）：54-59.
	BAO Kejie， LU Lingran. Study on preparation and performance of negative electrode materials for batteries of new energy vehicl-es［J］. Inorganic Chemicals Industry， 2021， 53（3）：54-59.
13	李凡群，赵星星. 钠离子电池负极材料的研究现状［J］. 电池， 2017， 47（2）：120-122.
	LI Fanqun， ZHAO Xingxing. Research status quo of anode materials for sodium ion battery［J］. Battery Bimonthly， 2017， 47（2）：120-122.
14	朱子翼，张英杰，董鹏，等. 高性能钠离子电池负极材料的研究进展［J］. 化工进展， 2019， 38（5）：2222-2232.
	ZHU Ziyi， ZHANG Yingjie， DONG Peng， et al. Research progress of anode materials for high performance sodium-ion batteries［J］. Chemical Industry and Engineering Progress， 2019， 38（5）：2222-2232.
15	党荣彬，陆雅翔，容晓晖，等. 钠离子电池关键材料研究及工程化探索进展［J］. 科学通报， 2022， 67（30）：3546-3564.
	DANG Rongbin， LU Yaxiang， RONG Xiaohui， et al. Research progress of key materials and engineering exploration for Na-ion batteries［J］. Chinese Science Bulletin， 2022， 67（30）：3546-3564.
16	SENGUTTUVAN P， ROUSSE G， SEZNEC V， et al. Na₂Ti₃O₇：Lowest voltage ever reported oxide insertion electrode for sodium ion batteries［J］. Chemistry of Materials， 2011， 23（18）：4109-4111. doi: 10.1021/cm202076g
17	RUDOLA A， SARAVANAN K， DEVARAJ S， et al. Na₂Ti₆O₁₃：A potential anode for grid-storage sodium-ion batteries［J］. Chemical Communications， 2013， 49（67）：7451-7453. doi: 10.1039/c3cc44381g
18	SHIRPOUR M， CABANA J， DOEFF M. New materials based on a layered sodium titanate for dual electrochemical Na and Li intercalation systems［J］. Energy & Environmental Science， 2013， 6（8）：2538-2547.
19	CECH O， VANÝSEK P， CHLADIL L， et al. Mixed sodium titanate as an anode for a sodium-ion battery［J］. ECS Transactions， 2016， 74（1）：331-337. doi: 10.1149/07401.0331ecst
20	WU Chunjin， HUA Weibo， ZHANG Zheng， et al. Design and synthesis of layered Na₂Ti₃O₇ and tunnel Na₂Ti₆O₁₃ hybrid structures with enhanced electrochemical behavior for sodium-ion batteri- es［J］. Advanced Science， 2018， 5（9）：1800519. doi: 10.1002/advs.v5.9
21	HWANG J， CAHYADI H S， CHANG W， et al. Uniform and ultrathin carbon-layer coated layered Na₂Ti₃O₇ and tunnel Na₂Ti₆O₁₃ hybrid with enhanced electrochemical performance for anodes in sodium ion batteries［J］. The Journal of Supercritical Fluids， 2019， 148：116-129. doi: 10.1016/j.supflu.2019.03.006
22	CHANDEL S， LEE S， LEE S， et al. Hierarchically nanorod structured Na₂Ti₆O₁₃/Na₂Ti₃O₇ nanocomposite as a superior anode for high-performance sodium ion battery［J］. Journal of Electroanalytical Chemistry， 2020， 877：114747. doi: 10.1016/j.jelechem.2020.114747
23	HO C K， LI C Y V， CHAN K Y. Scalable template-free synthesis of Na₂Ti₃O₇/Na₂Ti₆O₁₃ nanorods with composition tunable for synergistic performance in sodium-ion batteries［J］. Industrial & Engineering Chemistry Research， 2016， 55（38）：10065-10072. doi: 10.1021/acs.iecr.6b01867
24	BHARDWAJ H S， RAMIREDDY T， PRADEEP A， et al. Understanding the cyclic（In）stability and the effects of presence of a stable conducting network on the electrochemical performances of Na₂Ti₃O₇ ［J］. ChemElectroChem， 2018， 5（8）：1219-1229. doi: 10.1002/celc.v5.8
25	PIFFET C， VERTRUYEN B， HATERT F， et al. High temperature X-ray diffraction study of the formation of Na₂Ti₃O₇ from a mixture of sodium carbonate and titanium oxide［J］. Journal of Energy Chemistry， 2022， 65：210-218. doi: 10.1016/j.jechem.2021.05.050
26	ZARRABEITIA M， CASTILLO-MARTÍNEZ E， LÓPEZ DEL AMO J M， et al. Identification of the critical synthesis parameters for enhanced cycling stability of Na-ion anode material Na₂Ti₃O₇ ［J］. Acta Materialia， 2016， 104：125-130. doi: 10.1016/j.actamat.2015.11.033
27	CAO Yang， YE Qi， WANG Fanfan， et al. A new triclinic phase Na₂Ti₃O₇ anode for sodium-ion battery［J］. Advanced Functional Materials， 2020， 30（39）：2003733. doi: 10.1002/adfm.v30.39
28	PAN Jun， WANG Nana， Dan LÜ， et al. Layered structure Na₂Ti₃O₇ as a promising anode material for sodium-ion batteri-es［J］. Advanced Energy and Sustainability Research， 2021， 2（6）：2000095. doi: 10.1002/aesr.v2.6
29	吴乾鑫，刘磊，孙晋蒙，等. 磺酸基修饰石墨烯复合材料的储钠性能研究［J］. 材料工程， 2022， 50（4）：36-43. doi: 10.11868/j.issn.1001-4381.2020.001197
	WU Qianxin， LIU Lei， SUN Jinmeng， et al. Sodium ions storage performance of PSS-rGO composites［J］. Journal of Materials Engineering， 2022， 50（4）：36-43.
30	CHEN Fuyu， YUAN Jing， ZHOU Minquan， et al. Compressible neuron-like 3D few-layered MoS₂/N-doped graphene foam as freestanding and binder-free electrodes for high-performance lithium-ion batteries［J］. ACS Applied Energy Materials， 2022， 5（6）：7249-7259. doi: 10.1021/acsaem.2c00796
31	郑钧昊，吴源基，殷咏诗，等. 高性能氮掺杂中空碳纳米盒的制备及其在钠离子负极中的应用［J］. 材料研究与应用， 2022， 16（5）：804-811.
	ZHENG Junhao， WU Yuanji， YIN Yongshi， et al. Preparation of high performance nitrogen doped hollow carbon box and their application in sodium anode［J］. Materials Research and Application， 2022， 16（5）：804-811.

制备方法	原料	产物物相	电流密度/循环次数/放电比容量
水热法^［20］（850 ℃，焙烧12 h）	锐钛TiO₂，NaOH	Na₂Ti₃O₇/Na₂Ti₆O₁₃	20 mA/g，100次，约80 mA·h/g；2 000 mA/g， 4 000次，19.45 mA·h/g
溶胶-凝胶法^［24］（780 ℃，焙烧10 h）	丁醇钛，NaOH	Na₂Ti₃O₇；Na₂Ti₃O₇/MWCNT	0.2C，50次，8 mA·h/g；0.2C，50次，160 mA·h/g
喷雾干燥法^［25］（800 ℃，8 h； 1 000 ℃，8 h）	TiO₂，Na₂CO₃	800 ℃：Na₂Ti₃O₇； 1 000 ℃：Na₂Ti₃O₇	35.6 mA/g，500次，44 mA·h/g；178 mA/g， 500次，32 mA·h/g
高温固相法^［26］（800 ℃，24 h；800 ℃，20 h）	TiO₂和Na₂CO₃·H₂O，TiO₂和NaOH	24 h：CO-Na₂Ti₃O₇； 20 h：OH-Na₂Ti₃O₇	0.1C，100次，<10 mA·h/g；0.1C，100次，约 76.9 mA·h/g
高温固相法^［27］（800 ℃，20 h；1 000 ℃，20 h）	TiO₂（锐钛与金红石混合）和Na₂CO₃	m-Na₂Ti₃O₇；t-Na₂Ti₃O₇	20 mA/g，20次，35.5 mA·h/g；20 mA/g，20次，约92 mA·h/g
高温固相法（800 ℃，20 h）	工业钛液水解得到的偏钛酸，Na₂CO₃	Na₂Ti₃O₇/Na₂Ti₆O₁₃	88.5 mA/g，200次，26.87 mA·h/g

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Synthesis of sodium titanate anode from industrial titanium liquid and its sodium storage performance

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