菌渣生物炭负载四氧化三铁催化降解罗丹明B

doi:10.19964/j.issn.1006-4990.2022-0370

Abstract

Abstract:

Considering the high cost of catalyst carriers，it is significant to seek cheap carrier preparation method for synthesizing catalysts.The porous biochar（PRBC） was prepared as the carrier by pyrolysis of penicillin residue，and Fe₃O₄@PRBC was synthesized by co-precipitation loaded with Fe₃O₄.The catalysts were characterized by SEM，XRD，FT-IR and pore structure analysis，and the effects of different systems，catalyst dosage，H₂O₂ dosage，solution pH and Rhodamine B（RhB） concentration on the treatment effect were investigated by using RhB as the target degradation pollutant.The results showed that Fe₃O₄ was successfully loaded on biochar，and the surface of Fe₃O₄@PRBC was rough and porous with a specific surface area of 1 210.54 m²/g.The H₂O₂/Fe₃O₄@PRBC system showed outstanding catalytic characteristics.When the dosage of Fe₃O₄@PRBC was 0.8 g/L，H₂O₂ dosage was 30 mmol/L，the degradation rate of RhB was exceeded 90% in the range of pH=3~11.After recycling for 4 times，the degradation rate could still reach 90%.The free radical quenching experiment showed that the main active substances that catalyzed the degradation of RhB were ·OH and ·O₂^-.The Fenton-like degradation test was carried out on actual printing and dyeing wastewater，the COD removal rate was higher than 80%，and the chromaticity removal rate reached 100%.

Key words: biochar, Fe₃O₄, heterogeneous Fenton, Rhodamine B, penicillin residue

CLC Number:

TQ138.11

LIU Rui, GAO Wei, ZHANG Wenjing, AN Hongxue, LI Zaixing. Catalytic degradation of Rhodamine B by ferroferric oxide-loaded bacterial residue biochar[J]. Inorganic Chemicals Industry, 2023, 55(4): 111-119.

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样品	制备方法	反应条件	降解率/%	循环性能
Fe₃O₄@PRBC	青霉素菌渣热解制备生物炭、共沉淀法负载Fe₃O₄	pH=3、催化剂用量为0.8 g/L、H₂O₂用量为30 mmol/L	97.30	循环4次，降解率仍大于90%
磁性Fe₃O₄纳米微球^[34]	乙二醇溶剂热法制备Fe₃O₄微球	pH=3、催化剂用量为1.2 g/L、H₂O₂用量为140 mmol/L	接近完全去除	未研究
Fe₃O₄@NiSiO₃纳米颗粒^[35]	采用Ni刻蚀Fe₃O₄@SiO₂外壳制备 Fe₃O₄@NiSiO₃纳米颗粒	pH=5.5、催化剂用量为1.0 g/L、H₂O₂用量为2.50%	大于95	循环5次，未有明显下降
BC-FeOOH^[36]	水热法制备BC-FeOOH	催化剂用量为0.6 g/L、H₂O₂用量为10 mmol/L	达到90	循环3次，降解率在 80%左右
Fe⁰-MF-RGO^[37]	磁性还原氧化石墨烯负载零价纳米铁	pH=7、催化剂用量为1.0 g/L、H₂O₂用量为0.8 mmol/L	98.17	循环5次，降解率为 72.97%
Fe/SBA-15^[38]	以介孔二氧化硅SBA-15为载体，采用等体积浸渍法制备Fe/SBA-15	pH=5.4、催化剂用量为0.15 g/L、n（H₂O₂）/ n（Fe³⁺）=2 000	约93	循环6次，降解率维持在80%

编号	原水COD/（mol·L^-1）	出水COD/（mol·L^-1）	原水色度/（mg·L^-1）
水样1	495	95	65
水样2	506	92	66
水样3	489	66	62

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Catalytic degradation of Rhodamine B by ferroferric oxide-loaded bacterial residue biochar

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