氧化铝包覆锂离子电池正极材料的研究进展

doi:10.19964/j.issn.1006-4990.2022-0098

Abstract

Abstract:

The performance of lithium-ion battery cathode materials is the development bottleneck of lithium battery technology.Recently，alumina（Al₂O₃） coated cathode materials have been widely studied in order to improve the cycle life，thermal stability and multiplier properties of lithium-ion batteries.The Al₂O₃ coatings were divided into three different forms of namely rough，ultra-thin and thick coatings.The role of Al₂O₃ surface coatings in improving cathode material performance was briefly discussed，such as HF scavenger，physical protective barrier，increasing lithium ion diffusion rate，improving thermal stability of cathode material，reacting with LiPF₆ to form electrolyte additive LiPO₂F₂ and inhibiting Jahn-Teller effect，etc.The surface modification methods were introduced，including impregnation method，precipitation method，dry coating process，sputtering method and atomic layer deposition method，etc.and its influence on the cathode materials of lithium cobaltite（LiCoO₂），lithium manganite（LiMn₂O₄），lithium iron phosphate（LiFePO₄） and ternary material（Li-Ni-Co-Mn-O）.At last，the development trend of Al₂O₃ surface coating and atomic layer deposition technology was prospected.

Key words: alumina, surface coating, cathode material, lithium-ion battery

CLC Number:

TQ131.11

XU Qianjin,XU Jingang,TIAN Peng,LIU Kunji,GAO Tingting,NING Guiling. Research progress of alumina coated cathode materials for lithium-ion batteries[J]. Inorganic Chemicals Industry, 2023, 55(1): 46-55.

Figures/Tables 4

References 78

1	TARASCON J M, ARMAND M. Issues and challenges facing rechargeable lithium batteries[J].Nature, 2001, 414（6861）：359- 367.
2	SCHMUCH R, WAGNER R, HÖRPEL G, et al. Performance and cost of materials for lithium-based rechargeable automotive batteries[J].Nature Energy, 2018, 3（4）：267-278.
3	WHITTINGHAM M S. Lithium batteries：50 years of advances to address the next 20 years of climate issues[J].Nano Letters, 2020, 20（12）：8435-8437.
4	ARICÒ A S, BRUCE P, SCROSATI B, et al. Nanostructured materials for advanced energy conversion and storage devices[J].Nature Materials, 2005, 4（5）：366-377.
5	TAO Haisheng, FENG Zhizhong, LIU Hao, et al. Reality and future of rechargeable lithium batteries[J].The Open Materials Science Journal, 2011, 5（1）：204-214.
6	WANG Jiali, ZHAO Yu, ZHANG Xiaoqiang, et al. Trace molybdenum doped Li₂RuO₃ as a cathode material with enhanced performance for lithium ion batteries[J].Sustainable Energy & Fuels, 2019, 3（10）：2697-2704.
7	LIU Jiequn, WANG Jian, CHEN Qingrong, et al. Mg-doped LiMnPO₄/C cathode materials for enhanced lithium storage performance[J].Materials Technology, 2021, 36（3）：153-158.
8	MA Ben, HUANG Xiao, LIU Zhaofeng, et al. Al₂O₃ coated single-crystalline hexagonal nanosheets of LiNi_0.6Co_0.2Mn_0.2O₂ cathode materials for the high-performance lithium-ion batteries[J].Journal of Materials Science, 2022, 57（4）：2857-2869.
9	WANG Fangfang, HONG Ruoyu, LU Xuesong, et al. Improvement of long-term cycling performance of high-nickel cathode materials by ZnO coating[J].Nanotechnology Reviews, 2021, 10（1）：210- 220.
10	ZHAO Bing, XIE Jingwei, ZHUANG Hua, et al. Improved low-temperature performance of surface modified lithium-rich Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode materials for lithium ion batteri-es[J].Solid State Ionics, 2020, 347.Doi：10.1016/j.ssi.2020.2020.115245. doi: 10.1016/j.ssi.2020.2020.115245
11	TAI Zige, ZHU Wei, SHI Ming, et al. Improving electrochemical performances of lithium-rich oxide by cooperatively doping Cr and coating Li₃PO₄ as cathode material for lithium-ion batteri-es[J].Journal of Colloid and Interface Science, 2020, 576：468-475.
12	SUN Yongjiang, LIU Zhedong, CHEN Xiaochun, et al. Enhancing the stabilities and electrochemical performances of LiNi_0.5Co_0.2Mn_0.3O₂ cathode material by simultaneous LiAlO2 coat-ing and Al doping[J].Electrochimica Acta, 2021, 376.Doi：10.1016/j.electacta.2021.138038. doi: 10.1016/j.electacta.2021.138038
13	SUN Yanyun, LIU Sheng, HOU Yukun, et al. In-situ surface modification to stabilize Ni-rich layered oxide cathode with functional electrolyte[J].Journal of Power Sources, 2019, 410-411：115-123.
14	LIU Yuan, LIN Xijie, SUN Yonggang, et al. Precise surface engineering of cathode materials for improved stability of lithium-ion batteries[J].Small：Weinheim an Der Bergstrasse, Germany，2019, 15（32）.Doi：10.1002/smll.201901019. doi: 10.1002/smll.201901019
15	GUAN Peiyuan, ZHOU Lu, YU Zhenlu, et al. Recent progress of surface coating on cathode materials for high-performance lithium-ion batteries[J].Journal of Energy Chemistry, 2020, 43：220- 235.
16	KALLURI S, YOON M，JO M，et al. Li-ion cells：Surface engineering strategies of layered LiCoO₂ cathode material to realize high-energy and high-voltage Li-ion cells[J].Advanced Energy Materials, 2017, 7（1）.Doi：10.1002/aenm.201770006. doi: 10.1002/aenm.201770006
17	NISAR U, MURALIDHARAN N, ESSEHLI R, et al. Valuation of surface coatings in high-energy density lithium-ion battery cathode materials[J].Energy Storage Materials, 2021, 38：309-328.
18	SETENI B, RAPULENYANE N, NGILA J C, et al. Coating effect of LiFePO₄ and Al₂O₃ on Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode surface for lithium ion batteries[J].Journal of Power Sources, 2017, 353：210-220.
19	ZHU Wenchang, HUANG Xue, LIU Tingting, et al. Ultrathin Al₂O₃ coating on LiNi_0.8Co_0.1Mn_0.1O₂ cathode material for enhan-ced cycleability at extended voltage ranges[J].Coatings, 2019, 9（2）.Doi：10.3390/coatings9020092. doi: 10.3390/coatings9020092
20	ZHANG Hailin, XU Jiaqiang, ZHANG Jiujun. Surface-coated LiNi_0.8Co_0.1Mn_0.1O₂（NCM811） cathode materials by Al₂O₃，ZrO₂，and Li₂O-2B₂O₃ thin-layers for improving the performance of lithium ion batteries[J].Frontiers in Materials, 2019, 6.Doi：10.3389/fmats.2019.00309. doi: 10.3389/fmats.2019.00309
21	OH Y，AHN D，NAM S，et al. The effect of Al₂O₃-coating coverage on the electrochemical properties in LiCoO₂ thin films[J].Journal of Solid State Electrochemistry, 2010, 14（7）：1235-1240.
22	GRONER M D, ELAM J W, FABREGUETTE F H, et al. Electrical characterization of thin Al₂O₃ films grown by atomic layer deposition on silicon and various metal substrates[J].Thin Solid Films, 2002, 413（1/2）：186-197.
23	ZHAO Lini, CHEN Guorong, WENG Yuehua, et al. Precise Al₂O₃ coating on LiNi_0.5Co_0.2Mn_0.3O₂ by atomic layer deposition restrains the shuttle effect of transition metals in Li-ion capacitors[J].Che-mical Engineering Journal, 2020, 401.Doi：10.1016/j.cej.2020.126138. doi: 10.1016/j.cej.2020.126138
24	CAO Zhaoxia, LI Yanlei, SHI Mengjiao, et al. Improvement of the cycling performance and thermal stability of lithium-ion batteries by coating cathode materials with Al₂O₃ nano layer[J].Journal of the Electrochemical Society, 2017, 164（2）：A475-A481.
25	HAN J G, KIM K, LEE Y, et al. Scavenging materials to stabilize LiPF₆-containing carbonate-based electrolytes for Li-ion batteries[J].Advanced Materials：Deerfield Beach, Fla.，2019, 31（20）.Doi：10.1002/adma.201804822. doi: 10.1002/adma.201804822
26	WANG Qingsong, JIANG Lihua, YU Yan, et al. Progress of enhancing the safety of lithium ion battery from the electrolyte aspect[J].Nano Energy, 2019, 55：93-114.
27	YANG Hui, ZHUANG G V, ROSS P N Jr. Thermal stability of LiPF₆ salt and Li-ion battery electrolytes containing LiPF₆ [J].Journal of Power Sources, 2006, 161（1）：573-579.
28	LIU Mingzhu, VATAMANU J, CHEN Xinli, et al. Hydrolysis of LiPF₆-containing electrolyte at high voltage[J].ACS Energy Letters, 2021, 6（6）：2096-2102.
29	LIU Jianyong, LIU Na, LIU Daotan, et al. Improving the performances of LiCoO₂ cathode materials by soaking nano-alumina in commercial electrolyte[J].Journal of the Electrochemical Society, 2007, 154（1）：55-63.
30	MYUNG S T, IZUMI K, KOMABA S, et al. Role of alumina coating on Li-Ni-Co-Mn-O particles as positive electrode material for lithium-ion batteries[J].Chemistry of Materials, 2005, 17（14）：3695-3704.
31	HU Die, DU Fanghui, CAO Haishang, et al. An effective strategy to control thickness of Al₂O₃ coating layer on nickel-rich cathode materials[J].Journal of Electroanalytical Chemistry, 2021, 880.Doi：10.1016/j.jelechem.2020.114910. doi: 10.1016/j.jelechem.2020.114910
32	ZHENG J M, ZHANG Z R, WU X B, et al. The effects of AlF₃ coating on the performance of Li[Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ positive electrode material for lithium-ion battery[J].Journal of the Electrochemical Society, 2008, 155（10）：A775-A782.
33	LI Xiangnan, CAO Zhaoxia, DONG Hongyu, et al. Investigation of the structure and performance of Li[Li_0.13Ni_0.305Mn_0.565]O₂ Li-rich cathode materials derived from eco-friendly and simple coating techniques[J].RSC Advances, 2020, 10（6）：3166-3174.
34	LAI Feiyan, ZHANG Xiaohui, WANG Hongqiang, et al. Three-dimension hierarchical Al₂O₃ nanosheets wrapped LiMn₂O₄ with enhanced cycling stability as cathode material for lithium ion batteries[J].ACS Applied Materials & Interfaces, 2016, 8（33）：21656-21665.
35	WANG Q Y, LIU J, MURUGAN A V, et al. High capacity double-layer surface modified Li[Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂ cathode with improved rate capability[J].Journal of Materials Chemistry, 2009, 19（28）：4965-4972.
36	DONG Mingxia, WANG Zhixing, LI Hangkong, et al. Metallurgy inspired formation of homogeneous Al₂O₃ coating layer to improve the electrochemical properties of LiNi_0.8Co_0.1Mn_0.1O₂ cathode material[J].ACS Sustainable Chemistry & Engineering, 2017, 5（11）：10199-10205.
37	JUNG S C, HAN Y K. How do Li atoms pass through the Al₂O₃ coating layer during lithiation in Li-ion batteries？[J].The Journal of Physical Chemistry Letters, 2013, 4（16）：2681-2685.
38	LIU Wen, LI Xifei, XIONG Dongbin, et al. Significantly improving cycling performance of cathodes in lithium ion batteries：The effect of Al₂O₃ and LiAlO₂ coatings on LiNi_0.6Co_0.2Mn_0.2O₂ [J].Nano Energy, 2018, 44：111-120.
39	JUNG R, METZGER M, MAGLIA F, et al. Oxygen release and its effect on the cycling stability of LiNi _x Mn _y Co _z O₂（NMC） cathode materials for Li-ion batteries[J].Journal of the Electrochemical Society, 2017, 164（7）：A1361-A1377.
40	JUNG R, STROBL P, MAGLIA F, et al. Temperature dependence of oxygen release from LiNi_0.6Mn_0.2Co_0.2O₂（NMC622） cathode materials for Li-ion batteries[J].Journal of the Electrochemical Society, 2018, 165（11）：A2869-A2879.
41	JIANG Bing, LI Jingru, LUO Bi, et al. LiPO₂F₂ electrolyte additive for high-performance Li-rich cathode material[J].Journal of Energy Chemistry, 2021, 60：564-571.
42	WANG Chengyun, YU Le, FAN Weizhen, et al. Lithium difluorophosphate as a promising electrolyte lithium additive for high-voltage lithium-ion batteries[J].ACS Applied Energy Materials, 2018, 1（6）：2647-2656.
43	LIU Q Q, MA Lin, DU C Y, et al. Effects of the LiPO₂F₂ additive on unwanted lithium plating in lithium-ion cells[J].Electrochimica Acta, 2018, 263：237-248.
44	LIU Lili, GU Shijie, WANG Shili, et al. A LiPO₂F₂/LiPF₆ dual-salt electrolyte enabled stable cycling performance of nickel-rich lithium ion batteries[J].RSC Advances, 2020, 10（3）：1704-1710.
45	HALL D S, GAUTHIER R, ELDESOKY A, et al. New chemical insights into the beneficial role of Al₂O₃ cathode coatings in lithi-
	um-ion cells[J].ACS Applied Materials & Interfaces, 2019, 11（15）：14095-14100.
46	GUAN Dongsheng, JEEVARAJAN J A, WANG Ying. Enhanced cycleability of LiMn₂O₄ cathodes by atomic layer deposition of nanosized-thin Al₂O₃ coatings[J].Nanoscale, 2011, 3（4）：1465-1469.
47	ZUO Changjian, HU Zongxiang, QI Rui, et al. Double the capacity of manganese spinel for lithium-ion storage by suppression of cooperative Jahn-Teller distortion[J].Advanced Energy Materials, 2020, 10（34）.Doi：10.1002/aenm.202070141. doi: 10.1002/aenm.202070141
48	HERZOG M J, GAUQUELIN N, ESKEN D, et al. Facile dry coating method of high-nickel cathode material by nanostructured fumed alumina（Al₂O₃） improving the performance of lithium-ion batteries[J].Energy Technology, 2021, 9（4）.Doi：10.1002/ente.202100028. doi: 10.1002/ente.202100028
49	MCCORMICK J A, CLOUTIER B L, WEIMER A W, et al. Rotary reactor for atomic layer deposition on large quantities of nanoparticles[J].Journal of Vacuum Science & Technology A：Vacuum, Surfaces，and Films，2007, 25（1）：67-74.
50	DUAN Chenlong, DENG Zhang, CAO Kun, et al. Surface passivation of Fe₃O₄ nanoparticles with Al₂O₃ via atomic layer deposition in a rotating fluidized bed reactor[J].Journal of Vacuum Science & Technology A：Vacuum, Surfaces，and Films，2016, 34（4）.Doi：10.1116/1.4952401. doi: 10.1116/1.4952401
51	JUNG H, PARK W, HOLDER J, et al. Electrochemical properties of high nickel content Li（Ni_0.7Co_0.2Mn_0.1）O₂ with an alumina thin-coating layer as a cathode material for lithium ion batteries[J].Journal of Nanoscience and Nanotechnology, 2020, 20（10）：6505-6511.
52	CHANG Qian, WEI Aijia, LI Wen, et al. Structural and electrochemical characteristics of Al₂O₃-modified LiNi_0.5Mn_1.5O₄ cathode materials for lithium-ion batteries[J].Ceramics International, 2019, 45（4）：5100-5110.
53	CAO Guolin, JIN Zhuomin, ZHU Jie, et al. A green Al₂O₃ metal oxide coating method for LiNi_0.5Co_0.2Mn_0.3O₂ cathode material to improve the high voltage performance[J].Journal of Alloys and Compounds, 2020, 832.Doi：10.1016/j.jallcom.2020.153788. doi: 10.1016/j.jallcom.2020.153788
54	SUN Hao, REN Yurong, LIU Zhen, et al. Enhanced electrochemical properties of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ coated with Al₂O₃ nano-film[J].Vacuum, 2021, 183.Doi：10.1016/j.vacuum.2021.109757. doi: 10.1016/j.vacuum.2021.109757
55	LI Shiyou, LIANG Wenbiao, XIE Jing, et al. Synthesis of hollow microspheres LiNi_0.5Mn_1.5O₄ coated with Al₂O₃ and characterization of the electrochemical capabilities[J].Journal of Electrochemical Energy Conversion and Storage, 2020, 17（3）.Doi：10.1115/1.4045566. doi: 10.1115/1.4045566
56	ZOU Tong, QI Weijing, LIU Xiaoshuo, et al. Improvement of the electrochemical performance of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode material by Al₂O₃ surface coating[J].Journal of Electroanalytical Chemistry, 2020, 859.Doi：10.1016/j.jelechem.2020.113845. doi: 10.1016/j.jelechem.2020.113845
57	SONG Chunlin, LU Junnan, LIU Yuan, et al. Enhanced electrochemical performance of spinel LiNi_0.5Mn_1.5O₄ for Li-ion batteries with moderate Mn³⁺ concentration and nanosized thin Al₂O₃ coating[J].Journal of Materials Science：Materials in Electronics, 2020, 31（6）：4815-4821.
58	PARMAR R, REZVANI S J, NOBILI F, et al. Electrochemical response and structural stability of the Li⁺ ion battery cathode with coated LiMn₂O₄ nanoparticles[J].ACS Applied Energy Materials, 2020, 3（9）：8356-8365.
59	LI Shiyou, ZHU Konglei, ZHAO Dongni, et al. Porous LiMn₂O₄ with Al₂O₃ coating as high-performance positive materials[J].Ionics, 2019, 25（5）：1991-1998.
60	HAN Binghong，KEY B， LAPIDUS S H, et al. From coating to dopant：How the transition metal composition affects alumina coatings on Ni-rich cathodes[J].ACS Applied Materials & Interfaces, 2017, 9（47）：41291-41302.
61	HERZOG M J, ESKEN D, JANEK J. Improved cycling performance of high-nickel NMC by dry powder coating with nanostructured fumed Al₂O₃，TiO₂，and ZrO₂：A comparison[J].Batteries & Supercaps, 2021, 4（6）：1003-1017.
62	KIMURA N, SEKI E, TOOYAMA T, et al. STEM-EELS analysis of improved cycle life of lithium-ion cells with Al₂O₃-coated LiNi_0.8Co_0.1Mn_0.1O₂ cathode active material[J].Journal of Alloys and Compounds, 2021, 869.Doi：10.1016/j.jallcom.2021.159259. doi: 10.1016/j.jallcom.2021.159259
63	JEONG E, HONG Chan，TAK Y，et al. Investigation of interfacial resistance between LiCoO₂ cathode and LiPON electrolyte in the thin film battery[J].Journal of Power Sources, 2006, 159（1）：223-226.
64	CHEN Yangyang, WANG Mingshan, CHEN Junchen, et al. Atomic layer deposition of Al₂O₃ on LiNi_0.68Co_0.10Mn_0.22O₂ for enhanced electrochemical performance[J].Materials Letters, 2020, 271.Doi：10.1016/j.matlet.2020.127771. doi: 10.1016/j.matlet.2020.127771
65	SHI Yang, ZHANG Minghao, QIAN Danna, et al. Ultrathin Al₂O₃ coatings for improved cycling performance and thermal stability of LiNi_0.5Co_0.2Mn_0.3O₂ cathode material[J].Electrochimica Acta, 2016, 203：154-161.
66	LEE Boyi, KRAJEWSKI M, HUANG M K, et al. Spinel LiNi_0.5Mn_1.5O₄ with ultra-thin Al₂O₃ coating for Li-ion batteries：Investigation of improved cycling performance at elevated temperature[J].Journal of Solid State Electrochemistry, 2021, 25（10/11）：2665-2674.
67	ZHOU M M, ZHAO J J, QIU S T, et al. Structural and electrochemical properties of Li_1.2Ni_0.16Mn_0.54Co_0.08O₂-Al₂O₃ composite prepared by atomic layer deposition as the cathode material for LIBs[J].International Journal of Electrochemical Science, 2020, 15（11）：10759-10771.
68	JUNG Y S, CAVANAGH A S, DILLON A C, et al. Enhanced stability of LiCoO₂ cathodes in lithium-ion batteries using surface
	modification by atomic layer deposition[J].Journal of the Electrochemical Society, 2010, 157（1）：A75-A81.
69	TESFAMHRET Y, YOUNESI R, BERG E J. Influence of Al₂O₃ coatings on HF induced transition metal dissolution from lithium-ion cathodes[J].Journal of the Electrochemical Society, 2022, 169（1）.Doi：10.1149/1945-7111/ac4ab1. doi: 10.1149/1945-7111/ac4ab1
70	Yingchun LYU, WU Xia, WANG Kai, et al. An overview on the advances of LiCoO₂ cathodes for lithium-ion batteries[J].Advanced Energy Materials, 2021, 11（2）.Doi：10.1002/aenm.202000982. doi: 10.1002/aenm.202000982
71	KIM Y J, KIM H, KIM B, et al. Electrochemical stability of thin-film LiCoO₂ cathodes by aluminum-oxide coating[J].Chemistry of Materials, 2003, 15（7）：1505-1511.
72	ZHOU Aijun, LIU Qin, WANG Yi, et al. Al₂O₃ surface coating on LiCoO₂ through a facile and scalable wet-chemical method towards high-energy cathode materials withstanding high cutoff voltages[J].Journal of Materials Chemistry A, 2017, 5（46）：24361-24370.
73	HUANG Yimeng, DONG Yanhao, LI Sa, et al. Lithium manganese spinel cathodes for lithium-ion batteries[J].Advanced Energy Materials, 2021, 11（2）.Doi：10.1002/aenm.202000997. doi: 10.1002/aenm.202000997
74	WALLER G H, BROOKE P D, RAINWATER B H, et al. Structure and surface chemistry of Al₂O₃ coated LiMn₂O₄ nanostructured electrodes with improved lifetime[J].Journal of Power Sources, 2016, 306：162-170.
75	ZHANG H H, ZOU Z G, ZHANG S C, et al. A review of the doping modification of LiFePO₄ as a cathode material for lithium ion batteries[J].International Journal of Electrochemical Science, 2020, 15（12）：12041-12067.
76	ZHAO Qunfang, ZHANG Shuqiong, HU Minyi, et al. Recent advances in LiFePO₄ cathode materials for lithium-ion batteries.First-principles research[J].International Journal of Electrochemical Science, 2021, 16.Doi：10.20964/2021.12.11. doi: 10.20964/2021.12.11
77	SON J T. Surface treatment of LiFePO₄ cathode material for lithium secondary battery[J].Journal of the Korean Electrochemical Society, 2010, 13（4）：246-250.
78	WEN Xiaofeng, LIANG Kui, TIAN Lingyun, et al. Al₂O₃ coating on Li_1.256Ni_0.198Co_0.082Mn_0.689O_2.25 with spinel-structure interface layer for superior performance lithium ion batteries[J].Electrochimica Acta, 2018, 260：549-556.

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