钠离子电池正极材料Na3V2（PO4）3研究进展

doi:10.19964/j.issn.1006-4990.2021-0629

Abstract

Abstract:

As a new generation of rechargeable sodium ion battery（SIBs） cathode material，Na₃V₂（PO₄）₃（NVP） has attracted extensive attention due to its advantages of large theoretical capacity，good chemical stability，long service life，high natural abundance and low price.The latest advances in sodium storage mechanism，preparation methods and modification of NVP cathode materials were reviewed.Based on the inherent crystal structure and ion migration mechanism，the sodium storage mechanism of NVP cathode material was summarized.The effect law of different preparation methods on the morphology，particle size distribution，and crystallinity of NVP cathode materials was evaluated.In addition，the main modification methods of NVP cathode materials were summarized for serious volume effect，low electronic conductivity，poor interface compatibility and other problems.Finally，the future application prospects of NVP cathode materials in large?scale energy storage were prospected，the challenges of low electronic conductivity and volume effect were discussed.The potential research directions in controllable preparation of NVP and development of high pressure electrolyte were pointed out.

Key words: Na₃V₂（PO₄）₃, sodium ion batteries, cathode material, reversible capacity, electronic conductivity

CLC Number:

TQ131.12

DONG Peng,ZHOU Yingjie,HOU Minjie,YANG Dongrong,DAI Yongnian,LIANG Feng. Research progress on Na3V₂（PO₄）₃ cathode materials for sodium ion batteries[J]. Inorganic Chemicals Industry, 2022, 54(5): 1-10.

Figures/Tables 9

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Table 2

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References 61

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掺杂元素	成分组成	电压/V	倍率性能/ （mA·h· g^-1）	容量保持率/%	循环次数
Fe³⁺	Na₃V_1.85Fe_0.15（PO₄）₃@citric acid^［41］	2.3～4.3	103.69（1C）	92	1 200
Fe³⁺	Na₃V_1.9Fe_0.1（PO₄）₃@C+RGO^［42］	2.5～4.0	75.2（20C）	89	100
Mn³⁺	Na_3.5Mn_0.5V_1.5（PO₄）₃@ascorbic acid^［43］	2.0～3.8	96.0（20C）	94	3 000
	Na₃V_1.875Mn_0.025（PO₄）₃citric acid^［44］	2.5～4.0	86.7（15C）	91.6	100
	Na₃V_1.8Mn_0.2（PO₄）₃@ citric acid^［45］	2.5～4.0	77.8（30C）	82	10 000
	Na_3.5Mn_0.5V_1.5（PO₄）₃@ascorbic acid^［46］	2.5～4.1	104.5（20C）	87.2	4 000
Co²⁺	Na_3.01V_1.99Co_0.01（PO₄）₃@citric acid^［47］	2.5～4.0	89.0（10C）	80	1 000
Mg²⁺	Na₃V_1.93Mg_0.07（PO₄）₃@citric acid^［48］	2.3～4.2	95.0（10C）	84.6	1 000
	Na₃V_1.95Mg_0.05（PO₄）₃@citric acid^［49］	2.5～4.0	86.2（20C）	81	50
	Na_2.9Mg_0.05V₂（PO₄）₃@citric acid^［50］	2.4～4.0	77.3（10C）	83	1 200
	Na_2.91K_0.09V_1.93Mg_0.07（PO₄）₃@RGO^［51］	2.2～4.0	52.1（10C）	95	500
Ti⁴⁺	Na₃V_1.9Ti_0.1（PO₄）₃@citric acid^［52］	2.0～4.3	116.6（1C）	91.4	1 000
Ti⁴⁺	Na_2.2V_1.2Ti_0.8（PO₄）₃@citric acid^［53］	2.0～4.0	39.6（10C）	93.4	500
Ni²⁺	Na₃V_1.97Ni_0.03（PO₄）₃@citric acid^［54］	2.0～4.0	98.1（5C）	93.5	50
	Na_3.03V_1.97Ni_0.03（PO₄）₃@citric acid^［55］	2.4～4.0	107.1（1C）	95.5	100
	Na_3.2V_1.8Ni_0.2（PO₄）₃@citric acid^［56］	2.0～4.2	103.0（1C）	98	100

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Research progress on Na3V₂（PO₄）₃ cathode materials for sodium ion batteries

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Research progress on Na3V2（PO4）3 cathode materials for sodium ion batteries