Inorganic Chemicals Industry ›› 2022, Vol. 54 ›› Issue (1): 7-11.doi: 10.19964/j.issn.1006-4990.2021-0227

• Reviews and Special Topics • Previous Articles     Next Articles

Present situation and prospect of comprehensive utilization of waste residue containing calcium and magnesium

YAN Xin(),WEI Yilan   

  1. Hunan Vocational and Technical College of Chemical Engineering,Zhuzhou 412004,China
  • Received:2021-04-07 Online:2022-01-10 Published:2022-03-14

Abstract:

Calcium magnesium type waste residue can be divided into Ca(OH)2 type and CaCO3 type.According to the con-tent of magnesium,it can be divided into high magnesium type and low magnesium type.Only high magnesium type waste residue needs to separate and recover magnesium.The common calcium magnesium slags are calcium carbide slag,alkali slag,saponification slag,phosphorus tailings and so on.The present situation of comprehensive utilization of Ca(OH)2 type waste residue was summarized as follows:Ca(OH)2 type waste residue should be separated by leaching,filtration and carboni-zation.Calcium could be separated as PCC by calcination,digestion,leaching,filtration and carbonization.If it was a high mag-nesium type waste residue,it was necessary to increase the chemical and physical steps such as CO2 carbonization,filtration separation,ammonia precipitation separation or pyrolysis of magnesium bicarbonate to realize the separation and recovery of magnesium.Looking forward to the future,the comprehensive utilization of calcium magnesium slag would be a kind of circular economy project with environmental,social and economic benefits,which is worthy of concern,attention and promotion.

Key words: calcium magnesium waste residue, Ca(OH)2 type, CaCO3 type, carbide slag, alkaline, saponified waste residue, phosphorus tailings

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