钛酸亚铁材料的研究现状

doi:10.19964/j.issn.1006-4990.2021-0159

Abstract

Abstract:

FeTiO₃ is a typical ilmenite titanate,and its properties indicate that FeTiO₃ has rich physical and chemical perfor-mance.The preparation method,modification method and performance research status of FeTiO₃ at present were summarized, and the shortcoming in the current research was analyzed,for example,there were few modification methods.As the anode material of lithium ion battery,the capacity attenuation was serious at high magnification rate.In the future,the microstructure of FeTiO₃ could be regulated by changing the preparation process or ion doping,so as to improve its physical and chemical properties,to provide some references for the future performance research and apply of FeTiO₃.

Key words: FeTiO₃, semiconductor composite, magnetic, photocatalytic, lithium-ion battery

CLC Number:

TQ138.11

WANG Xiaohuan,LI Shenghao,SHI Zhiming,WANG Jun,XINBA Yaer,LIU Liang. Research status of FeTiO₃ materials[J]. Inorganic Chemicals Industry, 2022, 54(1): 12-17.

Figures/Tables 2

References 43

[1]	TANG X, HU K. The formation of ilmenite FeTiO₃ powders by a novel liquid mix and H₂/H₂O reduction process[J]. Journal of Materials Science, 2006, 41(23):8025-8028. doi: 10.1007/s10853-006-0908-8
[2]	YE F X, OHMORI A, LI C J, et al. New approach to enhance the pho-tocatalytic activity of plasma sprayed TiO₂ coatings using p-n junctions[J]. Surface and Coatings Technology, 2004, 184:233-238. doi: 10.1016/j.surfcoat.2003.11.012
[3]	YE F X, OHMORI A. The photocatalytic activity and photo-absorp-tion of plasma sprayed TiO₂-Fe₃O₄ binary oxide coatings[J]. Surface and Coatings Technology, 2002, 160:62-67. doi: 10.1016/S0257-8972(02)00377-8
[4]	NAYLOR B F. High-temperature heat contents of the metatitanates of calcium,iron and magnesium[J]. Journal of the American Chemi-cal Society, 1946, 68:1003-1006.
[5]	STICKLER J J. Magnetic resonance and susceptibility of several il-menite powders[J]. Physical Review B, 1967, 162:765-767.
[6]	SHOMATE C H. Heat capacities at low temperatures of the metati-tanates of iron,calcium and Magnesium1[J]. Journal of the Ameri-can Chemical Society, 1946, 68(6):964-966.
[7]	MØRUP S, RASMUSSEN H K, BROK E, et al. Influence of cationdi-sorder on the magnetic properties of ball-milled ilmenite(FeTiO₃)[J]. Materials Chemistry and Physics, 2012, 136(1):184-189. doi: 10.1016/j.matchemphys.2012.06.050
[8]	CHEN Y. Low-temperature oxidation of ilmenite(FeTiO₃) induced by high energy ball milling at room temperature[J]. Journal of Alloys and Compounds, 1997, 257:156-160. doi: 10.1016/S0925-8388(97)00012-1
[9]	ABSALAN Y, BRATCHIKOVA I G, LOBANOV N N, et al. Novel synjournal method for photo-catalytic system based on some 3d-metal titanates[J]. Journal of Materials Science:Materials in Electronics, 2017, 28(23):18207-18219. doi: 10.1007/s10854-017-7769-6
[10]	XIAO W, LU X G, ZOU X L, et al. Phase transitions,micro-morpho-logy and its oxidation mechanism in oxidation of ilmenite(FeTiO₃) powder[J]. Transactions of Nonferrous Metals Society of China, 2013, 23(8):2439-2445. doi: 10.1016/S1003-6326(13)62752-1
[11]	李晴宇, 杜继红, 奚正平, 等. 钛铁矿烧结性能研究[J]. 稀有金属材料与工程, 2010, 39(z1):239-243.
[12]	HAN T R, CHEN Y J, TIAN G H, et al. Hierarchical FeTiO₃-TiO₂ hollow spheres for efficient simulated sunlight-driven water oxida-tion[J]. Nanoscale, 2015, 7:15924-15934. doi: 10.1039/C5NR05242D
[13]	GUAN X F, ZHENG J, ZHAO M L, et al. Synjournal of FeTiO₃ nano-sheets with {0001} facets exposed:Enhanced electrochemical per-formance and catalytic activity[J]. RSC Advances, 2013, 3(33) :13635-13641. doi: 10.1039/c3ra22125c
[14]	TAO T, GLUSHENKOV A M, LIU H W, et al. Ilmenite FeTiO₃ nanoflowers and their pseudocapacitance[J]. The Journal of Physi-cal Chemistry C, 2011, 115:17297-17302.
[15]	ZHANG X, LI T, GONG Z, et al. Shape controlled FeTiO₃ nanostruc-tures:Crystal facet and photocatalytic property[J]. Journal of Alloys and Compounds, 2015, 653:619-623. doi: 10.1016/j.jallcom.2015.09.029
[16]	WANG J, XUE C, YAO W Q, et al. MOF-derived hollow TiO₂@C/FeTiO₃ nanoparticles as photoanodes with enhanced full spectrum light PEC activities[J]. Applied Catalysis B:Environmental, 2019, 250:369-381. doi: 10.1016/j.apcatb.2019.03.002
[17]	GU D G, QIN Y Y, WEN Y C, et al. Photochemical and magnetic activities of FeTiO₃ nanoparticles by electro-spinning synjournal[J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 78:431-437. doi: 10.1016/j.jtice.2017.04.003
[18]	SIVAKUMAR S, SELVARAJ A, RAMASAMY A K, et al. Enhanc-ed photocatalytic degradation of reactive dyes over FeTiO₃/TiO₂ heterojunction in the presence of H₂O₂[J]. Water,Air,and Soil Po-llution, 2013, 224(5).Doi: 10.1007/s11270-013-1529-x. doi: 10.1007/s11270-013-1529-x
[19]	YU L T, LIU J, XU X J, et al. Ilmenite nanotubes for high stability and high rate sodium-ion battery anodes[J]. ACS Nano, 2017, 11(5):5120-5129. doi: 10.1021/acsnano.7b02136
[20]	ZARAZUA-MORÍN M E, TORRES-MARTÍNEZ L M, MOCTEZUMA E, et al. Synjournal,characterization,and catalytic activity of FeTiO₃/TiO₂ for photodegradation of organic pollutants with visible light[J]. Research on Chemical Intermediates, 2016, 42(2):1029-1043. doi: 10.1007/s11164-015-2071-9
[21]	SRINIVAS P, KUMAR A S, BABU P D, et al. Synjournal and mag-netic properties of nanocrystalline FeTiO₃ materials[J]. Journal of Superconductivity and Novel Magnetism, 2018, 31(4):1189-1197. doi: 10.1007/s10948-017-4278-z
[22]	丁士文, 李梅, 王利勇, 等. 微波反应制备纳米TiO₂-Fe₂O₃复合材料及其光催化性能[J]. 河北大学学报:自然科学版, 2005, 25(1):38-42.
[23]	ZHOU F, KOTRU S, PANDEY R K, et al. Pulsed laser-deposited ilmenite-hematite films for application in high-temperature elec-tronics[J]. Thin Solid Films, 1999, 339:114-116. doi: 10.1016/S0040-6090(98)01161-4
[24]	MONA J, KALE S N, GAIKWAD A B, et al. Chemical methods to synthesize FeTiO₃ powders[J]. Materials Letters, 2006, 60(11):1425-1427. doi: 10.1016/j.matlet.2005.11.041
[25]	SIVA P, PRABU P, SELVAM M, et al. Electrocatalytic conversion of carbon dioxide to urea on nano-FeTiO₃ surface[J]. Ionics, 2017, 23(7):1871-1878. doi: 10.1007/s11581-017-1985-1
[26]	YU Y, ZHAO Y J, LI K, et al. Microstructures and optical proper-ties of TiO₂/ZrO₂ nanotube/nanoporous heterofilm prepared by an-odizing of Ti/Zr/Ti multilayer films[J]. Applied Surface Science, 2020, 503.Doi: 10.1016/j.apsusc.2019.144316. doi: 10.1016/j.apsusc.2019.144316
[27]	YU S H, LU Y Y, GAO F, et al. Study on the crystal plane effect of CuO/TiO₂ catalysts in NH₃-SCR reaction[J]. Catalysis Today, 2020, 339:265-273. doi: 10.1016/j.cattod.2019.04.051
[28]	LIN M J, JING G H, SHEN H Z, et al. Mechanism of enhancement of photooxidation of Hg⁰ by CeO₂-TiO₂:Effect of band structure on the formation of free radicals[J]. Chemical Engineering Journal, 2020, 382.Doi: 10.1016/j.cej.2019.122827. doi: 10.1016/j.cej.2019.122827
[29]	YU H L, WU Q X, WANG J, et al. Simple fabrication of the Ag-Ag₂O-TiO₂ photocatalyst thin films on polyester fabrics by magne-tron sputtering and its photocatalytic activity[J]. Applied Surface Science, 2020, 503.Doi: 10.1016/j.apsusc.2019.144075. doi: 10.1016/j.apsusc.2019.144075
[30]	MANUEL L, GATICA J M, VIDAL H. Use of Au/N-TiO₂/SiO₂ pho-tocatalysts in building materials with NO depolluting activity[J]. Journal of Cleaner Production, 2020, 243.Doi: 10.1016/j.jclepro.2019.118633. doi: 10.1016/j.jclepro.2019.118633
[31]	GAO B F, KIM Y J, CHAKRABORTY A K, et al. Efficient decom-position of organic compounds with FeTiO₃/TiO₂ heterojunction under visible light irradiation[J]. Applied Catalysis B:Environ-mental, 2008, 83:202-207.
[32]	ABBASI A. Grafting of silver particles on FeTiO₃/TiO₂/Ag:Synjournal and characterization of FeTiO₃/TiO₂ nanoparticles in presence of CTAB and their application as photocatalyst[J]. Journal of Mate-rials Science:Materials in Electronics, 2018, 29(12):10583-10592.
[33]	DADIGALA R, GANGAPURAM B R, BANDI R, et al. Synjournal and characterization of C-TiO₂/FeTiO₃ and CQD/C-TiO₂/FeTiO₃ photocatalysts with enhanced photocatalytic activities under sun-light irradiation[J]. Acta Metallurgica Sinica(English Letters), 2016, 29(1):17-27.
[34]	ZHANG S T, RUAN Y R, LIU C, et al. The evolution of structure,chemical state and photocatalytic performance of α-Fe/FeTiO₃/TiO₂ with the nitridation at different temperatures[J]. Materials Research Bulletin, 2017, 95:503-508. doi: 10.1016/j.materresbull.2017.08.042
[35]	LI J Q, JING M X, HAN C, et al. A 3D heterogeneous FeTiO₃/TiO₂@C fiber membrane as a self-standing anode for power Li-ion battery[J]. Applied Physics A, 2018, 124(4):332-340. doi: 10.1007/s00339-018-1750-y
[36]	FUJII T, KAYARO M, TAKADA Y, et al. Preparation and charac-terization of epitaxial FeTiO₃+_δ films[J]. Journal of Magnetism and Magnetic Materials, 2004, 272:2010-2011.
[37]	FUJII T, YAMASHITA M, FUJIMORI S, et al. Large magnetic po-larization of Ti⁴⁺ ions in FeTiO₃[J]. Journal of Magnetism and Ma-gnetic Materials, 2007, 310:555-557.
[38]	HOJO H, FUJITA K, TANAKA K, et al. Fabrication of p-type fer-rimagnetic semiconductor thin films based on FeTiO₃-Fe₂O₃ solid solution[J]. Journal of Magnetism and Magnetic Materials, 2007, 310:2105-2107. doi: 10.1016/j.jmmm.2006.10.782
[39]	PAN L H, SHI W, SEN T P, et al. Visible light-driven selective or-ganic degradation by FeTiO₃/persulfate system:the formation and effect of high valent Fe(Ⅳ)[J]. Applied Catalysis B:Environme-ntal, 2021, 280.Doi: 10.1016/j.apcatb.2020.119414. doi: 10.1016/j.apcatb.2020.119414
[40]	MORADI M, VASSEGHIAN Y, KHATAEE A, et al. Ultrasound-assisted synjournal of FeTiO₃/GO nanocomposite for photocatalytic degradation of phenol under visible light irradiation[J]. Separation and Purification Technology, 2021, 261.Doi: 10.1016/j.seppur.2020.118274. doi: 10.1016/j.seppur.2020.118274
[41]	GUO S M, LIU J R, QIU S, et al. Enhancing electrochemical performances of TiO₂ porous microspheres through hybridizing with FeTiO₃ and nanocarbon[J]. Electrochimica Acta, 2016, 190:556-565. doi: 10.1016/j.electacta.2015.12.135
[42]	BRUGNETTI G, FIORE M, LORENZI R, et al. FeTiO₃ as anode material for sodium-ion batteries:From morphology control to de-composition[J]. ChemElectroChem, 2020(7):1713-1722.
[43]	GUO S M, WANG Y, CHEN L J, et al. Porous TiO₂-FeTiO₃@carbon nanocomposites as anode for high-performance lithium-ion batter-ies[J]. Journal of Alloys and Compounds, 2021, 858.Doi: 10.1016/j.jallcom.2020.157635. doi: 10.1016/j.jallcom.2020.157635

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research status of FeTiO₃ materials

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 2

References 43

Related Articles 15

Metrics

Comments

Recommended 0

[1]	ZHANG Feigang, LIU Zhongli. Study on application of CuO/g-C₃N₄ composites in organic dye degradation and supercapacitors [J]. Inorganic Chemicals Industry, 2025, 57(1): 129-136.
[2]	SHI Mengke, FAN Zhaoya, YUE Feng, ZHANG Shuo, MENG Yang, ZHANG Hongzhong. Study on electro-assisted photocatalytic high selective conversion of CO₂ in air [J]. Inorganic Chemicals Industry, 2024, 56(9): 154-163.
[3]	ZHAO Tianting, ZHU Delun, YANG Lin, ZHOU Xinlei. Preparation and process optimization of porous silicon anode materials for lithium-ion battery [J]. Inorganic Chemicals Industry, 2024, 56(5): 31-38.
[4]	ZHOU Haitao, WEN Chengqin, ZHENG Ling, SUN Jie. Research on boron nitride modified film for cathode interface of metallic lithium battery [J]. Inorganic Chemicals Industry, 2024, 56(4): 85-89.
[5]	LI Kuai, LI Zhaoshuai, DONG Tingxuan, LI Dan, GUO Shengwei, HAN Fenglan. Study on effect of wet magnetic separation on distribution of Fe and heavy metal in fly ash [J]. Inorganic Chemicals Industry, 2024, 56(4): 98-104.
[6]	LIU Yichang, XIE Zhipeng, LIU Yunfeng, ZHANG Da, LIANG Feng. Study on impedance matching strategy of enhancing microwave absorption performance of nitrogen-doped single-walled carbon nanohorns [J]. Inorganic Chemicals Industry, 2024, 56(12): 29-34.
[7]	FENG Zhun. Improvement of high temperature stability of high nickel single crystal cathode materials by B/Al/Zr synergistic strategy [J]. Inorganic Chemicals Industry, 2023, 55(8): 59-64.
[8]	FU Minglian, CEN Jianmei, CHEN Zhangxu. Study on preparation of magnetic SiO₂/chitosan composite aerogel and its adsorption for Cu²⁺ [J]. Inorganic Chemicals Industry, 2023, 55(6): 70-77.
[9]	LI Hongyuan,HARI Bala. Research progress of preparation and photocatalytic application of metal halide perovskite quantum dots [J]. Inorganic Chemicals Industry, 2023, 55(2): 36-44.
[10]	TIAN Peng, XU Jingang, XU Qianjin, LIU Kunji, PANG Hongchang, NING Guiling. Preparation of nano-alumina slurry and its application in modifying lithium-ion battery cathode material [J]. Inorganic Chemicals Industry, 2023, 55(12): 43-49.
[11]	YU Jianguo,SUN Qing,QIU Shengbo,ZHANG Yiren,CHEN Jun. Lithium resources development supporting national new energy strategy development [J]. Inorganic Chemicals Industry, 2023, 55(1): 1-14.
[12]	TANG Di,WANG Junxiong,CHEN Wen,JI Guanjun,MA Jun,ZHOU Guangmin. Research status and prospect on direct regeneration of cathode materials from retired lithium-ion batteries [J]. Inorganic Chemicals Industry, 2023, 55(1): 15-25.
[13]	XU Qianjin,XU Jingang,TIAN Peng,LIU Kunji,GAO Tingting,NING Guiling. Research progress of alumina coated cathode materials for lithium-ion batteries [J]. Inorganic Chemicals Industry, 2023, 55(1): 46-55.
[14]	MA Bingxiang,SHEN Yunxia,LI Na,LI Min,WEI Yaoyi,ZHAO Yu. Effect of sulfate on photocatalytic activity of polymerized carbon nitride [J]. Inorganic Chemicals Industry, 2022, 54(9): 150-157.
[15]	SONG Zhi, LIU Boxia, CHEN Yaoyao. Study on synthesis of FeWO₄/WO₃ complex by sol-gel and degradation of textile dye wastewater [J]. Inorganic Chemicals Industry, 2022, 54(5): 131-137.

Research status of FeTiO3 materials