以轻烧氧化镁制备六角片状氢氧化镁的研究

doi:10.19964/j.issn.1006-4990.2021-0154

Abstract

Abstract:

Hexagonal plates of magnesium hydroxide was prepared from salt lake light-burned magnesia with different grain size by hydration-hydrothermal method.The influence of reaction temperature,reaction time,stirring rate and solid-liquid ratio on the conversion rate of magnesia,the morphology and particle size of magnesium hydroxide was investigated systematically. The phase,morphology and particle size of magnesium hydroxide were investigated by X-ray diffraction（XRD）,scanning electronic microscope（SEM）,and laser particle size analyzer（LPSA） respectively.Meanwhile,magnesium hydroxide from di-fferent raw materials was added in PE to test its flame retardancy.The results showed that by controlling the reaction tempera-ture,reaction time,stirring speed and solid-liquid ratio,the hydration rate of magnesium oxide raw powder could reach 95%,the hydration rate of magnesium oxide fine grinding powder could reach 100%,and the obtained magnesium hydroxide was both hexagonal,but the particle size was different.When it was used in PE,fine-grained magnesium hydroxide had better dispersion and more obvious flame retardant performance.

Key words: light-burned magnesia, hexagonal plates, magnesium hydroxide, flame retardant, hydrothermal

CLC Number:

TQ132.2

KONG Huimin,ZOU Laixi,LIU Yuan,CAO Yuwei,LIN Yanjun,LUO Xianping. Study on preparation of hexagonal plates of magnesium hydroxide by light-burned magnesium oxide[J]. Inorganic Chemicals Industry, 2022, 54(1): 39-44.

Figures/Tables 10

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

References 30

[1]	孙淑英, 宋兴福, 张登科, 等. 废弃水氯镁石反应结晶制备高纯氢氧化镁[J]. 环境科学与技术, 2010, 33(12F):298-300.
[2]	曹雨微, 逯登琴, 宋学文, 等. 新型镁系阻燃材料制备工艺及应用研究现状[J]. 盐科学与化工, 2019, 48(10):8-14.
[3]	罗仙平, 李建康, 徐徽, 等. 电熔镁砂制备工艺及熔炼过程[J]. 盐业与化工, 2016, 45(8):8-13.
[4]	李陇岗, 钟辉, 杨建元. 盐湖水氯镁石制备高纯镁砂的研究进展[J]. 盐湖研究, 2004, 12(1):57-61.
[5]	徐徽, 程俊峰, 李贵, 等. 水氯镁石制备硅钢级氧化镁[J]. 材料导报, 2013, 27(8):104-107.
[6]	PILARSKA A A, KLAPISZEWSKI L, JESIONOWSKI T. Recent de-velopment in the synjournal,modification and application of Mg(OH)₂ and MgO[J]. Powder Technology, 2017, 319:373-407. doi: 10.1016/j.powtec.2017.07.009
[7]	韩以群, 王朝乾. 氢氧化镁生产及其废液在烟气脱硫中的应用研究[J]. 盐科学与化工, 2017, 46(4):35-37.
[8]	郭如新. 氢氧化镁在工业废水处理中应用研究进展[J]. 精细与专用化学品, 2010, 18(4):42-47.
[9]	潘晓鸿, 杨兆元, 李东哲, 等. 纳米氢氧化镁对抗菌类药物的增效作用[J]. 基因组学与应用生物学, 2016, 35(12):3249-3254.
[10]	DONG C, CAIRNEY J, SUN Q, et al. Investigation of Mg(OH)₂ nano-particles as an antibacterial agent[J]. Journal of Nanoparticle Re-search, 2010, 12(10):2101-2109.
[11]	DONG C, HE G, ZHENG W, et al. Study on antibacterial mechanism of Mg(OH)₂ nanoparticles[J]. Materials Letters, 2014, 134(11):286-289. doi: 10.1016/j.matlet.2014.07.110
[12]	PILARSKA A, BULA K, MYSZKA K, et al. Functional polypro-pylene composites filled with ultra-fine magnesium hydroxide[J]. Open Chemistry, 2015, 13(9):161-171.
[13]	LI H, LIU S, ZHAO J, et al. Removal of reactive dyes from waste water assisted with kaolin clay by magnesium hydroxide coagula-tion process[J]. Colloids and Surfaces A-Physicochemical and Eng-ineering Aspects, 2016, 494:222-227.
[14]	LIU S. Flame retardant and mechanical properties of polyethylene/magnesium hydroxide/montmorillonite nanocomposites[J]. Journal of Industrial and Engineering Chemistry, 2014, 20(4):2401-2408. doi: 10.1016/j.jiec.2013.10.020
[15]	GUL R, ISLAM A, YASIN T, et al. Flame-retardant synergism of sepiolite and magnesium hydroxide in a linear low-density polye-thylene composite[J]. Journal of Applied Polymer Science, 2011, 121(5):2772-2777. doi: 10.1002/app.v121.5
[16]	SUIHKONEN R, NEVALAINEN K, ORELL O, et al. Performance of epoxy filled with nano-and micro-sized magnesium hydroxide[J]. Journal of Materials Science, 2012, 47(9):1480-1488. doi: 10.1007/s10853-011-5933-6
[17]	刘志启, 李丽娟, 曾忠民, 等. 用水氯镁石制备单分散六角片状氢氧化镁[J]. 材料科学与工艺, 2011, 19(4):138-144.
[18]	LIU L, HU J, ZHUO J, et al. Synergistic flame retardant effects bet-ween hollow glass microspheres and magnesium hydroxide in ethy-lene-vinyl acetate composites[J]. Polymer Degradation and Stabi-lity, 2014, 104(6):87-94.
[19]	CHEN X, JIE Y, GUO S, et al. Surface modification of magnesium hydroxide and its application in flame retardant polypropylene co-mposites[J]. Journal of Materials Science, 2009, 44(5):1324-1332. doi: 10.1007/s10853-009-3273-6
[20]	GENOVESE A, SHANKS R A. Structural and thermal interpreta-tion of the synergy and interactions between the fire retardants magnesium hydroxide and zinc borate[J]. Polymer Degradation and Stability, 2007, 92(1):2-13. doi: 10.1016/j.polymdegradstab.2006.10.006
[21]	CHEN D, ZHENG Q, LIU F, et al. Flame-retardant polypropylene composites based on magnesium hydroxide modified by phospho-rous-containing polymers[J]. Journal of Thermoplastic Composite Materials, 2009, 23(2):175-192. doi: 10.1177/0892705708103396
[22]	徐嘉欣, 颜粉鸽, 黄建翠, 等. 高分散型六角片状氢氧化镁的制备与表征[J]. 盐科学与化工, 2018, 47(3):14-21.
[23]	宋雪雪, 李丽娟, 姬连敏, 等. 纳米及微米级六角片状氢氧化镁的制备[J]. 盐湖研究, 2018, 26(2):66-74.
[24]	赵卓雅, 李祥高, 王世荣, 等. 六角片状氢氧化镁(001)晶面优先生长条件的研究[J]. 人工晶体学报, 2014, 43(7):1611-1619.
[25]	吴易梅, 孙玉柱, 路贵民, 等. 结晶-水热法制备六角片状氢氧化镁[J]. 高等化学工程学报, 2019, 32(2):425-434.
[26]	CHEN Y, ZHOU T, FANG H, et al. A novel preparation of nano-sized hexagonal Mg(OH)₂ as a flame retardant[J]. China Particuo-logy, 2016, 24(1):177-182.
[27]	FANG H, ZHOU T, CHEN X, et al. Controlled preparation and cha-racterization of nano-sized hexagonal Mg(OH)₂ flame retardant[J]. China Particuology, 2014, 14(3):51-56.
[28]	JIN D, GU X, YU X, et al. Hydrothermal synjournal and characteri-zation of hexagonal Mg(OH)₂ nano-flake as a flame retardant[J]. Materials Chemistry & Physics, 2008, 112(3):962-965.
[29]	汪艳, 王伟, 张俊, 等. 轻烧镁粉制备超细片状氢氧化镁[J]. 武汉工程大学学报, 2013, 35(1):41-45.
[30]	孙晓君, 丁珂, 仇龙, 等. 以轻烧粉制备六方片状氢氧化镁[J]. 硅酸盐学报, 2019, 47(4):530-536.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation of hexagonal plates of magnesium hydroxide by light-burned magnesium oxide

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 30

Related Articles 15

Metrics

Comments

Recommended 0

[1]	DI Lu, WANG Weiguo, CHEN Juexian, WU Chuanshu. Study on preparation of transition metal-supported Silicalite-1 zeolite catalyst and its catalytic performance for furfural hydrogenation [J]. Inorganic Chemicals Industry, 2024, 56(4): 125-132.
[2]	YANG En, SHEN Hongyan, LIU Youzhi. In situ modification of superfine magnesium hydroxide with silicon polyether [J]. Inorganic Chemicals Industry, 2024, 56(4): 42-49.
[3]	LI Chao, WANG Liping, DAI Yin, GAO Guimei, ZHANG Yunfeng, HONG Yu, XU Lijun, CUI Yongjie. Study on alkali fusion hydrothermal synthesis of 13X zeolite from high silicon tailings and its adsorption on lead，copper and zinc ions [J]. Inorganic Chemicals Industry, 2023, 55(9): 88-93.
[4]	DING Hongyu, ZHONG Jianchu, WANG Hongzhi, ZHANG Shuang. Hydrothermal synthesis of talc by crystal seed induction method [J]. Inorganic Chemicals Industry, 2023, 55(5): 59-65.
[5]	CHEN Zhangxu, FU Minglian, ZHU Danchen, ZHENG Bingyun. Preparation of carbon/graphite carbon nitride composites and their methylene blue removal performance [J]. Inorganic Chemicals Industry, 2023, 55(3): 134-139.
[6]	DONG Xiongwei, HAN Fenglan, HUA Wei, LI Maohui, AN Changcong, HUANG Yucai. Synthesis and characterization of silico-manganese slag zeolite [J]. Inorganic Chemicals Industry, 2023, 55(12): 128-132.
[7]	JIANG Demin, LI Shunmei, Li Qingqing, Chen Yuxin, LIU Daijun. Hydrothermal synthesis of basic magnesium sulfate whiskers from magnesium hydroxide and magnesium sulfate heptahydrate [J]. Inorganic Chemicals Industry, 2023, 55(12): 74-81.
[8]	PENG Qiugui, YANG Fan, LÜ Renliang, XIANG Lan. Effect of pre-reduction on deferrization in hydrothermal hydrolysis process of Mg/Al/Fe-bearing TiOSO₄ solution [J]. Inorganic Chemicals Industry, 2023, 55(12): 95-101.
[9]	TENG Jiayang, FENG Qingge, ZHANG Xuan, QIN Fanghong, FENG Jinghang, HU Jiawen, CHEN Chaohong. Study on preparation of pseudo-boehmite from aluminum dross resource treatment [J]. Inorganic Chemicals Industry, 2023, 55(11): 130-138.
[10]	LU Yang,WANG Jing,HE Lijie,WANG Fudong,ZHANG Jiaming. Research progress on preparation of magnesium aluminate spinel powders and it in field of luminescent material [J]. Inorganic Chemicals Industry, 2022, 54(9): 39-46.
[11]	YANG Yongyu,TIAN Peng,ZHOU Ruohui,XU Qianjin,LIU Kunji,NING Guiling. Effect of gibbsite activation on preparation of boehmite by hydrothermal method [J]. Inorganic Chemicals Industry, 2022, 54(9): 55-62.
[12]	PANG Hongchang,WANG Zhiyu,TIAN Peng,NING Guiling. Study on synthesis and properties of two component magnesium based flame retardant by“one?pot method” [J]. Inorganic Chemicals Industry, 2022, 54(8): 54-58.
[13]	JIANG Tiantian,XU Xuetang,WANG Fan. Research on growth and supercapacitance of NiCo based electrode materials regulated by halogen ions [J]. Inorganic Chemicals Industry, 2022, 54(8): 66-73.
[14]	LI Xiao,ZHAO Yuxiang,LI Bo,ZOU Xingwu,WANG Shuxuan. Study on controllable synthesis of spherical strontium fluoride [J]. Inorganic Chemicals Industry, 2022, 54(5): 67-71.
[15]	CUI Jiaxin,WANG Lianyong,LU Simeng,SUN Yanwen,WANG Rui,HE Yan,HAN Jianli. Research on performance of hydrothermally synthesized zeolite with fly ash from different producing areas [J]. Inorganic Chemicals Industry, 2022, 54(5): 96-100.