Inorganic Chemicals Industry ›› 2021, Vol. 53 ›› Issue (3): 68-72.doi: 10.11962/1006-4990.2020-0190

• Environment·Health·Safety • Previous Articles     Next Articles

Titanium white by-product ferrous sulfate photofenton oxidation degradation of methyl orange in wastewater

Shu Yirui1,2(),Zhang Pan1,2,Wang Wei1,2,Xiang Hengli1,2,Ren Genkuan3,Xu Dehua1,2,Zhang Zhiye1,2,Yang Xiushan1,2()   

  1. 1. School of Chemical Engineering,Sichuan University,Chengdu 610065,China
    2. Engineering Research Center of Comprehensive Utilization and Clean Processing of Phosphorus Resources,Ministry of Education
    3. Yibin University
  • Received:2020-09-19 Online:2021-03-10 Published:2021-03-11
  • Contact: Yang Xiushan E-mail:shuyirui@163.com;yangxiushan3@163.com

Abstract:

Using ferrous sulfate(by-product of tianium white) as iron source and catalyst of photogenic Fenton,the oxidative decomposition of methyl orange by ferrous sulfate-H2O2 system under ultraviolet light was studied.The effect of temperature, concentration of H2O2,wavelength of ultraviolet light,concentration of ferrous sulfate and concentration of Fe2+ on the decolorization rate of methyl orange was investigated.It is demonstrated that the decolorization rate of methyl orange is the fastest which reaches 100% under the conditions of 35 ℃,6.4 mmol/L of hydrogen peroxide,1.0 mmol/L of ferrous sulfate(about 1.0 mmol/L of Fe2+) and 395 nm of ultraviolet light.The decolorization effect of the ferrous sulfate on methyl orange was better than that of pure heptahydrate ferrous sulfate.The work has expanded a new strategy for the effective utilization of the by-product of tianium white,which can be used to treat methyl orange by catalytic degradation

Key words: ferrous sulfate produced by titanium dioxide, photocatalytic, wastewater treatment, methyl orange, degradation

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