糠醇加氢制1,2-戊二醇催化剂的制备及性能研究

doi:10.11962/1006-4990.2019-0419

Abstract

Abstract:

The copper oxide catalyst FAH-1 was synthesized by the chemical co-precipitation method.The performance and hydrogenation process conditions for hydrogenation of furfuryl alcohol to 1,2-pentanediol over FAH-1 catalyst were investigated in the 30 mL adiabatic fixed-bed microreactor.The results showed that FAH-1 catalyst exhibited good activity and selectivity for the catalytic hydrogenation of furfural alcohol,the conversion rate was 91.80%,the selectivity was 41.52% and the maximal 1,2-pentanediol yield was 38.12% under the conditions of reaction temperature of 160 ℃,hydrogen pressure of 6 MPa,LHSV of 0.3 h ^-1 and hydrogen to oil volume ratio of 10 000∶1.After 1 000 hours running,the catalyst exhibited stable hydrogenation performance.The production could satisfy the requirement of 1,2-pentaned-iol secondary processing with its high purity and good quality.It has good industrialization prospect by using fixed-bed reactor.

Key words: furfuryl alcohol, hydrogenation, 1, 2-pentanediol, copper oxide catalyst

CLC Number:

TQ131.21

Zheng Xiuxin,Jiang Zhikui,Sun Guofang,Fei Yanan,Zhang Yaori,Zhang Lijuan. Study on preparation and properties of 1,2-pentanediol catalyst by hydrogenation of furfuryl alcohol[J]. Inorganic Chemicals Industry, 2020, 52(6): 96-100.

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[1]	罗岩, 徐保明, 汤国亮 , 等. 丙环唑中间体1,2-戊二醇的合成进展[J]. 农药, 2010,49(3):161-163.
[2]	郑亚清, 丁克鸿, 杨进 , 等. 丙环唑中间体1,2-戊二醇合成[J]. 农药, 2014,53(2):96-98,106.
[3]	侯薇 . 用乙酐合成法制备邻二醇[J].天津化工, 1996(3):28-29.
[4]	侯薇, 陶风岗 . 合成环氧化合物的新途径[J]. 化学工业与工程, 1996,13(3):47-50.
[5]	丁小兵 . 杀菌剂丙环唑的合成研究[D]. 苏州:苏州大学, 2005.
[6]	Issler H ,Maul R. Continuous process for producing 1,2-alkanedi-ols:US,4479021[P]. 1984-10-23.
[7]	Siegmeier R, Prescher G, Maurer H , et al. ontinuous process for the production of pentanediol-l,2:US,4605795[P]. 1986 -08-12.
[8]	俞小鸥 .一种1 , 2-戊二醇的制备方法:中国,1552684[P]. 2004 -12-08.
[9]	Koch O, Kockritz A, Kant M , et al.Method for producing 1,2-pen-tanediol:US,8921617B2[P]. 2014-12-30.
[10]	Liu H . Selective hydrogenolysis of biomass-derived furfuryl alcohol into 1,2-and 1,5-pentanediol over highly dispersed Cu-Al₂O₃ catalysts[J]. Chinese Journal of Catalysis, 2016,37(5):700-710.
[11]	Panagiotopoulou P, Vlachos D G . Liquid phase catalytic transfer hydrogenation of furfural over a Ru/C catalyst[J]. Applied Cataly-sis A:General, 2014,480:17-24.
[12]	Sharma R V, Das U, Sammynaiken R , et al. Liquid phase chemo-selective catalytic hydrogenation of furfural to furfuryl alcohol[J]. Applied Catalysis A:General, 2013,454:127-136.
[13]	Villaverde M M, Bertero N M, Garetto T F , et al. Selective liquid-phase hydrogenation of furfural to furfuryl alcohol over Cu-based catalysts[J]. Catalysis Today, 2013,213:87-92.
[14]	赵会吉, 邢金仙, 刘晨光 . 骨架镍催化糠醇液相加氢制备四氢糠醇[J]. 石油大学学报:自然科学版, 2003,27(1):91-94.
[15]	许彦娟 . 糠醇催化加氢制备1,2-戊二醇的研究[D]. 杭州:浙江大学, 2014.
[16]	Chen X, Li H, Luo H , et al. Liquid phase hydrogenation of furfural to furfuryl alcohol over Mo-doped Co-B amorphous alloy catalys-ts[J]. Applied Catalysis A:General, 2002,233:13-20.
[17]	Kijeński J, Winiarek P, Paryjczak T , et al. Platinum deposited on monolayer supports in selective hydrogenation of furfural to furfu-ryl alcohol [J]. Applied Catalysis A:General, 2002,233:171-182.

项目	外观形状	孔容/ （mL·g^-1）	比表面积/ （m²·g^-1）	平均孔径/nm	表观密度/ （g·cm^-3）	强度/ （N·cm^-1）	磨耗/ %
测试结果	黑色,圆柱状	0.14	46.0	12.17	1.1	110	0.15
测试标准	—	—	—	—	—	①	②

1,2-戊二醇	外观	纯度（GC）/ %	密度（20 ℃）/ （g·cm^-3）	折光率	红外光谱	沸点/ ℃	闪点/ ℃
标准样品	无色至黄色液体	≥98	0.970 0~ 0.974 0	1.437 0~ 1.441 0	和对照匹配	—	—
制备样品	无色液体	>99.5	0.971 0	1.439 0	和对照匹配	208	106

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on preparation and properties of 1,2-pentanediol catalyst by hydrogenation of furfuryl alcohol

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