无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (11): 49-.

• 论文 • 上一篇    下一篇

还原挥发氧化锌烟尘中有价金属分离工艺研究

范兴祥,汪云华,吴跃东,赵家春,董海刚   

  1. 昆明贵金属研究所,稀贵金属综合利用新技术国家重点实验室,云南昆明 650106
  • 发布日期:2011-11-09

Research on process of separating valuable metals from zinc oxide fly ash

 FAN  Xing-Xiang, WANG  Yun-Hua, WU  Yue-Dong, ZHAO  Jia-Chun, DONG  Hai-Gang   

  1. State Key Laboratory of Advanced Technologies of Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals,Kunming 650106,China
  • Online:2011-11-09

摘要: 针对含多种有价金属的还原挥发氧化锌烟尘,提出一条全湿法分离烟尘中有价金属的工艺路线。首先采用加双氧水氧化稀硫酸浸出,经过滤和洗涤,分别获得含硫酸锌、硫酸铟浸出液和含铅、铋浸出渣,实现锌、铟与铅、铋分离;对含硫酸锌和硫酸铟浸出液采用P204萃取,实现锌与铟的分离;对含铅、铋浸出渣采用碳酸氢铵转化生成碳酸铅,加硝酸溶解,实现铅与铋的分离。该工艺不仅可有效分离烟尘中的有价金属,而且获得的硫酸锌、硫酸铟、硝酸铅、富铋渣可用于生产其他化工产品,为氧化锌烟尘高效综合利用提供了一条新的途径。

关键词: 烟尘, 氧化锌, 有价金属

Abstract: On the basis of zinc oxide fly ash bearing multiple valuable metals,a whole hydrometallurgical technique for separation valuable metals from zinc oxide fly ash has been put forward.First,zinc oxide fly ash was leached by adding hydrogen peroxide and sulfuric acid,leaching liquor bearing zinc sulfate and indium sulfate and leaching residue bearing Pb and Bi were obtained by filtration and washing,and realized the separation of Zn and In from Pb and Bi.Leaching liquor realized the separation of Zn from In by P204 extraction.Lead sulfate in leaching residue was converted into lead carbonate by adding ammonium bicarbonate,and then lead carbonate reacted with added nitric acid,which realized the separation of Pb from Bi.On the one hand,the process realized the separation valuable metals from zinc oxide fly ash,on the other hand,zinc sulfate,indium sulfate,lead nitrate, and rich bismuth residue during the separation were used for producing the other chemical products.This process has supplied a new process for making comprehensive use of zinc oxide fly ash.

Key words: fly ash;zinc oxide, valuable metals

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