无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (10): 1-6.doi: 10.11962/1006-4990.2018-0647

• 无机盐工业 •    下一篇

纳米或多孔氧化铬粒子制备的研究进展

刘玉欣1,石凤娟2,吕耀辉1,魏世丞1,王玉江1,何东昱1,王文宇1   

  1. 1.陆军装甲兵学院装备再制造技术国防科技重点实验室,北京 100072;2.中原工学院能源与环境学院
  • 出版日期:2019-10-10 发布日期:2020-03-06
  • 作者简介:刘玉欣(1972— ),女,副研究员,研究方向为应用化学及金属腐蚀与防护,已发表文章50余篇,授权国家发明专利10余项; E-mail:lyxinbgd@163.com。 通讯作者:石凤娟(1973— ),女,博士后,研究方向为环境催化;E-mail:zshifengjuan@163.com。 吕耀辉(1970— ),男,博士,博士生导师,研究方向为材料科学与工程;E-mail:lyxinbgd@163.com。

Progress in preparation of nano?鄄sized or porous chromium oxide particles

Liu Yuxin1,Shi Fengjuan2,Lü Yaohui1,Wei Shicheng1,Wang Yujiang1,He Dongyu1,Wang Wenyu1   

  1. 1.National Key Laboratory for Remanufacturing,Army Academy of Armored Forces,Beijing 100072,China; 2.College of Environmental and Energy,Zhongyuan University of Technology
  • Published:2019-10-10 Online:2020-03-06

摘要: 综述了近年来国内外纳米或多孔氧化铬的制备方法,即气相法、固相法和液相法(主要包括热分解法、沉淀法、溶胶-凝胶法、水热合成法、模板法、溶液燃烧法、超声化学法等);讨论了各制备方法对粒子表面形貌、粒径尺寸或孔结构、晶相结构等的影响;展望了今后对这类纳米或多孔材料研究与应用的发展方向。在诸多制备方法中,模板法或其与其他方法的联用法是制备规整形貌、有序孔结构、均匀粒径分布、高热稳定性氧化铬的较为适宜的方法。模板法有望发展成为高效实用的催化剂制备技术。

关键词: 氧化铬;纳米粒子;多孔材料;多相催化

Abstract: The preparation methods,such as gasphase method,solidphase method and liquidphase method(mainly includ ing thermal decomposition method,precipitation method,sol-gel method,hydrothermal method,templating method,solution combustion method and ultrasonic chemical method),of nanosized or porous chromium oxides reported in recent years at home and abroad were summarized.The influences of these methods on the surface morphology,particle size or pore structrue, crystal phase and so on were discussed.Then,the development trend in the investigations and applications of the nanosized or porous materials in future was envisioned.Among the above preparation methods,the templating method or its combination with other preparation methods might be a more appropriate pathway for the generation of chromium oxides with regular surface morphology,ordered pore structure,uniform particle size distribution and good thermal stability.It is expected that the templating method will be developed into efficient and practicable preparation method for catalyst.

Key words: chromium oxide;nanosized particle;porous material;heterogeneous catalysis

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