无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (7): 24-.

• 论文 • 上一篇    下一篇

微波协同条件下钾长石低温提钾工艺研究

徐 畅,赵建海,赵晶星   

  1. 天津城建大学环境与市政工程学院,天津 300384
  • 出版日期:2015-07-10 发布日期:2015-09-24

Study on potassium extraction technology from K-feldspar assisted with microwave at low temperature

 XU   Chang, ZHAO  Jian-Hai, ZHAO  Jing-Xing   

  1. School of Environmental and Municipal Engineering,Tianjin Chengjian University,Tianjin 300384,China
  • Online:2015-07-10 Published:2015-09-24

摘要: 探讨了微波协同条件下钾长石低温提钾工艺过程。在微波消解仪中使用化学试剂与钾长石反应,分析各影响因素对钾溶出率的影响。研究结果表明:钾长石粒径越小,钾的溶出率越高;硫酸质量分数增大,溶出率逐步增大;溶出率随反应温度的上升而增加,在反应温度达到160 ℃时,钾提取率趋于稳定。利用响应面分析法对钾长石提取工艺条件进行优化,最终确定最佳实验条件:硫酸质量分数为70%,钾长石与磷矿质量比为0.8∶1,氟化钙与磷酸钙质量比为3∶1,温度为160 ℃,钾提取率达到83%以上。

关键词: 微波, 钾长石, 提钾

Abstract: Potassium extraction technology from K-feldspar assisted with microwave at low temperature was discussed.Effects of different parameters on potassium dissolution rate were analyzed when chemical reagents reacted with K-feldspar in a microwave digestion system under different conditions.Results showed that potassium dissolution rate increased with decreasing K-feldspar size.Increasing reaction temperature and the mass fraction of sulphuric acid can increase higher potassium dissolution rate.Potassium extraction efficiency remained stable when increasing reaction temperature to 160 ℃.The optimized operation conditions were obtained by using response surface methodology(RSM).Above 83% of the potassium extraction efficiency was obtained under experimental conditions: the mass fraction of sulphuric acid was 70%,the mass ratio of K-feldspar to phosphorite was 0.8∶1,the mass ratio of calcium fluoride to calcium phosphate was 3∶1, and the temperature was 160 ℃.

Key words: microwave, K-feldspar, potassium extraction

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