无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (8): 15-.

• 论文 • 上一篇    下一篇

粗级碳酸锂提纯工艺过程研究

李燕茹,朱 亮,袁建军,沙作良,杨美洁,左玥华   

  1. 天津科技大学天津市海洋资源与化学重点实验室,天津 300457
  • 出版日期:2013-08-10 发布日期:2013-08-14

Research on purifying process of coarse lithium carbonate

LI  Yan-Ru, ZHU   Liang, YUAN  Jian-Jun, SHA  Zuo-Liang, YANG  Mei-Jie, ZUO  Yue-Hua   

  1. Tianjin Key Laboratory of Marine Resources and Chemistry,Tianjin University of Science and Technology,Tianjin 300457,China
  • Published:2013-08-10 Online:2013-08-14

摘要: 碳酸锂产品在陶瓷、冶金、能源、医药等行业应用广泛,实际应用中对碳酸锂产品的纯度要求很高。由于生产技术和盐湖卤水自身条件的限制,直接提取的碳酸锂产品都很难达到要求。基于实际应用的需求,以从卤水制备而得的粗级碳酸锂产品为原料,通过氢化分解法对其提纯,研究了氢化反应中的二氧化碳气体流速、氢化时间、氢化温度及固液比4个氢化条件对粗级碳酸锂溶解的影响。结果表明,采用这项简单工艺可使粗级碳酸锂产品的纯度由88%提高到99%以上,一次性产率达到75%以上。

关键词: 碳酸锂, 提纯工艺, 氢化分解法

Abstract: Lithium carbonate(Li2CO3) is widely used in the fields of ceramics,metallurgy,energy,and pharmaceutical etc..A lot of practical applications of Li2CO3 need high purity,but the Li2CO3 that extracts directly from the salt lake brine are difficult to meet the requirements due to existing technology and the limitations of the salt lake brine itself.Based on the practical requirements,carbonation-decomposition method to get high-purity Li2CO3 from the coarse Li2CO3 products was studied.The effects of carbonation conditions,such as CO2 flow rate,carbonation time,carbonation temperature,and the ratio of solid to liquid,on the dissolution of coarse Li2CO3 were also investigated.Results showed through the simple process the purity of Li2CO3 could increase from 88% to more than 99%,and the yield of the all process could reach more than 75%.

Key words: lithium carbonate, purifying process, carbonation-decomposition method

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