无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (5): 71-.

• 论文 • 上一篇    下一篇

钆掺杂铌酸钾的制备及其光催化降解罗丹明性能

蔡河山1,卓少春2,黄 芷2,李慧珊2,孙 明2   

  1. 1.佛山科学技术学院资源环境系,广东佛山 528000;2.广东工业大学轻工化工学院
  • 出版日期:2016-05-10 发布日期:2016-05-16

Hydrothermal synthesis of Gd-doped potassium niobate and its photocatalytic activity to rhodamine degradation

Cai Heshan1,Zhuo Shaochun2,Huang Zhi2,Li Huishan2,Sun Ming2   

  1. 1.Department of Resources and Environment,Foshan University,Foshan 528000,China;
    2.School of Chemical Engineering and Light Industry,Guangdong University of Technology
  • Published:2016-05-10 Online:2016-05-16

摘要: 以氢氧化钾、氧化铌和硝酸钆为原料,采用水热法合成了结晶度高、掺杂不同含量的稀土元素钆的K4Nb6O17光催化剂纳米片。借助XRD、SEM、TEM和XPS等手段对其结构和形貌做了表征,考察了钆掺杂铌酸钾复合材料对有机染料罗丹明的降解性能。结果表明,钆的掺杂提高了铌酸钾的结晶度,钆掺杂量为0.5%(物质的量分数)的铌酸钾具有最佳的光催化活性,30 mg催化剂可对质量浓度为20 mg/L的罗丹明溶液(100 mL)快速降解。

关键词: 铌酸钾, 水热合成, 光催化

Abstract:  Gd doped nano-flake K4Nb6O17 photocatalysts with high crystallinity were prepared by using KOH,Nb2O5,and Gd(NO3)3 as raw materials under hydrothermal conditions.The morphology and structure of the prepared photo-catalysts were characterized by XRD,SEM,TEM,snd XPS etc..The degradation performance to rhodamine was also investigated.Results showed that the doping of Gd increased the crystallinity of K4Nb6O17.The catalyst with a doping content of Gd of 0.5%(amount-of-substance fraction) had the best performance for rhodamine degradation.Under the radiation of ultraviolet lamp,30 mg of catalyst could effectively degraded 100 mL of rhodamine with a mass concentration of 20 mg/L.

Key words: potassium niobate, hydrothermal synthesis, photocatalysis

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