无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (3): 56-.

• 论文 • 上一篇    下一篇

徐闻盐场苦卤制备阻燃型氢氧化镁

吴健松1,黄雪清2,伍思韵2,潘琳清2,邓国丽2   

  1. 1.岭南师范学院化学化工学院,广东湛江 524048;2.岭南师范学院生物科学与技术学院
  • 出版日期:2016-03-10 发布日期:2016-03-11

Preparation of flame-retardant magnesium hydroxide with brine from Xuwen salt field

Wu Jiansong1,Huang Xueqing2,Wu Siyun2,Pan Linqing2,Deng Guoli2   

  1. 1.School of Chemistry and Chemical Engineering,Lingnan Normal University,Zhanjiang 524048,China;
    2.School of Biological Science and Technology,Lingnan Normal University
  • Online:2016-03-10 Published:2016-03-11

摘要: 以徐闻苦卤为原料,先在体系中加入碳酸钠-碳酸氢钠缓冲溶液,再以氢氧化钠为沉淀剂,采用液相沉淀法制备了阻燃型氢氧化镁。通过扫描电镜(SEM)及X射线衍射(XRD)等测试手段表征了产品的形貌及物相。实验结果表明,在氢氧化钠浓度为0.4 mol/L、反应温度为75 ℃、晶化时间为24 h条件下,可以获得纯度高、结晶度高的氢氧化镁,且氢氧化镁晶体粒度分布均匀、分散性好。该工艺简单易行、对环境无破坏,具有较高的潜在经济效益。

关键词: 氢氧化镁, 苦卤, 阻燃剂, 缓冲溶液

Abstract: The flame-retardant magnesium hydroxide was synthesized by liquid precipitation reaction method with Xuwen brine as raw material.This process was as follows:A buffer solution of Na2CO3-NaHCO3 was added into the reaction system firstly,and then NaOH was added as the precipitant.The phase and crystal morphology of magnesium hydroxide samples were characterized by X-ray diffraction(XRD) and scanning electron microscop(SEM).The magnesium hydroxides with a well- defined shape as well as smooth surface could be obtained under the following conditions:concentration of NaOH was 0.4 mol/L,reaction temperature was 75 ℃,and crystallization time was 24 h.The SEM revealed that the magnesium hydroxide form with fine dispersive capability and uniform distribution.The process was not only simple,but also production cost less and environment preserved.Therefore,it had higher potential economic benefits.

Key words: magnesium hydroxide, brine, flame-retardant, buffer solution

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