无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (10): 54-.

• 论文 • 上一篇    下一篇

二甲基亚砜工业废盐中亚硝酸钠的脱除研究

郭 举   

  1. 瓮福(集团)有限责任公司,贵州福泉 550501
  • 出版日期:2016-10-10 发布日期:2016-10-08

Study on removal of sodium nitrite from DMSO industrial waste residue

 GUO   Ju   

  1. Wengfu(Group) Co.,Ltd .,Fuquan 550501,China
  • Online:2016-10-10 Published:2016-10-08

摘要: 利用二甲基硫醚氧化法制备二甲基亚砜的企业在生产过程中会副产一定量的工业废盐,其主要成分为硝酸钠并含有较大量的亚硝酸钠,需要脱除其中含有的亚硝酸钠使其达到国家排放标准要求。研究了二甲基亚砜工业废盐中亚硝酸钠的氧化脱除工艺,分别采用热空气、双氧水、臭氧3种不同的氧化剂,对废盐中亚硝酸钠的氧化脱除效果进行了研究,并比较了其处理成本。研究结果表明臭氧对亚硝酸钠的脱除效果最好,可将废盐中亚硝酸钠质量分数由2.48%降至0.000 14%,脱除率近100%,其处理成本低,约60元/t。

关键词: 二甲基亚砜废盐, 亚硝酸钠, 脱除

Abstract: A certain amount of industrial waste residue were produced from the enterprises in the production process of DMSO by dimethyl thioether oxidation method,and the main ingredient of the residue was sodium nitrate and contained some sodium nitrite which needed to be removed to meet the requirements of the national emission standards.The oxidation process of sodium nitrite in industrial waste residue with hot air,H2O2,and ozone was studied respectively,and their costs were compared.Results showed that the effect of ozone was the best,sodium nitrite mass fraction can be reduced from 2.48% to 0.000 14%,the removal rate was near 100%,the treatment cost was low,and it was about 60 yuan/t.

Key words: residue of DMSO, sodium nitrite, removal

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