无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (10): 23-.

• 论文 • 上一篇    下一篇

轻烧粉蒸氨液中杂离子对氢氧化镁晶体的影响

李 雪1,张 滢1,侯 睿2,张 研1,刘云义1   

  1. 1.沈阳化工大学化学工程学院,辽宁沈阳 110142;2.中国寰球工程公司辽宁分公司
  • 出版日期:2016-10-10 发布日期:2016-10-08

Influence of impurity ions on magnesium hydroxide product in ammonia-evaporation refined solution

Li Xue1,Zhang Ying1,Hou Rui2,Zhang Yan1,Liu Yunyi1   

  1. 1.College of Chemical Engineering,Shenyang University of Chemical Technology,
    Shenyang 110142,China;2.Huanqiu Liaoning Co.,HQC
  • Online:2016-10-10 Published:2016-10-08

摘要: 以轻烧粉精制液和氨气为原料,研究了蒸氨精制液中杂质离子对氢氧化镁形貌的影响。选取阳离子NH4+、Ca2+和阴离子SO42-作为研究对象,考察了其对氢氧化镁的形貌和颗粒大小的影响。采用扫描电镜(SEM)、X射线衍射仪(XRD)和激光粒度仪对产品进行表征。结果表明,NH4+、Ca2+对氢氧化镁产品的性能影响较小,而SO42-对氢氧化镁产品的形貌和粒径影响较显著。并利用氯化钡除去溶液中的SO42-,比较未除硫、除硫后与用纯氯化镁制备的产品的差别。

关键词: 轻烧粉, 氨气, 杂质离子, 氢氧化镁

Abstract: With the light burning powder refined liquid and ammonia as raw materials,the influence of impurity ions in steamed ammonia refining fluid on the magnesium hydroxide morphology was investigated.Cationic NH4+,Ca2+,and anion SO42- were selected as the research objects to investigate their influences on the morphology and particle size of magnesium hydroxide.The products were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),and laser par- ticle size analyzer.Results showed that NH4+ and Ca2+ little influenced on the performance of magnesium hydroxide product, and the SO42-  had a great influence on the morphology and particle size of magnesium hydroxide product.BaCl2 was used to remove SO42- in the solution.The difference of the undesulphurized and desulphurized products was also compared with the product prepared with pure magnesium chloride.

Key words: light burning powder, ammonia, impurity ions, magnesium hydroxide

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